Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Identifieur interne : 002D15 ( Istex/Corpus ); précédent : 002D14; suivant : 002D16Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Auteurs : Matthias Tamm ; Andreas Kunst ; Thomas Bannenberg ; Eberhardt Herdtweck ; Peter Sirsch ; Cornelis J. Elsevier ; Jan M. ErnstingSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2004-10-18.
English descriptors
- KwdEn :
Abstract
Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].
Url:
DOI: 10.1002/anie.200460538
Links to Exploration step
ISTEX:F3F02EA42C57CE648A2400C5A12DA397722307A3Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
<author><name sortKey="Tamm, Matthias" sort="Tamm, Matthias" uniqKey="Tamm M" first="Matthias" last="Tamm">Matthias Tamm</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>E-mail: matthias.tamm@ch.tum.de</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Kunst, Andreas" sort="Kunst, Andreas" uniqKey="Kunst A" first="Andreas" last="Kunst">Andreas Kunst</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Bannenberg, Thomas" sort="Bannenberg, Thomas" uniqKey="Bannenberg T" first="Thomas" last="Bannenberg">Thomas Bannenberg</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Herdtweck, Eberhardt" sort="Herdtweck, Eberhardt" uniqKey="Herdtweck E" first="Eberhardt" last="Herdtweck">Eberhardt Herdtweck</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Sirsch, Peter" sort="Sirsch, Peter" uniqKey="Sirsch P" first="Peter" last="Sirsch">Peter Sirsch</name>
<affiliation><mods:affiliation>Institut für Physik, Universität Augsburg</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Elsevier, Cornelis J" sort="Elsevier, Cornelis J" uniqKey="Elsevier C" first="Cornelis J." last="Elsevier">Cornelis J. Elsevier</name>
<affiliation><mods:affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Ernsting, Jan M" sort="Ernsting, Jan M" uniqKey="Ernsting J" first="Jan M." last="Ernsting">Jan M. Ernsting</name>
<affiliation><mods:affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</mods:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:F3F02EA42C57CE648A2400C5A12DA397722307A3</idno>
<date when="2004" year="2004">2004</date>
<idno type="doi">10.1002/anie.200460538</idno>
<idno type="url">https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">002D15</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
<author><name sortKey="Tamm, Matthias" sort="Tamm, Matthias" uniqKey="Tamm M" first="Matthias" last="Tamm">Matthias Tamm</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
<affiliation><mods:affiliation>E-mail: matthias.tamm@ch.tum.de</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Kunst, Andreas" sort="Kunst, Andreas" uniqKey="Kunst A" first="Andreas" last="Kunst">Andreas Kunst</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Bannenberg, Thomas" sort="Bannenberg, Thomas" uniqKey="Bannenberg T" first="Thomas" last="Bannenberg">Thomas Bannenberg</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Herdtweck, Eberhardt" sort="Herdtweck, Eberhardt" uniqKey="Herdtweck E" first="Eberhardt" last="Herdtweck">Eberhardt Herdtweck</name>
<affiliation><mods:affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Sirsch, Peter" sort="Sirsch, Peter" uniqKey="Sirsch P" first="Peter" last="Sirsch">Peter Sirsch</name>
<affiliation><mods:affiliation>Institut für Physik, Universität Augsburg</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Elsevier, Cornelis J" sort="Elsevier, Cornelis J" uniqKey="Elsevier C" first="Cornelis J." last="Elsevier">Cornelis J. Elsevier</name>
<affiliation><mods:affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</mods:affiliation>
</affiliation>
</author>
<author><name sortKey="Ernsting, Jan M" sort="Ernsting, Jan M" uniqKey="Ernsting J" first="Jan M." last="Ernsting">Jan M. Ernsting</name>
<affiliation><mods:affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</mods:affiliation>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Angewandte Chemie International Edition</title>
<title level="j" type="abbrev">Angewandte Chemie International Edition</title>
<idno type="ISSN">1433-7851</idno>
<idno type="eISSN">1521-3773</idno>
<imprint><publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2004-10-18">2004-10-18</date>
<biblScope unit="volume">43</biblScope>
<biblScope unit="issue">41</biblScope>
<biblScope unit="page" from="5530">5530</biblScope>
<biblScope unit="page" to="5534">5534</biblScope>
</imprint>
<idno type="ISSN">1433-7851</idno>
</series>
<idno type="istex">F3F02EA42C57CE648A2400C5A12DA397722307A3</idno>
<idno type="DOI">10.1002/anie.200460538</idno>
<idno type="ArticleID">ANIE200460538</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1433-7851</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>cycloheptatrienyl ligands</term>
<term>cyclopentadienyl ligands</term>
<term>density functional calculations</term>
<term>sandwich complexes</term>
<term>titanium</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</div>
</front>
</TEI>
<istex><corpusName>wiley</corpusName>
<author><json:item><name>Matthias Tamm Prof. Dr.</name>
<affiliations><json:string>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</json:string>
<json:string>E-mail: matthias.tamm@ch.tum.de</json:string>
</affiliations>
</json:item>
<json:item><name>Andreas Kunst Dipl.‐Chem.</name>
<affiliations><json:string>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</json:string>
</affiliations>
</json:item>
<json:item><name>Thomas Bannenberg Dr.</name>
<affiliations><json:string>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</json:string>
</affiliations>
</json:item>
<json:item><name>Eberhardt Herdtweck Dr.</name>
<affiliations><json:string>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</json:string>
</affiliations>
</json:item>
<json:item><name>Peter Sirsch Dr.</name>
<affiliations><json:string>Institut für Physik, Universität Augsburg</json:string>
</affiliations>
</json:item>
<json:item><name>Cornelis J. Elsevier Prof. Dr.</name>
<affiliations><json:string>Institute for Molecular Chemistry, Universiteit van Amsterdam</json:string>
</affiliations>
</json:item>
<json:item><name>Jan M. Ernsting</name>
<affiliations><json:string>Institute for Molecular Chemistry, Universiteit van Amsterdam</json:string>
</affiliations>
</json:item>
</author>
<subject><json:item><lang><json:string>eng</json:string>
</lang>
<value>cycloheptatrienyl ligands</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>cyclopentadienyl ligands</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>density functional calculations</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>sandwich complexes</value>
</json:item>
<json:item><lang><json:string>eng</json:string>
</lang>
<value>titanium</value>
</json:item>
</subject>
<articleId><json:string>ANIE200460538</json:string>
</articleId>
<language><json:string>eng</json:string>
</language>
<abstract>Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</abstract>
<qualityIndicators><score>3.63</score>
<pdfVersion>1.2</pdfVersion>
<pdfPageSize>595 x 842 pts (A4)</pdfPageSize>
<refBibsNative>true</refBibsNative>
<keywordCount>5</keywordCount>
<abstractCharCount>431</abstractCharCount>
<pdfWordCount>2958</pdfWordCount>
<pdfCharCount>18443</pdfCharCount>
<pdfPageCount>5</pdfPageCount>
<abstractWordCount>56</abstractWordCount>
</qualityIndicators>
<title>Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
<genre.original><json:string>shortCommunication</json:string>
</genre.original>
<genre><json:string>brief-communication</json:string>
</genre>
<host><volume>43</volume>
<publisherId><json:string>ANIE</json:string>
</publisherId>
<pages><total>5</total>
<last>5534</last>
<first>5530</first>
</pages>
<issn><json:string>1433-7851</json:string>
</issn>
<issue>41</issue>
<subject><json:item><value>Communication</value>
</json:item>
</subject>
<genre><json:string>journal</json:string>
</genre>
<language><json:string>unknown</json:string>
</language>
<eissn><json:string>1521-3773</json:string>
</eissn>
<title>Angewandte Chemie International Edition</title>
<doi><json:string>10.1002/(ISSN)1521-3773</json:string>
</doi>
</host>
<publicationDate>2004</publicationDate>
<copyrightDate>2004</copyrightDate>
<doi><json:string>10.1002/anie.200460538</json:string>
</doi>
<id>F3F02EA42C57CE648A2400C5A12DA397722307A3</id>
<score>1</score>
<fulltext><json:item><original>true</original>
<mimetype>application/pdf</mimetype>
<extension>pdf</extension>
<uri>https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/pdf</uri>
</json:item>
<json:item><original>false</original>
<mimetype>application/zip</mimetype>
<extension>zip</extension>
<uri>https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/zip</uri>
</json:item>
<istex:fulltextTEI uri="https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
</titleStmt>
<publicationStmt><authority>ISTEX</authority>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<availability><p>WILEY</p>
</availability>
<date>2004</date>
</publicationStmt>
<notesStmt><note type="content">*This work has been supported by the Deutsche Forschungsgemeinschaft.</note>
</notesStmt>
<sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
<author><persName><forename type="first">Matthias</forename>
<surname>Tamm</surname>
</persName>
<roleName type="degree">Prof. Dr.</roleName>
<email>matthias.tamm@ch.tum.de</email>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
</author>
<author><persName><forename type="first">Andreas</forename>
<surname>Kunst</surname>
</persName>
<roleName type="degree">Dipl.‐Chem.</roleName>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
</author>
<author><persName><forename type="first">Thomas</forename>
<surname>Bannenberg</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
</author>
<author><persName><forename type="first">Eberhardt</forename>
<surname>Herdtweck</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
</author>
<author><persName><forename type="first">Peter</forename>
<surname>Sirsch</surname>
</persName>
<roleName type="degree">Dr.</roleName>
<affiliation>Institut für Physik, Universität Augsburg</affiliation>
</author>
<author><persName><forename type="first">Cornelis J.</forename>
<surname>Elsevier</surname>
</persName>
<roleName type="degree">Prof. Dr.</roleName>
<affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation>
</author>
<author><persName><forename type="first">Jan M.</forename>
<surname>Ernsting</surname>
</persName>
<affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation>
</author>
</analytic>
<monogr><title level="j">Angewandte Chemie International Edition</title>
<title level="j" type="abbrev">Angewandte Chemie International Edition</title>
<idno type="pISSN">1433-7851</idno>
<idno type="eISSN">1521-3773</idno>
<idno type="DOI">10.1002/(ISSN)1521-3773</idno>
<imprint><publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2004-10-18"></date>
<biblScope unit="volume">43</biblScope>
<biblScope unit="issue">41</biblScope>
<biblScope unit="page" from="5530">5530</biblScope>
<biblScope unit="page" to="5534">5534</biblScope>
</imprint>
</monogr>
<idno type="istex">F3F02EA42C57CE648A2400C5A12DA397722307A3</idno>
<idno type="DOI">10.1002/anie.200460538</idno>
<idno type="ArticleID">ANIE200460538</idno>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><creation><date>2004</date>
</creation>
<langUsage><language ident="en">en</language>
</langUsage>
<abstract xml:lang="en" style="graphical"><p>Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</p>
</abstract>
<textClass xml:lang="en"><keywords scheme="keyword"><list><head>keywords</head>
<item><term>cycloheptatrienyl ligands</term>
</item>
<item><term>cyclopentadienyl ligands</term>
</item>
<item><term>density functional calculations</term>
</item>
<item><term>sandwich complexes</term>
</item>
<item><term>titanium</term>
</item>
</list>
</keywords>
</textClass>
<textClass><keywords scheme="Journal Subject"><list><head>article-category</head>
<item><term>Communication</term>
</item>
</list>
</keywords>
</textClass>
</profileDesc>
<revisionDesc><change when="2004-05-02">Received</change>
<change when="2004-10-18">Published</change>
</revisionDesc>
</teiHeader>
</istex:fulltextTEI>
<json:item><original>false</original>
<mimetype>text/plain</mimetype>
<extension>txt</extension>
<uri>https://api.istex.fr/document/F3F02EA42C57CE648A2400C5A12DA397722307A3/fulltext/txt</uri>
</json:item>
</fulltext>
<metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration>
<istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName>
<publisherLoc>Weinheim</publisherLoc>
</publisherInfo>
<doi registered="yes">10.1002/(ISSN)1521-3773</doi>
<issn type="print">1433-7851</issn>
<issn type="electronic">1521-3773</issn>
<idGroup><id type="product" value="ANIE"></id>
</idGroup>
<titleGroup><title type="main" xml:lang="en" sort="ANGEWANDTE CHEMIE INTERNATIONAL EDITION">Angewandte Chemie International Edition</title>
<title type="short">Angewandte Chemie International Edition</title>
</titleGroup>
</publicationMeta>
<publicationMeta level="part" position="410"><doi origin="wiley" registered="yes">10.1002/anie.v43:41</doi>
<numberingGroup><numbering type="journalVolume" number="43">43</numbering>
<numbering type="journalIssue">41</numbering>
</numberingGroup>
<coverDate startDate="2004-10-18">October 18, 2004</coverDate>
</publicationMeta>
<publicationMeta level="unit" type="shortCommunication" position="30" status="forIssue"><doi origin="wiley" registered="yes">10.1002/anie.200460538</doi>
<idGroup><id type="unit" value="ANIE200460538"></id>
</idGroup>
<countGroup><count type="pageTotal" number="5"></count>
</countGroup>
<titleGroup><title type="articleCategory">Communication</title>
</titleGroup>
<copyright ownership="publisher">Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright>
<eventGroup><event type="manuscriptReceived" date="2004-05-02"></event>
<event type="firstOnline" date="2004-10-13"></event>
<event type="publishedOnlineFinalForm" date="2004-10-13"></event>
<event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText mathml2tex" date="2010-04-20"></event>
<event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-03"></event>
<event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event>
</eventGroup>
<numberingGroup><numbering type="pageFirst">5530</numbering>
<numbering type="pageLast">5534</numbering>
</numberingGroup>
<objectNameGroup><objectName elementName="figure">Scheme</objectName>
</objectNameGroup>
<linkGroup><link type="toTypesetVersion" href="file:ANIE.ANIE200460538.pdf"></link>
</linkGroup>
</publicationMeta>
<contentMeta><countGroup><count type="figureTotal" number="9"></count>
<count type="tableTotal" number="1"></count>
<count type="referenceTotal" number="44"></count>
</countGroup>
<titleGroup><title type="main" xml:lang="en"><i>Ansa</i>
‐Cycloheptatrienyl–Cyclopentadienyl Complexes<link href="#nss"></link>
</title>
</titleGroup>
<creators><creator xml:id="au1" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Matthias</givenNames>
<familyName>Tamm</familyName>
<degrees>Prof. Dr.</degrees>
</personName>
<contactDetails><email>matthias.tamm@ch.tum.de</email>
</contactDetails>
</creator>
<creator xml:id="au2" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Andreas</givenNames>
<familyName>Kunst</familyName>
<degrees>Dipl.‐Chem.</degrees>
</personName>
</creator>
<creator xml:id="au3" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Thomas</givenNames>
<familyName>Bannenberg</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
<creator xml:id="au4" creatorRole="author" affiliationRef="#aa"><personName><givenNames>Eberhardt</givenNames>
<familyName>Herdtweck</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
<creator xml:id="au5" creatorRole="author" affiliationRef="#ab"><personName><givenNames>Peter</givenNames>
<familyName>Sirsch</familyName>
<degrees>Dr.</degrees>
</personName>
</creator>
<creator xml:id="au6" creatorRole="author" affiliationRef="#ac"><personName><givenNames>Cornelis J.</givenNames>
<familyName>Elsevier</familyName>
<degrees>Prof. Dr.</degrees>
</personName>
</creator>
<creator xml:id="au7" creatorRole="author" affiliationRef="#ac"><personName><givenNames>Jan M.</givenNames>
<familyName>Ernsting</familyName>
</personName>
</creator>
</creators>
<affiliationGroup><affiliation xml:id="aa" countryCode="DE" type="organization"><unparsedAffiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</unparsedAffiliation>
</affiliation>
<affiliation xml:id="ab" countryCode="DE" type="organization"><unparsedAffiliation>Institut für Physik, Universität Augsburg</unparsedAffiliation>
</affiliation>
<affiliation xml:id="ac" countryCode="NL" type="organization"><unparsedAffiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</unparsedAffiliation>
</affiliation>
</affiliationGroup>
<keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">cycloheptatrienyl ligands</keyword>
<keyword xml:id="kwd2">cyclopentadienyl ligands</keyword>
<keyword xml:id="kwd3">density functional calculations</keyword>
<keyword xml:id="kwd4">sandwich complexes</keyword>
<keyword xml:id="kwd5">titanium</keyword>
</keywordGroup>
<supportingInformation><p>Supporting information for this article is available on the WWW under <url href="http://www.wiley-vch.de/contents/jc_2002/2004/z460538_s.pdf">http://www.wiley‐vch.de/contents/jc_2002/2004/z460538_s.pdf</url>
or from the author.</p>
</supportingInformation>
<abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Introduction of the Me</b>
<sub><b>2</b>
</sub>
<b>Si bridge</b>
and distortion of the sandwich structure facilitate the interaction of the 16‐electron <i>ansa‐</i>
complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first <i>ansa</i>
‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C<sub>7</sub>
H<sub>7</sub>
)Ti(η‐C<sub>5</sub>
H<sub>5</sub>
)].<blockFixed type="graphic"><mediaResourceGroup><mediaResource alt="image" eRights="yes" copyright="WILEY-VCH" href="urn:x-wiley:14337851:media:ANIE200460538:content"></mediaResource>
<mediaResource alt="thumbnail image" rendition="webLoRes" mimeType="image/gif" href=""></mediaResource>
<mediaResource alt="original image" rendition="webOriginal" mimeType="image/gif" href=""></mediaResource>
<mediaResource alt="magnified image" rendition="webHiRes" mimeType="image/gif" href=""></mediaResource>
</mediaResourceGroup>
</blockFixed>
</p>
</abstract>
</abstractGroup>
</contentMeta>
<noteGroup><note xml:id="nss"><p>This work has been supported by the Deutsche Forschungsgemeinschaft.</p>
</note>
</noteGroup>
</header>
</component>
</istex:document>
</istex:metadataXml>
<mods version="3.6"><titleInfo lang="en"><title>Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA" lang="en"><title>‐Cycloheptatrienyl–Cyclopentadienyl Complexes</title>
</titleInfo>
<name type="personal"><namePart type="given">Matthias</namePart>
<namePart type="family">Tamm</namePart>
<namePart type="termsOfAddress">Prof. Dr.</namePart>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
<affiliation>E-mail: matthias.tamm@ch.tum.de</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Andreas</namePart>
<namePart type="family">Kunst</namePart>
<namePart type="termsOfAddress">Dipl.‐Chem.</namePart>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Thomas</namePart>
<namePart type="family">Bannenberg</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Eberhardt</namePart>
<namePart type="family">Herdtweck</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Lehrstuhl für Anorganische Chemie, Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany, Fax: (+49) 89‐289‐13473</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Peter</namePart>
<namePart type="family">Sirsch</namePart>
<namePart type="termsOfAddress">Dr.</namePart>
<affiliation>Institut für Physik, Universität Augsburg</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Cornelis J.</namePart>
<namePart type="family">Elsevier</namePart>
<namePart type="termsOfAddress">Prof. Dr.</namePart>
<affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal"><namePart type="given">Jan M.</namePart>
<namePart type="family">Ernsting</namePart>
<affiliation>Institute for Molecular Chemistry, Universiteit van Amsterdam</affiliation>
<role><roleTerm type="text">author</roleTerm>
</role>
</name>
<typeOfResource>text</typeOfResource>
<genre type="brief-communication" displayLabel="shortCommunication"></genre>
<originInfo><publisher>WILEY‐VCH Verlag</publisher>
<place><placeTerm type="text">Weinheim</placeTerm>
</place>
<dateIssued encoding="w3cdtf">2004-10-18</dateIssued>
<dateCaptured encoding="w3cdtf">2004-05-02</dateCaptured>
<copyrightDate encoding="w3cdtf">2004</copyrightDate>
</originInfo>
<language><languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
</language>
<physicalDescription><internetMediaType>text/html</internetMediaType>
<extent unit="figures">9</extent>
<extent unit="tables">1</extent>
<extent unit="references">44</extent>
</physicalDescription>
<abstract type="graphical" lang="en">Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</abstract>
<note type="content">*This work has been supported by the Deutsche Forschungsgemeinschaft.</note>
<subject lang="en"><genre>keywords</genre>
<topic>cycloheptatrienyl ligands</topic>
<topic>cyclopentadienyl ligands</topic>
<topic>density functional calculations</topic>
<topic>sandwich complexes</topic>
<topic>titanium</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title>
</titleInfo>
<titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title>
</titleInfo>
<genre type="journal">journal</genre>
<note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2002/2004/z460538_s.pdf or from the author.</note>
<subject><genre>article-category</genre>
<topic>Communication</topic>
</subject>
<identifier type="ISSN">1433-7851</identifier>
<identifier type="eISSN">1521-3773</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3773</identifier>
<identifier type="PublisherID">ANIE</identifier>
<part><date>2004</date>
<detail type="volume"><caption>vol.</caption>
<number>43</number>
</detail>
<detail type="issue"><caption>no.</caption>
<number>41</number>
</detail>
<extent unit="pages"><start>5530</start>
<end>5534</end>
<total>5</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">F3F02EA42C57CE648A2400C5A12DA397722307A3</identifier>
<identifier type="DOI">10.1002/anie.200460538</identifier>
<identifier type="ArticleID">ANIE200460538</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition>
<recordInfo><recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag</recordOrigin>
</recordInfo>
</mods>
</metadata>
<serie></serie>
</istex>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Ticri/CIDE/explor/HapticV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002D15 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 002D15 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Ticri/CIDE |area= HapticV1 |flux= Istex |étape= Corpus |type= RBID |clé= ISTEX:F3F02EA42C57CE648A2400C5A12DA397722307A3 |texte= Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes }}
![]() | This area was generated with Dilib version V0.6.23. | ![]() |