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Coupled effects of chloride ions and branch chained polypropylene ether LP-1™ on the electrochemical deposition of copper from sulfate solutions

Identifieur interne : 001E88 ( Main/Curation ); précédent : 001E87; suivant : 001E89

Coupled effects of chloride ions and branch chained polypropylene ether LP-1™ on the electrochemical deposition of copper from sulfate solutions

Auteurs : Susanne Goldbach [France] ; Werner Messing [Pays-Bas] ; Theo Daenen [Pays-Bas] ; François Lapicque [France]

Source :

RBID : ISTEX:F838FABE8735F74E97C1B679F0D1C16A6491076B

Descripteurs français

English descriptors

Abstract

Abstract: The paper presents the results of electrochemical investigations of copper deposition from a sulfate/sulfuric bath of industrial relevancy and containing two additives. In particular the effect of chloride ion with polypropylene ether (LP-1™) could be highlighted by voltammetry and impedance measurements. When used without chloride ion LP-1 adsorbs at the surface which reduces significantly the current density and the double layer capacitance. A current peak was observed for the simultaneous presence of the two additives and this was attributed to a sudden inhibition of the surface: in a narrow range of potential Cl-complexes were assumed to desorb from the surface, allowing significant adsorption of inert LP-1 molecules. Besides, kinetic parameters and the diffusion coefficient of cupric ion were correlated to the concentrations of additives, copper sulfate and sulfuric acid in a broad range of concentration.

Url:
DOI: 10.1016/S0013-4686(98)00112-1

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ISTEX:F838FABE8735F74E97C1B679F0D1C16A6491076B

Le document en format XML

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<term>Absolute overpotential</term>
<term>Acta</term>
<term>Active surface</term>
<term>Additive</term>
<term>Adsorption</term>
<term>Adsorption phenomena</term>
<term>Ambient temperature</term>
<term>Anodic charge transfer</term>
<term>Average value</term>
<term>Bath composition</term>
<term>Branched polymer</term>
<term>Broad range</term>
<term>Bulk concentrations</term>
<term>Bulk solution</term>
<term>Capacitance</term>
<term>Cathode surface</term>
<term>Charge transfer</term>
<term>Charge transfer resistance</term>
<term>Chemical composition</term>
<term>Chloride</term>
<term>Chloride ions</term>
<term>Complexation phenomena</term>
<term>Concentration effect</term>
<term>Constant phase element</term>
<term>Copper</term>
<term>Copper Sulfates</term>
<term>Copper deposition</term>
<term>Copper electrodeposition</term>
<term>Copper sulfate</term>
<term>Copper surface</term>
<term>Coverage fraction</term>
<term>Cupric</term>
<term>Cupric ions</term>
<term>Cuprous</term>
<term>Cuprous ions</term>
<term>Current densities</term>
<term>Current density</term>
<term>Current peak</term>
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<term>Deposition</term>
<term>Disk electrode</term>
<term>Double layer capacitance</term>
<term>Electrical impedance</term>
<term>Electrochemical investigations</term>
<term>Electrochemical reaction</term>
<term>Electrochimica</term>
<term>Electrochimica acta</term>
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<term>Electrode impedance</term>
<term>Electrode surface</term>
<term>Electrodeposition</term>
<term>Electrolyte solutions</term>
<term>Electrolytic</term>
<term>Electrolytic bath</term>
<term>Electron transfer</term>
<term>Electrostatic phenomena</term>
<term>Elsevier science</term>
<term>Experimental data</term>
<term>Experimental study</term>
<term>Frequency domain</term>
<term>Frequency loop</term>
<term>Goldbach</term>
<term>Good agreement</term>
<term>High overpotentials</term>
<term>Impedance</term>
<term>Impedance measurements</term>
<term>Impedance parameter</term>
<term>Impedance spectra</term>
<term>Industrial relevancy</term>
<term>Inert molecules</term>
<term>Kinetic parameter</term>
<term>Kinetic parameters</term>
<term>Linear voltammetry</term>
<term>Lower extent</term>
<term>Medium effect</term>
<term>Metal interface</term>
<term>Nacl</term>
<term>Overpotential</term>
<term>Overpotential range</term>
<term>Overpotentials</term>
<term>Physical parameters</term>
<term>Plating surf</term>
<term>Platinum</term>
<term>Polypropylene ether</term>
<term>Potential range</term>
<term>Previous investigations</term>
<term>Production lines</term>
<term>Propylene oxide polymer</term>
<term>Rate constant</term>
<term>Reaction mechanism</term>
<term>Reference solution</term>
<term>Rotating disk electrode</term>
<term>Rotation rate</term>
<term>Rsol</term>
<term>Scan rate</term>
<term>Second loop</term>
<term>Simultaneous presence</term>
<term>Sodium Chlorides</term>
<term>Sodium chloride</term>
<term>Sodium chloride concentrations</term>
<term>Standard potentials</term>
<term>Sudden inhibition</term>
<term>Sulfate</term>
<term>Sulfate bath</term>
<term>Sulfuric</term>
<term>Sulfuric acid</term>
<term>Sulfuric solutions</term>
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<term>Voltammetric curves</term>
<term>Voltammetry</term>
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<term>Constante vitesse</term>
<term>Cuivre</term>
<term>Cuivre Sulfate</term>
<term>Dépôt électrolytique</term>
<term>Effet concentration</term>
<term>Effet milieu</term>
<term>Electrode disque tournant</term>
<term>Etude expérimentale</term>
<term>Impédance électrique</term>
<term>Mécanisme réaction</term>
<term>Paramètre cinétique</term>
<term>Platine</term>
<term>Polymère ramifié</term>
<term>Propène oxyde polymère</term>
<term>Réaction électrochimique</term>
<term>Sodium Chlorure</term>
<term>Sulfurique acide</term>
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<keywords scheme="Teeft" xml:lang="en">
<term>Absolute overpotential</term>
<term>Acta</term>
<term>Active surface</term>
<term>Additive</term>
<term>Adsorption</term>
<term>Adsorption phenomena</term>
<term>Ambient temperature</term>
<term>Anodic charge transfer</term>
<term>Average value</term>
<term>Bath composition</term>
<term>Broad range</term>
<term>Bulk concentrations</term>
<term>Bulk solution</term>
<term>Capacitance</term>
<term>Cathode surface</term>
<term>Charge transfer</term>
<term>Charge transfer resistance</term>
<term>Chemical composition</term>
<term>Chloride</term>
<term>Chloride ions</term>
<term>Complexation phenomena</term>
<term>Constant phase element</term>
<term>Copper deposition</term>
<term>Copper electrodeposition</term>
<term>Copper sulfate</term>
<term>Copper surface</term>
<term>Coverage fraction</term>
<term>Cupric</term>
<term>Cupric ions</term>
<term>Cuprous</term>
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<term>Current densities</term>
<term>Current density</term>
<term>Current peak</term>
<term>Cuso4</term>
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<term>Disk electrode</term>
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<term>Electrochimica</term>
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<term>Electrode surface</term>
<term>Electrolyte solutions</term>
<term>Electrolytic</term>
<term>Electrolytic bath</term>
<term>Electron transfer</term>
<term>Electrostatic phenomena</term>
<term>Elsevier science</term>
<term>Experimental data</term>
<term>Frequency domain</term>
<term>Frequency loop</term>
<term>Goldbach</term>
<term>Good agreement</term>
<term>High overpotentials</term>
<term>Impedance</term>
<term>Impedance measurements</term>
<term>Impedance parameter</term>
<term>Impedance spectra</term>
<term>Industrial relevancy</term>
<term>Inert molecules</term>
<term>Kinetic parameters</term>
<term>Linear voltammetry</term>
<term>Lower extent</term>
<term>Metal interface</term>
<term>Nacl</term>
<term>Overpotential</term>
<term>Overpotential range</term>
<term>Overpotentials</term>
<term>Physical parameters</term>
<term>Plating surf</term>
<term>Polypropylene ether</term>
<term>Potential range</term>
<term>Previous investigations</term>
<term>Production lines</term>
<term>Reference solution</term>
<term>Rotation rate</term>
<term>Rsol</term>
<term>Scan rate</term>
<term>Second loop</term>
<term>Simultaneous presence</term>
<term>Sodium chloride</term>
<term>Sodium chloride concentrations</term>
<term>Standard potentials</term>
<term>Sudden inhibition</term>
<term>Sulfate</term>
<term>Sulfate bath</term>
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<term>Sulfuric acid</term>
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<term>Voltammetric</term>
<term>Voltammetric curves</term>
<term>Voltammetry</term>
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<div type="abstract" xml:lang="en">Abstract: The paper presents the results of electrochemical investigations of copper deposition from a sulfate/sulfuric bath of industrial relevancy and containing two additives. In particular the effect of chloride ion with polypropylene ether (LP-1™) could be highlighted by voltammetry and impedance measurements. When used without chloride ion LP-1 adsorbs at the surface which reduces significantly the current density and the double layer capacitance. A current peak was observed for the simultaneous presence of the two additives and this was attributed to a sudden inhibition of the surface: in a narrow range of potential Cl-complexes were assumed to desorb from the surface, allowing significant adsorption of inert LP-1 molecules. Besides, kinetic parameters and the diffusion coefficient of cupric ion were correlated to the concentrations of additives, copper sulfate and sulfuric acid in a broad range of concentration.</div>
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<s1>Laboratoire des Sciences du Génie Chimique, CNRS-ENSIC-INPL, BP 451</s1>
<s2>54001 Nancy</s2>
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<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<region type="region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName>
<orgName type="university">Université de Lorraine</orgName>
<orgName type="institution">Centre national de la recherche scientifique</orgName>
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<title level="j" type="main">Electrochimica acta</title>
<title level="j" type="abbreviated">Electrochim. acta</title>
<idno type="ISSN">0013-4686</idno>
<imprint>
<date when="1998">1998</date>
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<title level="j" type="main">Electrochimica acta</title>
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<idno type="ISSN">0013-4686</idno>
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<term>Branched polymer</term>
<term>Concentration effect</term>
<term>Copper</term>
<term>Copper Sulfates</term>
<term>Electrical impedance</term>
<term>Electrochemical reaction</term>
<term>Electrodeposition</term>
<term>Experimental study</term>
<term>Kinetic parameter</term>
<term>Medium effect</term>
<term>Platinum</term>
<term>Propylene oxide polymer</term>
<term>Rate constant</term>
<term>Reaction mechanism</term>
<term>Rotating disk electrode</term>
<term>Sodium Chlorides</term>
<term>Sulfuric acid</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Dépôt électrolytique</term>
<term>Réaction électrochimique</term>
<term>Cuivre</term>
<term>Cuivre Sulfate</term>
<term>Sulfurique acide</term>
<term>Effet milieu</term>
<term>Sodium Chlorure</term>
<term>Propène oxyde polymère</term>
<term>Polymère ramifié</term>
<term>Effet concentration</term>
<term>Electrode disque tournant</term>
<term>Platine</term>
<term>Paramètre cinétique</term>
<term>Constante vitesse</term>
<term>Mécanisme réaction</term>
<term>Impédance électrique</term>
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<keywords scheme="Wicri" type="topic" xml:lang="fr">
<term>Cuivre</term>
<term>Platine</term>
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<div type="abstract" xml:lang="en">The paper presents the results of electrochemical investigations of copper deposition from a sulfate/sulfuric bath of industrial relevancy and containing two additives. In particular the effect of chloride ion with polypropylene ether (LP-1) could be highlighted by voltammetry and impedance measurements. When used without chloride ion LP-1 adsorbs at the surface which reduces significantly the current density and the double layer capacitance. A current peak was observed for the simultaneous presence of the two additives and this was attributed to a sudden inhibition of the surface: in a narrow range of potential Cl-complexes were assumed to desorb from the surface, allowing significant adsorption of inert LP-1 molecules. Besides, kinetic parameters and the diffusion coefficient of cupric ion were correlated to the concentrations of additives, copper sulfate and sulfuric acid in a broad range of concentration.</div>
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<title level="j" type="abbrev">EA</title>
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<publisher>ELSEVIER</publisher>
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<term>Absolute overpotential</term>
<term>Acta</term>
<term>Active surface</term>
<term>Additive</term>
<term>Adsorption</term>
<term>Adsorption phenomena</term>
<term>Ambient temperature</term>
<term>Anodic charge transfer</term>
<term>Average value</term>
<term>Bath composition</term>
<term>Broad range</term>
<term>Bulk concentrations</term>
<term>Bulk solution</term>
<term>Capacitance</term>
<term>Cathode surface</term>
<term>Charge transfer</term>
<term>Charge transfer resistance</term>
<term>Chemical composition</term>
<term>Chloride</term>
<term>Chloride ions</term>
<term>Complexation phenomena</term>
<term>Constant phase element</term>
<term>Copper deposition</term>
<term>Copper electrodeposition</term>
<term>Copper sulfate</term>
<term>Copper surface</term>
<term>Coverage fraction</term>
<term>Cupric</term>
<term>Cupric ions</term>
<term>Cuprous</term>
<term>Cuprous ions</term>
<term>Current densities</term>
<term>Current density</term>
<term>Current peak</term>
<term>Cuso4</term>
<term>Deposition</term>
<term>Disk electrode</term>
<term>Double layer capacitance</term>
<term>Electrochemical investigations</term>
<term>Electrochimica</term>
<term>Electrochimica acta</term>
<term>Electrode</term>
<term>Electrode impedance</term>
<term>Electrode surface</term>
<term>Electrolyte solutions</term>
<term>Electrolytic</term>
<term>Electrolytic bath</term>
<term>Electron transfer</term>
<term>Electrostatic phenomena</term>
<term>Elsevier science</term>
<term>Experimental data</term>
<term>Frequency domain</term>
<term>Frequency loop</term>
<term>Goldbach</term>
<term>Good agreement</term>
<term>High overpotentials</term>
<term>Impedance</term>
<term>Impedance measurements</term>
<term>Impedance parameter</term>
<term>Impedance spectra</term>
<term>Industrial relevancy</term>
<term>Inert molecules</term>
<term>Kinetic parameters</term>
<term>Linear voltammetry</term>
<term>Lower extent</term>
<term>Metal interface</term>
<term>Nacl</term>
<term>Overpotential</term>
<term>Overpotential range</term>
<term>Overpotentials</term>
<term>Physical parameters</term>
<term>Plating surf</term>
<term>Polypropylene ether</term>
<term>Potential range</term>
<term>Previous investigations</term>
<term>Production lines</term>
<term>Reference solution</term>
<term>Rotation rate</term>
<term>Rsol</term>
<term>Scan rate</term>
<term>Second loop</term>
<term>Simultaneous presence</term>
<term>Sodium chloride</term>
<term>Sodium chloride concentrations</term>
<term>Standard potentials</term>
<term>Sudden inhibition</term>
<term>Sulfate</term>
<term>Sulfate bath</term>
<term>Sulfuric</term>
<term>Sulfuric acid</term>
<term>Sulfuric solutions</term>
<term>Voltammetric</term>
<term>Voltammetric curves</term>
<term>Voltammetry</term>
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<keywords scheme="Teeft" xml:lang="en">
<term>Absolute overpotential</term>
<term>Acta</term>
<term>Active surface</term>
<term>Additive</term>
<term>Adsorption</term>
<term>Adsorption phenomena</term>
<term>Ambient temperature</term>
<term>Anodic charge transfer</term>
<term>Average value</term>
<term>Bath composition</term>
<term>Broad range</term>
<term>Bulk concentrations</term>
<term>Bulk solution</term>
<term>Capacitance</term>
<term>Cathode surface</term>
<term>Charge transfer</term>
<term>Charge transfer resistance</term>
<term>Chemical composition</term>
<term>Chloride</term>
<term>Chloride ions</term>
<term>Complexation phenomena</term>
<term>Constant phase element</term>
<term>Copper deposition</term>
<term>Copper electrodeposition</term>
<term>Copper sulfate</term>
<term>Copper surface</term>
<term>Coverage fraction</term>
<term>Cupric</term>
<term>Cupric ions</term>
<term>Cuprous</term>
<term>Cuprous ions</term>
<term>Current densities</term>
<term>Current density</term>
<term>Current peak</term>
<term>Cuso4</term>
<term>Deposition</term>
<term>Disk electrode</term>
<term>Double layer capacitance</term>
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<term>Electrochimica</term>
<term>Electrochimica acta</term>
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<term>Electrode impedance</term>
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<term>Electrolyte solutions</term>
<term>Electrolytic</term>
<term>Electrolytic bath</term>
<term>Electron transfer</term>
<term>Electrostatic phenomena</term>
<term>Elsevier science</term>
<term>Experimental data</term>
<term>Frequency domain</term>
<term>Frequency loop</term>
<term>Goldbach</term>
<term>Good agreement</term>
<term>High overpotentials</term>
<term>Impedance</term>
<term>Impedance measurements</term>
<term>Impedance parameter</term>
<term>Impedance spectra</term>
<term>Industrial relevancy</term>
<term>Inert molecules</term>
<term>Kinetic parameters</term>
<term>Linear voltammetry</term>
<term>Lower extent</term>
<term>Metal interface</term>
<term>Nacl</term>
<term>Overpotential</term>
<term>Overpotential range</term>
<term>Overpotentials</term>
<term>Physical parameters</term>
<term>Plating surf</term>
<term>Polypropylene ether</term>
<term>Potential range</term>
<term>Previous investigations</term>
<term>Production lines</term>
<term>Reference solution</term>
<term>Rotation rate</term>
<term>Rsol</term>
<term>Scan rate</term>
<term>Second loop</term>
<term>Simultaneous presence</term>
<term>Sodium chloride</term>
<term>Sodium chloride concentrations</term>
<term>Standard potentials</term>
<term>Sudden inhibition</term>
<term>Sulfate</term>
<term>Sulfate bath</term>
<term>Sulfuric</term>
<term>Sulfuric acid</term>
<term>Sulfuric solutions</term>
<term>Voltammetric</term>
<term>Voltammetric curves</term>
<term>Voltammetry</term>
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<div type="abstract" xml:lang="en">Abstract: The paper presents the results of electrochemical investigations of copper deposition from a sulfate/sulfuric bath of industrial relevancy and containing two additives. In particular the effect of chloride ion with polypropylene ether (LP-1™) could be highlighted by voltammetry and impedance measurements. When used without chloride ion LP-1 adsorbs at the surface which reduces significantly the current density and the double layer capacitance. A current peak was observed for the simultaneous presence of the two additives and this was attributed to a sudden inhibition of the surface: in a narrow range of potential Cl-complexes were assumed to desorb from the surface, allowing significant adsorption of inert LP-1 molecules. Besides, kinetic parameters and the diffusion coefficient of cupric ion were correlated to the concentrations of additives, copper sulfate and sulfuric acid in a broad range of concentration.</div>
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