ThuliumV1, Pmc, Curation, bibRecord, 000351

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Identifieur interne : 000351 ( Pmc/Curation ); précédent : 000350; suivant : 000352

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Auteurs : Zhu-Qing Gao [République populaire de Chine] ; Dong-Yu Lv [République populaire de Chine] ; Jin-Zhong Gu [République populaire de Chine] ; Hong-Jin Li [République populaire de Chine]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3099919

Abstract

In the title coordination polymer, {[Tm(C₇H₂NO₅)(H₂O)₃]·H₂O}_n, the Tm^III atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO₇ coordination geometry. The anions bridge adjacent Tm^III ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919

DOI: 10.1107/S1600536811007628
PubMed: 21753941
PubMed Central: 3099919

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Le document en format XML

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-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
<author><name sortKey="Gao, Zhu Qing" sort="Gao, Zhu Qing" uniqKey="Gao Z" first="Zhu-Qing" last="Gao">Zhu-Qing Gao</name>
<affiliation wicri:level="1"><nlm:aff id="a">School of Chemistry and Biology Engineering, Taiyuan University of Science and Technology, Taiyuan 030021,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lv, Dong Yu" sort="Lv, Dong Yu" uniqKey="Lv D" first="Dong-Yu" last="Lv">Dong-Yu Lv</name>
<affiliation wicri:level="1"><nlm:aff id="b">Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Gu, Jin Zhong" sort="Gu, Jin Zhong" uniqKey="Gu J" first="Jin-Zhong" last="Gu">Jin-Zhong Gu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Li, Hong Jin" sort="Li, Hong Jin" uniqKey="Li H" first="Hong-Jin" last="Li">Hong-Jin Li</name>
<affiliation wicri:level="1"><nlm:aff id="a">School of Chemistry and Biology Engineering, Taiyuan University of Science and Technology, Taiyuan 030021,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Poly[[triaqua(μ<sub>3</sub>
-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
<author><name sortKey="Gao, Zhu Qing" sort="Gao, Zhu Qing" uniqKey="Gao Z" first="Zhu-Qing" last="Gao">Zhu-Qing Gao</name>
<affiliation wicri:level="1"><nlm:aff id="a">School of Chemistry and Biology Engineering, Taiyuan University of Science and Technology, Taiyuan 030021,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lv, Dong Yu" sort="Lv, Dong Yu" uniqKey="Lv D" first="Dong-Yu" last="Lv">Dong-Yu Lv</name>
<affiliation wicri:level="1"><nlm:aff id="b">Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Gu, Jin Zhong" sort="Gu, Jin Zhong" uniqKey="Gu J" first="Jin-Zhong" last="Gu">Jin-Zhong Gu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Li, Hong Jin" sort="Li, Hong Jin" uniqKey="Li H" first="Hong-Jin" last="Li">Hong-Jin Li</name>
<affiliation wicri:level="1"><nlm:aff id="a">School of Chemistry and Biology Engineering, Taiyuan University of Science and Technology, Taiyuan 030021,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2011">2011</date>
</imprint>
</series>
</biblStruct>
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<front><div type="abstract" xml:lang="en"><p>In the title coordination polymer, {[Tm(C<sub>7</sub>
H<sub>2</sub>
NO<sub>5</sub>
)(H<sub>2</sub>
O)<sub>3</sub>
]·H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, the Tm<sup>III</sup>
 atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO<sub>7</sub>
 coordination geometry. The anions bridge adjacent Tm<sup>III</sup>
 ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
  <front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">21753941</article-id>
<article-id pub-id-type="pmc">3099919</article-id>
<article-id pub-id-type="publisher-id">pv2392</article-id>
<article-id pub-id-type="doi">10.1107/S1600536811007628</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536811007628</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Metal-Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>Poly[[triaqua(μ<sub>3</sub>
-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</article-title>
<alt-title><italic>[Tm(C<sub>7</sub>
H<sub>2</sub>
NO<sub>5</sub>
)(H<sub>2</sub>
O)<sub>3</sub>
]·H<sub>2</sub>
mO</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Gao</surname>
<given-names>Zhu-Qing</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Lv</surname>
<given-names>Dong-Yu</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Gu</surname>
<given-names>Jin-Zhong</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Li</surname>
<given-names>Hong-Jin</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
School of Chemistry and Biology Engineering, Taiyuan University of Science and Technology, Taiyuan 030021,<country>People’s Republic of China</country>
</aff>
<aff id="b"><label>b</label>
Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000,<country>People’s Republic of China</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>zqgao2008@163.com</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>4</month>
<year>2011</year>
</pub-date>
<pub-date pub-type="epub"><day>09</day>
<month>3</month>
<year>2011</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>09</day>
<month>3</month>
<year>2011</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the 
 							. </pmc-comment>
      <volume>67</volume>
<issue>Pt 4</issue>
<issue-id pub-id-type="publisher-id">e110400</issue-id>
<fpage>m409</fpage>
<lpage>m409</lpage>
<history><date date-type="received"><day>21</day>
<month>2</month>
<year>2011</year>
</date>
<date date-type="accepted"><day>28</day>
<month>2</month>
<year>2011</year>
</date>
</history>
<permissions><copyright-statement>© Gao et al. 2011</copyright-statement>
<copyright-year>2011</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536811007628">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>In the title coordination polymer, {[Tm(C<sub>7</sub>
H<sub>2</sub>
NO<sub>5</sub>
)(H<sub>2</sub>
O)<sub>3</sub>
]·H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, the Tm<sup>III</sup>
 atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO<sub>7</sub>
 coordination geometry. The anions bridge adjacent Tm<sup>III</sup>
 ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O9—H8<italic>W</italic>
⋯O2<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.88</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.54</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.111 (6)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">123</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O9—H7<italic>W</italic>
⋯O5<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.83</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.03</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.694 (6)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">137</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H6<italic>W</italic>
⋯O9<sup>iii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.95</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.73</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.679 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">179</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O8—H5<italic>W</italic>
⋯O9<sup>iv</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.90</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.27</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.068 (6)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">148</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H4<italic>W</italic>
⋯O5<sup>v</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.95</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.79</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.697 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">158</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H3<italic>W</italic>
⋯O1<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.90 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.85 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.672 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">151 (5)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O6—H2<italic>W</italic>
⋯O4<sup>vi</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.83 (4)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.11 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.791 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">139 (5)</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O6—H1<italic>W</italic>
⋯O3<sup>vii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.91 (4)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.84 (4)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.706 (5)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">156 (4)</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iii) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iv) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (v) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi6.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (vi) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi7.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (vii) <inline-formula><inline-graphic xlink:href="e-67-0m409-efi8.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
</record>

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Poly[[triaqua­(μ3-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

Poly[[triaqua­(μ3-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

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Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]