Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Identifieur interne : 006E45 ( Main/Merge ); précédent : 006E44; suivant : 006E46Ansa‐Cycloheptatrienyl–Cyclopentadienyl Complexes
Auteurs : Matthias Tamm [Allemagne] ; Andreas Kunst ; Thomas Bannenberg ; Eberhardt Herdtweck ; Peter Sirsch ; Cornelis J. Elsevier ; Jan M. ErnstingSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2004-10-18.
English descriptors
- KwdEn :
Abstract
Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].
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DOI: 10.1002/anie.200460538
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<front><div type="abstract" xml:lang="en">Introduction of the Me2Si bridge and distortion of the sandwich structure facilitate the interaction of the 16‐electron ansa‐complex (see picture; blue Ti, yellow Si, gray C) with σ‐donor/π‐acceptor ligands, such as CO or isocyanides, which allows the electronic structure of this strongly bent first ansa‐cycloheptatrienyl–cyclopentadienyl transition‐metal complex to be studied. The complex is prepared from [(η‐C7H7)Ti(η‐C5H5)].</div>
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