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A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds

Identifieur interne : 001390 ( Pascal/Curation ); précédent : 001389; suivant : 001391

A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds

Auteurs : A. Palenzona [Italie] ; P. Manfrinetti [Italie] ; R. Palenzona [Italie]

Source :

RBID : Pascal:97-0284420

Descripteurs français

English descriptors

Abstract

Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type), Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu5In4 (Ti5Ga4-type), LuIn (AuCu-type), Tm3In5 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.
pA  
A01 01  1    @0 0925-8388
A03   1    @0 J. alloys compd.
A05       @2 243
A06       @2 1-2
A08 01  1  ENG  @1 A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds
A11 01  1    @1 PALENZONA (A.)
A11 02  1    @1 MANFRINETTI (P.)
A11 03  1    @1 PALENZONA (R.)
A14 01      @1 Department of Chemistry, University of Genova, Via Dodecaneso 31 @2 I-16146 Genova @3 ITA @Z 1 aut. @Z 2 aut. @Z 3 aut.
A20       @1 182-185
A21       @1 1996
A23 01      @0 ENG
A24 01      @0 eng
A43 01      @1 INIST @2 1151 @5 354000060920850068
A44       @0 9000 @1 © 1997 Elsevier Science B.V. All rights reserved.
A47 01  1    @0 97-0284420
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of alloys and compounds
A66 01      @0 CHE
C01 01    ENG  @0 Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type), Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu5In4 (Ti5Ga4-type), LuIn (AuCu-type), Tm3In5 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.
C02 01  3    @0 001B80A30B
C02 02  X    @0 240
C03 01  3  FRE  @0 Système binaire @5 01
C03 01  3  ENG  @0 Binary systems @5 01
C03 02  3  FRE  @0 Diagramme phase @5 02
C03 02  3  ENG  @0 Phase diagrams @5 02
C03 03  3  FRE  @0 Equilibre phase @5 03
C03 03  3  ENG  @0 Phase equilibria @5 03
C03 04  3  FRE  @0 Thulium @2 NC @5 04
C03 04  3  ENG  @0 Thulium @2 NC @5 04
C03 05  3  FRE  @0 Lutétium @2 NC @5 05
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C03 06  3  FRE  @0 Indium @2 NC @5 06
C03 06  3  ENG  @0 Indium @2 NC @5 06
C03 07  3  FRE  @0 Système ternaire @5 07
C03 07  3  ENG  @0 Ternary systems @5 07
C03 08  3  FRE  @0 XRD @5 08
C03 08  3  ENG  @0 XRD @5 08
C03 09  3  FRE  @0 ATD @5 09
C03 09  3  ENG  @0 DTA @5 09
C03 10  3  FRE  @0 Groupe espace @5 10
C03 10  3  ENG  @0 Space groups @5 10
C03 11  3  FRE  @0 Structure cristalline @5 23
C03 11  3  ENG  @0 Crystal structure @5 23
C03 12  3  FRE  @0 Etude expérimentale @5 24
C03 12  3  ENG  @0 Experimental study @5 24
C03 13  3  FRE  @0 Système In Sc @2 NK @4 INC @5 32
C03 14  3  FRE  @0 Système In Lu Tm @2 NK @4 INC @5 33
C03 15  3  FRE  @0 8130B @2 PAC @4 INC @5 95
N21       @1 160

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<div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn
<sub>3</sub>
(AuCu
<sub>3</sub>
-type), Sc
<sub>2</sub>
In (Ni
<sub>2</sub>
In-type) and Sc
<sub>3</sub>
In (Ni
<sub>3</sub>
Sn-type), while Sc
<sub>3</sub>
In
<sub>5</sub>
and Sc
<sub>5</sub>
In
<sub>3</sub>
should be replaced by ScIn
<sub>2</sub>
(ZrGa
<sub>2</sub>
-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm
<sub>5</sub>
In
<sub>4</sub>
and Lu
<sub>5</sub>
In
<sub>4</sub>
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<sub>5</sub>
Ga
<sub>4</sub>
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<sub>3</sub>
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<sub>5</sub>
(Tm
<sub>3</sub>
Ga
<sub>5</sub>
-type) and LuIn
<sub>2</sub>
(ZrGa
<sub>2</sub>
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<sub>3</sub>
(AuCu
<sub>3</sub>
-type), Sc
<sub>2</sub>
In (Ni
<sub>2</sub>
In-type) and Sc
<sub>3</sub>
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<sub>5</sub>
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<sub>5</sub>
In
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<sub>2</sub>
(ZrGa
<sub>2</sub>
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<sub>5</sub>
In
<sub>4</sub>
and Lu
<sub>5</sub>
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<sub>5</sub>
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<sub>3</sub>
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