Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/
Identifieur interne : 006266 ( Main/Exploration ); précédent : 006265; suivant : 006267Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/
Auteurs : Alberto Albinati [Italie] ; Valeria Filippi [Italie] ; Piero Leoni [Italie] ; Lorella Marchetti [Italie] ; Marco Pasquali [Italie] ; Vincenzo Passarelli [Italie]Source :
- Chemical Communications [ 1359-7345 ] ; 2005.
Abstract
The reductive coupling of the bridging phosphide and the adjacent σ-alkynyl moieties in [Pt2(μ-PtBu2){μ,η1:η2-C(Ph)CH2}(CC–Ph)(CO)(PtBu2H)(Br)] is promoted by bromide abstraction and is reversed by adding NnBu4Br.
Url:
DOI: 10.1039/b418893d
Affiliations:
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<front><div type="abstract">The reductive coupling of the bridging phosphide and the adjacent σ-alkynyl moieties in [Pt2(μ-PtBu2){μ,η1:η2-C(Ph)CH2}(CC–Ph)(CO)(PtBu2H)(Br)] is promoted by bromide abstraction and is reversed by adding NnBu4Br.</div>
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<name sortKey="Filippi, Valeria" sort="Filippi, Valeria" uniqKey="Filippi V" first="Valeria" last="Filippi">Valeria Filippi</name>
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<name sortKey="Leoni, Piero" sort="Leoni, Piero" uniqKey="Leoni P" first="Piero" last="Leoni">Piero Leoni</name>
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