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Czochralski growth of RE3Ga5SiO14 (RE=La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity

Identifieur interne : 001E87 ( Main/Curation ); précédent : 001E86; suivant : 001E88

Czochralski growth of RE3Ga5SiO14 (RE=La, Pr, Nd) single crystals for the analysis of the influence of rare earth substitution on piezoelectricity

Auteurs : J. Sato [Japon] ; H. Takeda [Japon] ; H. Morikoshi [Japon] ; K. Shimamura [Japon] ; P. Rudolph [Japon, Allemagne] ; T. Fukuda [Japon]

Source :

RBID : ISTEX:3287437C1195150D8C9800326310A9111BDB9E49

English descriptors

Abstract

Abstract: Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.

Url:
DOI: 10.1016/S0022-0248(98)00362-5

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ISTEX:3287437C1195150D8C9800326310A9111BDB9E49

Le document en format XML

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<div type="abstract" xml:lang="en">Abstract: Pr3Ga5SiO14 and Nd3Ga5SiO14 single crystals with constant diameter of 22mm and lengths up to 145mm have been grown by the Czochralski method. The phase identification, site occupancy of cations and axial lattice parameter distribution were determined by X-ray analysis. The transmission spectra within the 340–3200nm wavelength region were measured. The centre of interest are the piezoelectric properties of (2 1̄ 0) and (0 1 0) plates in comparison with former grown La3Ga5SiO14 crystals in order to find out the influence of the rare earth substitution of La3+ by Pr3+ and Nd3+ on the piezoelectric strain constant d11. A decrease of |d11| with increasing atomic number was found giving the hint to the substitution of lanthanum by further elements with larger atomic radii.</div>
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