A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds
Identifieur interne : 003029 ( Main/Merge ); précédent : 003028; suivant : 003030A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds
Auteurs : A. Palenzona [Italie] ; P. Manfrinetti [Italie] ; R. Palenzona [Italie]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 1996.
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- Pascal (Inist)
English descriptors
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Abstract
Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type), Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu5In4 (Ti5Ga4-type), LuIn (AuCu-type), Tm3In5 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.
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<series><title level="j" type="main">Journal of alloys and compounds</title>
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<term>Lutetium</term>
<term>Phase diagrams</term>
<term>Phase equilibria</term>
<term>Space groups</term>
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<term>Thulium</term>
<term>XRD</term>
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<term>Diagramme phase</term>
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<term>Indium</term>
<term>Système ternaire</term>
<term>XRD</term>
<term>ATD</term>
<term>Groupe espace</term>
<term>Structure cristalline</term>
<term>Etude expérimentale</term>
<term>Système In Sc</term>
<term>Système In Lu Tm</term>
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<front><div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn<sub>3</sub>
(AuCu<sub>3</sub>
-type), Sc<sub>2</sub>
In (Ni<sub>2</sub>
In-type) and Sc<sub>3</sub>
In (Ni<sub>3</sub>
Sn-type), while Sc<sub>3</sub>
In<sub>5</sub>
and Sc<sub>5</sub>
In<sub>3</sub>
should be replaced by ScIn<sub>2</sub>
(ZrGa<sub>2</sub>
-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm<sub>5</sub>
In<sub>4</sub>
and Lu<sub>5</sub>
In<sub>4</sub>
(Ti<sub>5</sub>
Ga<sub>4</sub>
-type), LuIn (AuCu-type), Tm<sub>3</sub>
In<sub>5</sub>
and Lu<sub>3</sub>
In<sub>5</sub>
(Tm<sub>3</sub>
Ga<sub>5</sub>
-type) and LuIn<sub>2</sub>
(ZrGa<sub>2</sub>
-type), previously unknown, have also been prepared and characterized for comparison.</div>
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<affiliations><list><country><li>Italie</li>
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<tree><country name="Italie"><noRegion><name sortKey="Palenzona, A" sort="Palenzona, A" uniqKey="Palenzona A" first="A." last="Palenzona">A. Palenzona</name>
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