catena-Poly[[[diaquathulium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]
Identifieur interne : 000467 ( Ncbi/Curation ); précédent : 000466; suivant : 000468catena-Poly[[[diaquathulium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]
Auteurs : Sheng Li [République populaire de Chine] ; Yue Chen [République populaire de Chine] ; Hong-Mei He [République populaire de Chine] ; Yuan-Fang Ma [République populaire de Chine]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.
Abstract
The title compound, {[Tm(C7H3NO4)(C7H4NO4)(H2O)2]·2H2O}
Url:
DOI: 10.1107/S1600536809008836
PubMed: 21582354
PubMed Central: 2968913
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PMC:2968913Le document en format XML
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-Poly[[[diaquathulium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]</title>
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-Poly[[[diaquathulium(III)]-μ-6-carboxynicotinato-μ-pyridine-2,5-dicarboxylato] dihydrate]</title>
<author><name sortKey="Li, Sheng" sort="Li, Sheng" uniqKey="Li S" first="Sheng" last="Li">Sheng Li</name>
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<front><div type="abstract" xml:lang="en"><p>The title compound, {[Tm(C<sub>7</sub>
H<sub>3</sub>
NO<sub>4</sub>
)(C<sub>7</sub>
H<sub>4</sub>
NO<sub>4</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]·2H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, is isotypic with the analogous Tb<sup>III</sup>
compound [Li <italic>et al.</italic>
(2009<xref ref-type="bibr" rid="bb5"> ▶</xref>
). <italic>Acta Cryst</italic>
. E<bold>65</bold>
, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.</p>
</div>
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