A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds
Identifieur interne : 001390 ( Pascal/Curation ); précédent : 001389; suivant : 001391A reinvestigation of the Sc-In system and related (Tm,Lu)-In compounds
Auteurs : A. Palenzona [Italie] ; P. Manfrinetti [Italie] ; R. Palenzona [Italie]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 1996.
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- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn3 (AuCu3-type), Sc2In (Ni2In-type) and Sc3In (Ni3Sn-type), while Sc3In5 and Sc5In3 should be replaced by ScIn2 (ZrGa2-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm5In4 and Lu5In4 (Ti5Ga4-type), LuIn (AuCu-type), Tm3In5 and Lu3In5 (Tm3Ga5-type) and LuIn2 (ZrGa2-type), previously unknown, have also been prepared and characterized for comparison.
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<front><div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn<sub>3</sub>
(AuCu<sub>3</sub>
-type), Sc<sub>2</sub>
In (Ni<sub>2</sub>
In-type) and Sc<sub>3</sub>
In (Ni<sub>3</sub>
Sn-type), while Sc<sub>3</sub>
In<sub>5</sub>
and Sc<sub>5</sub>
In<sub>3</sub>
should be replaced by ScIn<sub>2</sub>
(ZrGa<sub>2</sub>
-type) and ScIn respectively. The latter shows, however, a rather complex behaviour, assuming the CsCl- or AuCu-type structure, depending on composition. Tm<sub>5</sub>
In<sub>4</sub>
and Lu<sub>5</sub>
In<sub>4</sub>
(Ti<sub>5</sub>
Ga<sub>4</sub>
-type), LuIn (AuCu-type), Tm<sub>3</sub>
In<sub>5</sub>
and Lu<sub>3</sub>
In<sub>5</sub>
(Tm<sub>3</sub>
Ga<sub>5</sub>
-type) and LuIn<sub>2</sub>
(ZrGa<sub>2</sub>
-type), previously unknown, have also been prepared and characterized for comparison.</div>
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<fC01 i1="01" l="ENG"><s0>Copyright (c) 1997 Elsevier Science S.A. All rights reserved. The phase diagram of the Sc-In system has been revised in the range 30 to 100at.% In using differential thermal analysis, metallographic analysis, X-ray diffraction and electron microscopy. Six intermediate phases have been found. Three of them have been confirmed: ScIn<sub>3</sub>
(AuCu<sub>3</sub>
-type), Sc<sub>2</sub>
In (Ni<sub>2</sub>
In-type) and Sc<sub>3</sub>
In (Ni<sub>3</sub>
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and Sc<sub>5</sub>
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and Lu<sub>5</sub>
In<sub>4</sub>
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