Gibbs Free Energy of Formation of Ln 2CuBaO5Compounds Determined by the EMF Method ( Ln =Yb, Tm, Er, Ho, Dy, and Gd)
Identifieur interne : 002C24 ( Main/Merge ); précédent : 002C23; suivant : 002C25Gibbs Free Energy of Formation of Ln 2CuBaO5Compounds Determined by the EMF Method ( Ln =Yb, Tm, Er, Ho, Dy, and Gd)
Auteurs : M. Kopyto [Pologne] ; K. Fitzner [Pologne]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1997.
Descripteurs français
- Wicri :
- topic : Oxyde.
English descriptors
- KwdEn :
- Academic press, Bacuo phases, Baf2 caf2, Cell reaction, Constituent oxides, Cubao compounds, Cugd, Electrochemical cells, Electrode, Electrode pellets, Energy change, Enthalpy, Fitzner, Galvanic cell, Lanthanide, Lanthanide elements, Oxide, Oxide superconductor, Phase equilibria, Previous paper, Respective phases, Side reaction, Similar compounds, Solid state chem, Subsequent lanthanide elements, Temperature dependence, Temperature range, Thermodynamic stability.
- Teeft :
- Academic press, Bacuo phases, Baf2 caf2, Cell reaction, Constituent oxides, Cubao compounds, Cugd, Electrochemical cells, Electrode, Electrode pellets, Energy change, Enthalpy, Fitzner, Galvanic cell, Lanthanide, Lanthanide elements, Oxide, Oxide superconductor, Phase equilibria, Previous paper, Respective phases, Side reaction, Similar compounds, Solid state chem, Subsequent lanthanide elements, Temperature dependence, Temperature range, Thermodynamic stability.
Abstract
Abstract: Employing electrochemical cells with calcium fluoride solid electrolyte forLn=Yb, Er, Tm, Ho, Dy, and the Gibbs free energy change of the reaction of formation of the solidLn2CuBaO5“green” phase for subsequent lanthanide elements was determined. Obtained results were used to derive Gibbs free energy change of reactions of formation of respectiveLn2CuBaO5phases from constituent oxides.
Url:
DOI: 10.1006/jssc.1997.7540
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ISTEX:09035087C6245C767CD8852FF17BE968D4C13249Le document en format XML
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Kopyto</name><affiliation wicri:level="1"><country xml:lang="fr">Pologne</country><wicri:regionArea>Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta Street, 30-059, Krakow</wicri:regionArea><wicri:noRegion>Krakow</wicri:noRegion></affiliation></author><author><name sortKey="Fitzner, K" sort="Fitzner, K" uniqKey="Fitzner K" first="K." last="Fitzner">K. Fitzner</name><affiliation wicri:level="1"><country xml:lang="fr">Pologne</country><wicri:regionArea>Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta Street, 30-059, Krakow</wicri:regionArea><wicri:noRegion>Krakow</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Solid State Chemistry</title><title level="j" type="abbrev">YJSSC</title><idno type="ISSN">0022-4596</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997">1997</date><biblScope unit="volume">134</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="85">85</biblScope><biblScope unit="page" to="90">90</biblScope></imprint><idno type="ISSN">0022-4596</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Academic press</term><term>Bacuo phases</term><term>Baf2 caf2</term><term>Cell reaction</term><term>Constituent oxides</term><term>Cubao compounds</term><term>Cugd</term><term>Electrochemical cells</term><term>Electrode</term><term>Electrode pellets</term><term>Energy change</term><term>Enthalpy</term><term>Fitzner</term><term>Galvanic cell</term><term>Lanthanide</term><term>Lanthanide elements</term><term>Oxide</term><term>Oxide superconductor</term><term>Phase equilibria</term><term>Previous paper</term><term>Respective phases</term><term>Side reaction</term><term>Similar compounds</term><term>Solid state chem</term><term>Subsequent lanthanide elements</term><term>Temperature dependence</term><term>Temperature range</term><term>Thermodynamic stability</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Academic press</term><term>Bacuo phases</term><term>Baf2 caf2</term><term>Cell reaction</term><term>Constituent oxides</term><term>Cubao compounds</term><term>Cugd</term><term>Electrochemical cells</term><term>Electrode</term><term>Electrode pellets</term><term>Energy change</term><term>Enthalpy</term><term>Fitzner</term><term>Galvanic cell</term><term>Lanthanide</term><term>Lanthanide elements</term><term>Oxide</term><term>Oxide superconductor</term><term>Phase equilibria</term><term>Previous paper</term><term>Respective phases</term><term>Side reaction</term><term>Similar compounds</term><term>Solid state chem</term><term>Subsequent lanthanide elements</term><term>Temperature dependence</term><term>Temperature range</term><term>Thermodynamic stability</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Oxyde</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: Employing electrochemical cells with calcium fluoride solid electrolyte forLn=Yb, Er, Tm, Ho, Dy, and the Gibbs free energy change of the reaction of formation of the solidLn2CuBaO5“green” phase for subsequent lanthanide elements was determined. Obtained results were used to derive Gibbs free energy change of reactions of formation of respectiveLn2CuBaO5phases from constituent oxides.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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