A reinvestigation of the ScIn system and related (Tm,Lu)In compounds
Identifieur interne : 002C46 ( Main/Exploration ); précédent : 002C45; suivant : 002C47A reinvestigation of the ScIn system and related (Tm,Lu)In compounds
Auteurs : A. Palenzona [Italie] ; P. Manfrinetti [Italie] ; R. Palenzona [Italie]Source :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1996.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Alliage.
English descriptors
- KwdEn :
- Teeft :
Abstract
Abstract: The phase diagram of the ScIn system has been revised in the range 30 to 100 at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type). Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu8In4 (Ti5Ga4-type). LuIn (AuCu-type), Tm3In4 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.
Url:
DOI: 10.1016/S0925-8388(96)02402-4
Affiliations:
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Le document en format XML
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<term>Indium</term>
<term>Lutetium</term>
<term>Phase diagrams</term>
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<front><div type="abstract" xml:lang="en">Abstract: The phase diagram of the ScIn system has been revised in the range 30 to 100 at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type). Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu8In4 (Ti5Ga4-type). LuIn (AuCu-type), Tm3In4 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.</div>
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