Bis[tris(3-tert-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
Identifieur interne : 000468 ( Ncbi/Curation ); précédent : 000467; suivant : 000469Bis[tris(3-tert-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate
Auteurs : Kuburat O. Saliu [Canada] ; Josef Takats [Canada] ; Michael J. Ferguson [Canada]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.
Abstract
In the title compound, [Yb(C24H40BN6)2]·C7H8, the Yb atom is coordinated by two tris(3-
Url:
DOI: 10.1107/S1600536809017152
PubMed: 21583010
PubMed Central: 2969540
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-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate</title>
<author><name sortKey="Saliu, Kuburat O" sort="Saliu, Kuburat O" uniqKey="Saliu K" first="Kuburat O." last="Saliu">Kuburat O. Saliu</name>
<affiliation wicri:level="1"><nlm:aff id="a">Department of Chemistry, University of Alberta, Edmonton, Alberta,<country>Canada</country>
T6G 2G2</nlm:aff>
<country xml:lang="fr">Canada</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<author><name sortKey="Takats, Josef" sort="Takats, Josef" uniqKey="Takats J" first="Josef" last="Takats">Josef Takats</name>
<affiliation wicri:level="1"><nlm:aff id="a">Department of Chemistry, University of Alberta, Edmonton, Alberta,<country>Canada</country>
T6G 2G2</nlm:aff>
<country xml:lang="fr">Canada</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Ferguson, Michael J" sort="Ferguson, Michael J" uniqKey="Ferguson M" first="Michael J." last="Ferguson">Michael J. Ferguson</name>
<affiliation wicri:level="1"><nlm:aff id="b">X-ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta,<country>Canada</country>
T6G 2G2</nlm:aff>
<country xml:lang="fr">Canada</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis[tris(3-<italic>tert</italic>
-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate</title>
<author><name sortKey="Saliu, Kuburat O" sort="Saliu, Kuburat O" uniqKey="Saliu K" first="Kuburat O." last="Saliu">Kuburat O. Saliu</name>
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T6G 2G2</nlm:aff>
<country xml:lang="fr">Canada</country>
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<author><name sortKey="Takats, Josef" sort="Takats, Josef" uniqKey="Takats J" first="Josef" last="Takats">Josef Takats</name>
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T6G 2G2</nlm:aff>
<country xml:lang="fr">Canada</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Ferguson, Michael J" sort="Ferguson, Michael J" uniqKey="Ferguson M" first="Michael J." last="Ferguson">Michael J. Ferguson</name>
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T6G 2G2</nlm:aff>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, [Yb(C<sub>24</sub>
H<sub>40</sub>
BN<sub>6</sub>
)<sub>2</sub>
]·C<sub>7</sub>
H<sub>8</sub>
, the Yb atom is coordinated by two tris(3-<italic>tert</italic>
-butyl-5-methylpyrazol-1-yl)hydridoborate [Tp<sup><italic>t</italic>
Bu,Me</sup>
] ligands. One ligand binds in the κ<sup>3</sup>
mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of the pyrazolyl rings and the H atom attached to the central B <italic>via</italic>
an agostic-type interaction through the B—H group of the second Tp<sup><italic>t</italic>
Bu,Me</sup>
ligand, giving an overall distorted octahedral geometry. One of the <italic>tert</italic>
-butyl groups is disordered over two sites, with occupancies of 0.65 and 0.35.</p>
</div>
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