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Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/

Identifieur interne : 006606 ( Main/Merge ); précédent : 006605; suivant : 006607

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/

Auteurs : Alberto Albinati [Italie] ; Valeria Filippi [Italie] ; Piero Leoni [Italie] ; Lorella Marchetti [Italie] ; Marco Pasquali [Italie] ; Vincenzo Passarelli [Italie]

Source :

Chemical Communications [ 1359-7345 ] ; 2005.

RBID : ISTEX:1B84DA87E1A53A20A7DE8E4F70288A55B2C768D8

Abstract

The reductive coupling of the bridging phosphide and the adjacent σ-alkynyl moieties in [Pt2(μ-PtBu2){μ,η1:η2-C(Ph)CH2}(CC–Ph)(CO)(PtBu2H)(Br)] is promoted by bromide abstraction and is reversed by adding NnBu4Br.

Url:

https://api.istex.fr/document/1B84DA87E1A53A20A7DE8E4F70288A55B2C768D8/fulltext/pdf

DOI: 10.1039/b418893d

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ISTEX:1B84DA87E1A53A20A7DE8E4F70288A55B2C768D8

Le document en format XML

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<front><div type="abstract">The reductive coupling of the bridging phosphide and the adjacent σ-alkynyl moieties in [Pt2(μ-PtBu2){μ,η1:η2-C(Ph)CH2}(CC–Ph)(CO)(PtBu2H)(Br)] is promoted by bromide abstraction and is reversed by adding NnBu4Br.</div>
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Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum frameworkElectronic supplementary information (ESI) available: NMR data. See http://www.rsc.org/suppdata/cc/b4/b418893d/

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Abstract

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