Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Identifieur interne : 001162 ( Main/Exploration ); précédent : 001161; suivant : 001163Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Auteurs : E. P. Levanova [Russie] ; V. A. Grabel Ykh [Russie] ; N. V. Russavskaya [Russie] ; L. V. Klyba [Russie] ; E. R. Zhanchipova [Russie] ; A. I. Albanov [Russie] ; O. A. Tarasova [Russie] ; N. A. Korchevin [Russie]Source :
- Russian Journal of General Chemistry [ 1070-3632 ] ; 2009-06-01.
Abstract
Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.
Url:
DOI: 10.1134/S1070363209060103
Affiliations:
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<front><div type="abstract" xml:lang="en">Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</div>
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