Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue
Identifieur interne : 001521 ( Main/Exploration ); précédent : 001520; suivant : 001522Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue
Auteurs : Guo-Ming Wang [République populaire de Chine] ; Hai-Lan Huang [République populaire de Chine] ; Hui Li [République populaire de Chine] ; Qing-Hua Zheng [République populaire de Chine]Source :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2007-11.
Descripteurs français
- Wicri :
- topic : Polymère.
English descriptors
- KwdEn :
- Acta, Acta cryst, Adjacent chains, Aqua ligand, Bond lengths, Bruker, Carboxylate, Chem, Coordination polymers, Cryst, Crystal structures, Data collection siemems, Different coordination environments, Diffractometer absorption correction, Eddaoudi, Hydrogen bonds, Inorg, Intensity measurements, Ligand, Parameters parameters, Polymer, Sheldrick, Symmetry codes, Title compounds, Tmin tmax, Wang, Zhang.
- Teeft :
- Acta, Acta cryst, Adjacent chains, Aqua ligand, Bond lengths, Bruker, Carboxylate, Chem, Coordination polymers, Cryst, Crystal structures, Data collection siemems, Different coordination environments, Diffractometer absorption correction, Eddaoudi, Hydrogen bonds, Inorg, Intensity measurements, Ligand, Parameters parameters, Polymer, Sheldrick, Symmetry codes, Title compounds, Tmin tmax, Wang, Zhang.
Abstract
The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.
Url:
DOI: 10.1107/S0108270107047403
Affiliations:
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last="Zheng">Qing-Hua Zheng</name><affiliation wicri:level="1"><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071</wicri:regionArea><wicri:noRegion>Shandong 266071</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Acta Crystallographica Section C</title><title level="j" type="alt">ACTA CRYSTALLOGRAPHICA C</title><idno type="ISSN">0108-2701</idno><idno type="eISSN">1600-5759</idno><imprint><biblScope unit="vol">63</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="m531">m531</biblScope><biblScope unit="page" to="m533">m533</biblScope><publisher>Blackwell Publishing Ltd</publisher><pubPlace>5 Abbey Square, Chester, Cheshire CH1 2HU, England</pubPlace><date type="published" when="2007-11">2007-11</date></imprint><idno 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cryst</term><term>Adjacent chains</term><term>Aqua ligand</term><term>Bond lengths</term><term>Bruker</term><term>Carboxylate</term><term>Chem</term><term>Coordination polymers</term><term>Cryst</term><term>Crystal structures</term><term>Data collection siemems</term><term>Different coordination environments</term><term>Diffractometer absorption correction</term><term>Eddaoudi</term><term>Hydrogen bonds</term><term>Inorg</term><term>Intensity measurements</term><term>Ligand</term><term>Parameters parameters</term><term>Polymer</term><term>Sheldrick</term><term>Symmetry codes</term><term>Title compounds</term><term>Tmin tmax</term><term>Wang</term><term>Zhang</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Polymère</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</div></front></TEI><affiliations><list><country><li>République populaire de Chine</li></country></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Wang, Guo Ing" sort="Wang, Guo Ing" uniqKey="Wang G" first="Guo-Ming" last="Wang">Guo-Ming Wang</name></noRegion><name sortKey="Huang, Hai An" sort="Huang, Hai An" uniqKey="Huang H" first="Hai-Lan" last="Huang">Hai-Lan Huang</name><name sortKey="Li, Hui" sort="Li, Hui" uniqKey="Li H" first="Hui" last="Li">Hui Li</name><name sortKey="Zheng, Qing Ua" sort="Zheng, Qing Ua" uniqKey="Zheng Q" first="Qing-Hua" last="Zheng">Qing-Hua Zheng</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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