Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Identifieur interne : 000B70 ( Istex/Corpus ); précédent : 000B69; suivant : 000B71Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Auteurs : E. P. Levanova ; V. A. Grabel Ykh ; N. V. Russavskaya ; L. V. Klyba ; E. R. Zhanchipova ; A. I. Albanov ; O. A. Tarasova ; N. A. KorchevinSource :
- Russian Journal of General Chemistry [ 1070-3632 ] ; 2009-06-01.
Abstract
Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.
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DOI: 10.1134/S1070363209060103
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P. Levanova</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: venk@irioch.irk.ru</mods:affiliation></affiliation></author><author><name sortKey="Grabel Ykh, V A" sort="Grabel Ykh, V A" uniqKey="Grabel Ykh V" first="V. A." last="Grabel Ykh">V. A. Grabel Ykh</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Russavskaya, N V" sort="Russavskaya, N V" uniqKey="Russavskaya N" first="N. V." last="Russavskaya">N. V. Russavskaya</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Klyba, L V" sort="Klyba, L V" uniqKey="Klyba L" first="L. V." last="Klyba">L. V. Klyba</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Zhanchipova, E R" sort="Zhanchipova, E R" uniqKey="Zhanchipova E" first="E. R." last="Zhanchipova">E. R. Zhanchipova</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Albanov, A I" sort="Albanov, A I" uniqKey="Albanov A" first="A. I." last="Albanov">A. I. Albanov</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Tarasova, O A" sort="Tarasova, O A" uniqKey="Tarasova O" first="O. A." last="Tarasova">O. A. Tarasova</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author><author><name sortKey="Korchevin, N A" sort="Korchevin, N A" uniqKey="Korchevin N" first="N. A." last="Korchevin">N. A. Korchevin</name><affiliation><mods:affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Russian Journal of General Chemistry</title><title level="j" type="abbrev">Russ J Gen Chem</title><idno type="ISSN">1070-3632</idno><idno type="eISSN">1608-3350</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2009-06-01">2009-06-01</date><biblScope unit="volume">79</biblScope><biblScope unit="issue">6</biblScope><biblScope unit="page" from="1097">1097</biblScope><biblScope unit="page" to="1101">1101</biblScope></imprint><idno type="ISSN">1070-3632</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1070-3632</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</div></front></TEI><istex><corpusName>springer-journals</corpusName><author><json:item><name>E. P. Levanova</name><affiliations><json:string>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</json:string><json:string>E-mail: venk@irioch.irk.ru</json:string></affiliations></json:item><json:item><name>V. A. Grabel’nykh</name><affiliations><json:string>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</json:string></affiliations></json:item><json:item><name>N. V. Russavskaya</name><affiliations><json:string>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. 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Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</abstract><qualityIndicators><score>5.342</score><pdfWordCount>2754</pdfWordCount><pdfCharCount>16445</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>5</pdfPageCount><pdfPageSize>612 x 792 pts (letter)</pdfPageSize><refBibsNative>false</refBibsNative><abstractWordCount>49</abstractWordCount><abstractCharCount>373</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH</title><genre><json:string>research-article</json:string></genre><host><title>Russian Journal of General Chemistry</title><language><json:string>unknown</json:string></language><publicationDate>2009</publicationDate><copyrightDate>2009</copyrightDate><issn><json:string>1070-3632</json:string></issn><eissn><json:string>1608-3350</json:string></eissn><journalId><json:string>11176</json:string></journalId><volume>79</volume><issue>6</issue><pages><first>1097</first><last>1101</last></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Chemistry/Food Science, general</value></json:item></subject></host><ark><json:string>ark:/67375/VQC-G1HJV8MF-V</json:string></ark><publicationDate>2009</publicationDate><copyrightDate>2009</copyrightDate><doi><json:string>10.1134/S1070363209060103</json:string></doi><id>5EAD20939ED16BB9EA3BA728E079EB0BEEFF7B40</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-G1HJV8MF-V/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-G1HJV8MF-V/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/VQC-G1HJV8MF-V/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher scheme="https://scientific-publisher.data.istex.fr">SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><availability><licence><p>Pleiades Publishing, Ltd., 2009</p></licence><p scheme="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</p></availability><date>2008-12-08</date></publicationStmt><notesStmt><note type="research-article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</note><note type="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH</title><author xml:id="author-0000" corresp="yes"><persName><forename type="first">E.</forename><surname>Levanova</surname></persName><email>venk@irioch.irk.ru</email><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. 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Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>Chemistry</head><item><term>Chemistry/Food Science, general</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2008-12-08">Created</change><change when="2009-06-01">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-G1HJV8MF-V/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="corpus springer-journals not found" wicri:toSee="no header"><istex:xmlDeclaration>version="1.0" encoding="UTF-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//Springer-Verlag//DTD A++ V2.4//EN" URI="http://devel.springer.de/A++/V2.4/DTD/A++V2.4.dtd" 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hydrate-KOH</ArticleTitle><ArticleFirstPage>1097</ArticleFirstPage><ArticleLastPage>1101</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2009</Year><Month>7</Month><Day>16</Day></RegistrationDate><Received><Year>2008</Year><Month>12</Month><Day>8</Day></Received><OnlineDate><Year>2009</Year><Month>8</Month><Day>11</Day></OnlineDate></ArticleHistory><ArticleCopyright><CopyrightHolderName>Pleiades Publishing, Ltd.</CopyrightHolderName><CopyrightYear>2009</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant Grant="Restricted"></ESMGrant></ArticleGrants></ArticleInfo><ArticleHeader><AuthorGroup><Author AffiliationIDS="Aff1" CorrespondingAffiliationID="Aff1"><AuthorName DisplayOrder="Western"><GivenName>E.</GivenName><GivenName>P.</GivenName><FamilyName>Levanova</FamilyName></AuthorName><Contact><Email>venk@irioch.irk.ru</Email></Contact></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>V.</GivenName><GivenName>A.</GivenName><FamilyName>Grabel’nykh</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>N.</GivenName><GivenName>V.</GivenName><FamilyName>Russavskaya</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>L.</GivenName><GivenName>V.</GivenName><FamilyName>Klyba</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>E.</GivenName><GivenName>R.</GivenName><FamilyName>Zhanchipova</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>A.</GivenName><GivenName>I.</GivenName><FamilyName>Albanov</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>O.</GivenName><GivenName>A.</GivenName><FamilyName>Tarasova</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>N.</GivenName><GivenName>A.</GivenName><FamilyName>Korchevin</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgDivision>Favorskii Irkutsk Institute of Chemistry, Siberian Branch</OrgDivision><OrgName>Russian Academy of Sciences</OrgName><OrgAddress><Street>ul. Favorskogo 1</Street><City>Irkutsk</City><Postcode>664033</Postcode><Country Code="RU">Russia</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Abstract</Heading><Para TextBreak="No">2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K<Subscript>2</Subscript>S<Subscript>2</Subscript> or K<Subscript>2</Subscript>S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</Para></Abstract><ArticleNote Type="Misc"><SimplePara>Original Russian Text © E.P. Levanova, V.A. Grabel’nykh, N.V. Russavskaya, L.V. Klyba, E.R. Zhanchipova, A.I. Albanov, O.A. Tarasova, N.A. Korchevin, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 6, pp. 925–929.</SimplePara></ArticleNote></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH</title></titleInfo><name type="personal" displayLabel="corresp"><namePart type="given">E.</namePart><namePart type="given">P.</namePart><namePart type="family">Levanova</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><affiliation>E-mail: venk@irioch.irk.ru</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">V.</namePart><namePart type="given">A.</namePart><namePart type="family">Grabel’nykh</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">N.</namePart><namePart type="given">V.</namePart><namePart type="family">Russavskaya</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">L.</namePart><namePart type="given">V.</namePart><namePart type="family">Klyba</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">E.</namePart><namePart type="given">R.</namePart><namePart type="family">Zhanchipova</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.</namePart><namePart type="given">I.</namePart><namePart type="family">Albanov</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">O.</namePart><namePart type="given">A.</namePart><namePart type="family">Tarasova</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">N.</namePart><namePart type="given">A.</namePart><namePart type="family">Korchevin</namePart><affiliation>Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>SP MAIK Nauka/Interperiodica</publisher><place><placeTerm type="text">Dordrecht</placeTerm></place><dateCreated encoding="w3cdtf">2008-12-08</dateCreated><dateIssued encoding="w3cdtf">2009-06-01</dateIssued><copyrightDate encoding="w3cdtf">2009</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract lang="en">Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</abstract><relatedItem type="host"><titleInfo><title>Russian Journal of General Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Russ J Gen Chem</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>Springer</publisher><dateIssued encoding="w3cdtf">2009-07-24</dateIssued><copyrightDate encoding="w3cdtf">2009</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Chemistry/Food Science, general</topic></subject><identifier type="ISSN">1070-3632</identifier><identifier type="eISSN">1608-3350</identifier><identifier type="JournalID">11176</identifier><identifier type="IssueArticleCount">54</identifier><identifier type="VolumeIssueCount">12</identifier><part><date>2009</date><detail type="volume"><number>79</number><caption>vol.</caption></detail><detail type="issue"><number>6</number><caption>no.</caption></detail><extent unit="pages"><start>1097</start><end>1101</end></extent></part><recordInfo><recordOrigin>Pleiades Publishing, Ltd., 2009</recordOrigin></recordInfo></relatedItem><identifier type="istex">5EAD20939ED16BB9EA3BA728E079EB0BEEFF7B40</identifier><identifier type="ark">ark:/67375/VQC-G1HJV8MF-V</identifier><identifier type="DOI">10.1134/S1070363209060103</identifier><identifier type="ArticleID">6010</identifier><identifier type="ArticleID">S1070363209060103</identifier><accessCondition type="use and reproduction" contentType="copyright">Pleiades Publishing, Ltd., 2009</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</recordContentSource><recordOrigin>Pleiades Publishing, Ltd., 2009</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-G1HJV8MF-V/record.json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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