Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Identifieur interne : 006A37 ( Main/Exploration ); précédent : 006A36; suivant : 006A38Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Auteurs : Matthias Tamm [Allemagne] ; Andreas Kunst ; Thomas Bannenberg ; Eberhardt Herdtweck ; Peter Sirsch ; Cornelis J. Elsevier ; Jan M. ErnstingSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2004-10-18.
English descriptors
- KwdEn :
Abstract
Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].
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DOI: 10.1002/anie.200460538
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The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</div></front></TEI><affiliations><list><country><li>Allemagne</li></country></list><tree><noCountry><name sortKey="Bannenberg, Thomas" sort="Bannenberg, Thomas" uniqKey="Bannenberg T" first="Thomas" last="Bannenberg">Thomas Bannenberg</name><name sortKey="Elsevier, Cornelis J" sort="Elsevier, Cornelis J" uniqKey="Elsevier C" first="Cornelis J." last="Elsevier">Cornelis J. Elsevier</name><name sortKey="Ernsting, Jan M" sort="Ernsting, Jan M" uniqKey="Ernsting J" first="Jan M." last="Ernsting">Jan M. Ernsting</name><name sortKey="Herdtweck, Eberhardt" sort="Herdtweck, Eberhardt" uniqKey="Herdtweck E" first="Eberhardt" last="Herdtweck">Eberhardt Herdtweck</name><name sortKey="Kunst, Andreas" sort="Kunst, Andreas" uniqKey="Kunst A" first="Andreas" last="Kunst">Andreas Kunst</name><name sortKey="Sirsch, Peter" sort="Sirsch, Peter" uniqKey="Sirsch P" first="Peter" last="Sirsch">Peter Sirsch</name></noCountry><country name="Allemagne"><noRegion><name sortKey="Tamm, Matthias" sort="Tamm, Matthias" uniqKey="Tamm M" first="Matthias" last="Tamm">Matthias Tamm</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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