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Gibbs Free Energy of Formation of Ln 2CuBaO5Compounds Determined by the EMF Method ( Ln =Yb, Tm, Er, Ho, Dy, and Gd)

Identifieur interne : 000183 ( Istex/Corpus ); précédent : 000182; suivant : 000184

Gibbs Free Energy of Formation of Ln 2CuBaO5Compounds Determined by the EMF Method ( Ln =Yb, Tm, Er, Ho, Dy, and Gd)

Auteurs : M. Kopyto ; K. Fitzner

Source :

RBID : ISTEX:09035087C6245C767CD8852FF17BE968D4C13249

English descriptors

Abstract

Abstract: Employing electrochemical cells with calcium fluoride solid electrolyte forLn=Yb, Er, Tm, Ho, Dy, and the Gibbs free energy change of the reaction of formation of the solidLn2CuBaO5“green” phase for subsequent lanthanide elements was determined. Obtained results were used to derive Gibbs free energy change of reactions of formation of respectiveLn2CuBaO5phases from constituent oxides.

Url:
DOI: 10.1006/jssc.1997.7540

Links to Exploration step

ISTEX:09035087C6245C767CD8852FF17BE968D4C13249

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