Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Identifieur interne : 000280 ( Istex/Checkpoint ); précédent : 000279; suivant : 000281Reactions of 2,3-dichloro-1-propene with sulfur and tellurium in the system hydrazine hydrate-KOH
Auteurs : E. P. Levanova [Russie] ; V. A. Grabel Ykh [Russie] ; N. V. Russavskaya [Russie] ; L. V. Klyba [Russie] ; E. R. Zhanchipova [Russie] ; A. I. Albanov [Russie] ; O. A. Tarasova [Russie] ; N. A. Korchevin [Russie]Source :
- Russian Journal of General Chemistry [ 1070-3632 ] ; 2009-06-01.
Abstract
Abstract: 2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.
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DOI: 10.1134/S1070363209060103
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Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal.</div></front></TEI><affiliations><list><country><li>Russie</li></country></list><tree><country name="Russie"><noRegion><name sortKey="Levanova, E P" sort="Levanova, E P" uniqKey="Levanova E" first="E. P." last="Levanova">E. P. Levanova</name></noRegion><name sortKey="Albanov, A I" sort="Albanov, A I" uniqKey="Albanov A" first="A. I." last="Albanov">A. I. Albanov</name><name sortKey="Grabel Ykh, V A" sort="Grabel Ykh, V A" uniqKey="Grabel Ykh V" first="V. A." last="Grabel Ykh">V. A. Grabel Ykh</name><name sortKey="Klyba, L V" sort="Klyba, L V" uniqKey="Klyba L" first="L. V." last="Klyba">L. V. Klyba</name><name sortKey="Korchevin, N A" sort="Korchevin, N A" uniqKey="Korchevin N" first="N. A." last="Korchevin">N. A. Korchevin</name><name sortKey="Levanova, E P" sort="Levanova, E P" uniqKey="Levanova E" first="E. P." last="Levanova">E. P. Levanova</name><name sortKey="Russavskaya, N V" sort="Russavskaya, N V" uniqKey="Russavskaya N" first="N. V." last="Russavskaya">N. V. Russavskaya</name><name sortKey="Tarasova, O A" sort="Tarasova, O A" uniqKey="Tarasova O" first="O. A." last="Tarasova">O. A. Tarasova</name><name sortKey="Zhanchipova, E R" sort="Zhanchipova, E R" uniqKey="Zhanchipova E" first="E. R." last="Zhanchipova">E. R. Zhanchipova</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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