Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Identifieur interne : 002D15 ( Istex/Corpus ); précédent : 002D14; suivant : 002D16Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Auteurs : Matthias Tamm ; Andreas Kunst ; Thomas Bannenberg ; Eberhardt Herdtweck ; Peter Sirsch ; Cornelis J. Elsevier ; Jan M. ErnstingSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2004-10-18.
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Abstract
Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].
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DOI: 10.1002/anie.200460538
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ISTEX:F3F02EA42C57CE648A2400C5A12DA397722307A3Le document en format XML
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The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>keywords</head><item><term>cycloheptatrienyl ligands</term></item><item><term>cyclopentadienyl ligands</term></item><item><term>density functional calculations</term></item><item><term>sandwich complexes</term></item><item><term>titanium</term></item></list></keywords></textClass><textClass><keywords scheme="Journal Subject"><list><head>article-category</head><item><term>Communication</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2004-05-02">Received</change><change when="2004-10-18">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3773</doi><issn type="print">1433-7851</issn><issn type="electronic">1521-3773</issn><idGroup><id type="product" value="ANIE"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="ANGEWANDTE CHEMIE INTERNATIONAL EDITION">Angewandte Chemie International Edition</title><title type="short">Angewandte Chemie International Edition</title></titleGroup></publicationMeta><publicationMeta level="part" position="410"><doi origin="wiley" registered="yes">10.1002/anie.v43:41</doi><numberingGroup><numbering type="journalVolume" number="43">43</numbering><numbering type="journalIssue">41</numbering></numberingGroup><coverDate startDate="2004-10-18">October 18, 2004</coverDate></publicationMeta><publicationMeta level="unit" type="shortCommunication" position="30" status="forIssue"><doi origin="wiley" registered="yes">10.1002/anie.200460538</doi><idGroup><id type="unit" value="ANIE200460538"></id></idGroup><countGroup><count type="pageTotal" number="5"></count></countGroup><titleGroup><title type="articleCategory">Communication</title></titleGroup><copyright ownership="publisher">Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2004-05-02"></event><event type="firstOnline" date="2004-10-13"></event><event type="publishedOnlineFinalForm" date="2004-10-13"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText mathml2tex" date="2010-04-20"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-03"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">5530</numbering><numbering type="pageLast">5534</numbering></numberingGroup><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:ANIE.ANIE200460538.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="9"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="44"></count></countGroup><titleGroup><title type="main" xml:lang="en"><i>Ansa</i>‐Cycloheptatrienyl–Cyclopentadienyl Complexes<link href="#nss"></link></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Matthias</givenNames><familyName>Tamm</familyName><degrees>Prof. Dr.</degrees></personName><contactDetails><email>matthias.tamm@ch.tum.de</email></contactDetails></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Andreas</givenNames><familyName>Kunst</familyName><degrees>Dipl.‐Chem.</degrees></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Thomas</givenNames><familyName>Bannenberg</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Eberhardt</givenNames><familyName>Herdtweck</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#ab"><personName><givenNames>Peter</givenNames><familyName>Sirsch</familyName><degrees>Dr.</degrees></personName></creator><creator xml:id="au6" creatorRole="author" affiliationRef="#ac"><personName><givenNames>Cornelis J.</givenNames><familyName>Elsevier</familyName><degrees>Prof. Dr.</degrees></personName></creator><creator xml:id="au7" creatorRole="author" affiliationRef="#ac"><personName><givenNames>Jan M.</givenNames><familyName>Ernsting</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="aa" countryCode="DE" type="organization"><unparsedAffiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</unparsedAffiliation></affiliation><affiliation xml:id="ab" countryCode="DE" type="organization"><unparsedAffiliation>Institut für Physik, Universität Augsburg</unparsedAffiliation></affiliation><affiliation xml:id="ac" countryCode="NL" type="organization"><unparsedAffiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">cycloheptatrienyl ligands</keyword><keyword xml:id="kwd2">cyclopentadienyl ligands</keyword><keyword xml:id="kwd3">density functional calculations</keyword><keyword xml:id="kwd4">sandwich complexes</keyword><keyword xml:id="kwd5">titanium</keyword></keywordGroup><supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2002/2004/z460538_s.pdf">http://www.wiley‐vch.de/contents/jc_2002/2004/z460538_s.pdf</url> or from the author.</p></supportingInformation><abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Introduction of the Me</b><sub><b>2</b></sub><b>Si bridge</b> and distortion of the sandwich structure facilitate the interaction of the 16‐electron <i>ansa‐</i>complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first <i>ansa</i>‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C<sub>7</sub>H<sub>7</sub>)Ti(η‐C<sub>5</sub>H<sub>5</sub>)].<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14337851:media:ANIE200460538:content"></mediaResource><mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource><mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource><mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource></mediaResourceGroup></blockFixed></p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="nss"><p>This work has been supported by the Deutsche Forschungsgemeinschaft.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title></titleInfo><name type="personal"><namePart type="given">Matthias</namePart><namePart type="family">Tamm</namePart><namePart type="termsOfAddress">Prof. Dr.</namePart><affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation><affiliation>E-mail: matthias.tamm@ch.tum.de</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Andreas</namePart><namePart type="family">Kunst</namePart><namePart type="termsOfAddress">Dipl.‐Chem.</namePart><affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Thomas</namePart><namePart type="family">Bannenberg</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Eberhardt</namePart><namePart type="family">Herdtweck</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Peter</namePart><namePart type="family">Sirsch</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Institut für Physik, Universität Augsburg</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Cornelis J.</namePart><namePart type="family">Elsevier</namePart><namePart type="termsOfAddress">Prof. Dr.</namePart><affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jan M.</namePart><namePart type="family">Ernsting</namePart><affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication"></genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2004-10-18</dateIssued><dateCaptured encoding="w3cdtf">2004-05-02</dateCaptured><copyrightDate encoding="w3cdtf">2004</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType><extent unit="figures">9</extent><extent unit="tables">1</extent><extent unit="references">44</extent></physicalDescription><abstract type="graphical" lang="en">Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</abstract><note type="content">*This work has been supported by the Deutsche Forschungsgemeinschaft.</note><subject lang="en"><genre>keywords</genre><topic>cycloheptatrienyl ligands</topic><topic>cyclopentadienyl ligands</topic><topic>density functional calculations</topic><topic>sandwich complexes</topic><topic>titanium</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title></titleInfo><titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title></titleInfo><genre type="journal">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2002/2004/z460538_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">1433-7851</identifier><identifier type="eISSN">1521-3773</identifier><identifier type="DOI">10.1002/(ISSN)1521-3773</identifier><identifier type="PublisherID">ANIE</identifier><part><date>2004</date><detail type="volume"><caption>vol.</caption><number>43</number></detail><detail type="issue"><caption>no.</caption><number>41</number></detail><extent unit="pages"><start>5530</start><end>5534</end><total>5</total></extent></part></relatedItem><identifier type="istex">F3F02EA42C57CE648A2400C5A12DA397722307A3</identifier><identifier type="DOI">10.1002/anie.200460538</identifier><identifier type="ArticleID">ANIE200460538</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. 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