Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Identifieur interne : 006A38 ( Main/Exploration ); précédent : 006A37; suivant : 006A39Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Auteurs : Matthias Tamm [Allemagne] ; Andreas Kunst ; Thomas Bannenberg ; Eberhardt Herdtweck ; Peter Sirsch ; Cornelis J. Elsevier ; Jan M. ErnstingSource :
- Angewandte Chemie [ 0044-8249 ] ; 2004-10-18.
English descriptors
- KwdEn :
Abstract
Die Einführung der Me2Si‐Brücke und die Verzerrung der Sandwichstruktur erleichtern die Wechselwirkung des 16‐Elektronen‐ansa‐Komplexes (siehe Bild; blau Ti, gelb Si, grau C) mit σ‐Donor/π‐Acceptorliganden wie CO oder Isocyaniden. Dadurch gelang es, die elektronische Struktur dieses stark gebogenen ersten ansa‐Cycloheptatrienyl‐Cyclopentadienyl‐Übergangsmetallkomplexes zu untersuchen. Der Komplex wurde aus [(η‐C7H7)Ti(η‐C5H5)] erhalten.
Url:
DOI: 10.1002/ange.200460538
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="de">Die Einführung der Me2Si‐Brücke und die Verzerrung der Sandwichstruktur erleichtern die Wechselwirkung des 16‐Elektronen‐ansa‐Komplexes (siehe Bild; blau Ti, gelb Si, grau C) mit σ‐Donor/π‐Acceptorliganden wie CO oder Isocyaniden. Dadurch gelang es, die elektronische Struktur dieses stark gebogenen ersten ansa‐Cycloheptatrienyl‐Cyclopentadienyl‐Übergangsmetallkomplexes zu untersuchen. Der Komplex wurde aus [(η‐C7H7)Ti(η‐C5H5)] erhalten.</div>
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