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Quantitative identification of phonon modes controlling the multiphonon relaxation in heavy-metal oxide glasses

Identifieur interne : 000A26 ( Pascal/Checkpoint ); précédent : 000A25; suivant : 000A27

Quantitative identification of phonon modes controlling the multiphonon relaxation in heavy-metal oxide glasses

Auteurs : YONG SEOP HAN [Corée du Sud] ; JAY HYOK SONG [Corée du Sud] ; Jong Heo [Corée du Sud]

Source :

RBID : Pascal:05-0058784

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Abstract

The phonon mode(s) controlling the multiphonon relaxation (MPR) in PbO-Bi2O3-Ga2O3 glass was analyzed, and the effect of GeO2 addition on the MPR process was investigated. MPR rates were obtained from the lifetimes of the Tm3+:3H4 level in glasses over the temperature range 20-280 K. In PbO-Bi2O3-Ga2O3 glass, phonons from the bending vibration between GaO4 tetrahedra (∼550 cm-') controlled the MPR process. On the addition of GeO2, the phonon mode at ∼770 cm-1 due to the stretching vibration of GeO4 tetrahedra started to affect the MPR process. Phonon modes controlling the MPR process in PbO-Bi2O3-Ga2O3-GeO2 glass were both 550 cm-1 and 770 cm-1.


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<div type="abstract" xml:lang="en">The phonon mode(s) controlling the multiphonon relaxation (MPR) in PbO-Bi
<sub>2</sub>
O
<sub>3</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
glass was analyzed, and the effect of GeO
<sub>2</sub>
addition on the MPR process was investigated. MPR rates were obtained from the lifetimes of the Tm
<sup>3+</sup>
:
<sup>3</sup>
H
<sub>4</sub>
level in glasses over the temperature range 20-280 K. In PbO-Bi
<sub>2</sub>
O
<sub>3</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
glass, phonons from the bending vibration between GaO
<sub>4</sub>
tetrahedra (∼550 cm-') controlled the MPR process. On the addition of GeO
<sub>2</sub>
, the phonon mode at ∼770 cm
<sup>-1</sup>
due to the stretching vibration of GeO
<sub>4</sub>
tetrahedra started to affect the MPR process. Phonon modes controlling the MPR process in PbO-Bi
<sub>2</sub>
O
<sub>3</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
-GeO
<sub>2</sub>
glass were both 550 cm
<sup>-1</sup>
and 770 cm
<sup>-1</sup>
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