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catena-Poly[[[diaqua­thulium(III)]-μ-6-carboxy­nicotinato-μ-pyridine-2,5-di­carboxyl­ato] dihydrate]

Identifieur interne : 000467 ( Ncbi/Merge ); précédent : 000466; suivant : 000468

catena-Poly[[[diaqua­thulium(III)]-μ-6-carboxy­nicotinato-μ-pyridine-2,5-di­carboxyl­ato] dihydrate]

Auteurs : Sheng Li [République populaire de Chine] ; Yue Chen [République populaire de Chine] ; Hong-Mei He [République populaire de Chine] ; Yuan-Fang Ma [République populaire de Chine]

Source :

RBID : PMC:2968913

Abstract

The title compound, {[Tm(C7H3NO4)(C7H4NO4)(H2O)2]·2H2O}n, is isotypic with the analogous TbIII compound [Li et al. (2009). Acta Cryst. E65, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.


Url:
DOI: 10.1107/S1600536809008836
PubMed: 21582354
PubMed Central: 2968913

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PMC:2968913

Le document en format XML

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-Poly[[[diaqua­thulium(III)]-μ-6-carboxy­nicotinato-μ-pyridine-2,5-di­carboxyl­ato] dihydrate]</title>
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-Poly[[[diaqua­thulium(III)]-μ-6-carboxy­nicotinato-μ-pyridine-2,5-di­carboxyl­ato] dihydrate]</title>
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<p>The title compound, {[Tm(C
<sub>7</sub>
H
<sub>3</sub>
NO
<sub>4</sub>
)(C
<sub>7</sub>
H
<sub>4</sub>
NO
<sub>4</sub>
)(H
<sub>2</sub>
O)
<sub>2</sub>
]·2H
<sub>2</sub>
O}
<sub>
<italic>n</italic>
</sub>
, is isotypic with the analogous Tb
<sup>III</sup>
compound [Li
<italic>et al.</italic>
(2009
<xref ref-type="bibr" rid="bb5"></xref>
).
<italic>Acta Cryst</italic>
. E
<bold>65</bold>
, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.</p>
</div>
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-Poly[[[diaqua­thulium(III)]-μ-6-carboxy­nicotinato-μ-pyridine-2,5-di­carboxyl­ato] dihydrate]</title>
<author>
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<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
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<country>People’s Republic of China</country>
</nlm:aff>
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</nlm:aff>
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<p>The title compound, {[Tm(C
<sub>7</sub>
H
<sub>3</sub>
NO
<sub>4</sub>
)(C
<sub>7</sub>
H
<sub>4</sub>
NO
<sub>4</sub>
)(H
<sub>2</sub>
O)
<sub>2</sub>
]·2H
<sub>2</sub>
O}
<sub>
<italic>n</italic>
</sub>
, is isotypic with the analogous Tb
<sup>III</sup>
compound [Li
<italic>et al.</italic>
(2009
<xref ref-type="bibr" rid="bb5"></xref>
).
<italic>Acta Cryst</italic>
. E
<bold>65</bold>
, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.</p>
</div>
</front>
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<name sortKey="Li, Sheng" sort="Li, Sheng" uniqKey="Li S" first="Sheng" last="Li">Sheng Li</name>
</author>
<author>
<name sortKey="Chen, Yue" sort="Chen, Yue" uniqKey="Chen Y" first="Yue" last="Chen">Yue Chen</name>
</author>
<author>
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</author>
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<name sortKey="Li, Sheng" sort="Li, Sheng" uniqKey="Li S" first="Sheng" last="Li">Sheng Li</name>
</author>
<author>
<name sortKey="Chen, Yue" sort="Chen, Yue" uniqKey="Chen Y" first="Yue" last="Chen">Yue Chen</name>
</author>
<author>
<name sortKey="He, Hong Mei" sort="He, Hong Mei" uniqKey="He H" first="Hong-Mei" last="He">Hong-Mei He</name>
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<div type="abstract" xml:lang="en">The title compound, {[Tm(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(2)]·2H(2)O}(n), is isotypic with the analogous Tb(III) compound [Li et al. (2009 ▶). Acta Cryst. E65, m410]. All interatomic distances and angles and the hydrogen-bond geometries are very similar for the two structures. The refined Flack parameter of 0.49 (2) suggests inversion twinning.</div>
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