Poly[aqua(mu3-benzene-1,2-dicarboxylato)bis(mu3-hydroxido)bis(mu2-isonicotinato)dierbium(III) monohydrate] and the thulium analogue.
Identifieur interne : 000610 ( PubMed/Corpus ); précédent : 000609; suivant : 000611Poly[aqua(mu3-benzene-1,2-dicarboxylato)bis(mu3-hydroxido)bis(mu2-isonicotinato)dierbium(III) monohydrate] and the thulium analogue.
Auteurs : Guo Ming Wang ; Hai Lan Huang ; Hui Li ; Qing Hua ZhengSource :
- Acta crystallographica. Section C, Crystal structure communications [ 1600-5759 ] ; 2007.
Abstract
The two isomorphous lanthanide coordination polymers, {[Ln(2)(C(6)H(4)NO(2))(2)(C(8)H(4)O(4))(OH)(2)(H(2)O)].H(2)O}(n) (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight-coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by mu(3)-OH groups and carboxylate groups of isonicotinate and benzene-1,2-dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)-3.894 (4) and 3.599 (7)-3.873 (1) A, respectively. Adjacent chains are further connected through hydrogen bonds and pi-pi interactions into a three-dimensional supramolecular framework.
DOI: 10.1107/S0108270107047403
PubMed: 17989474
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Section C, Crystal structure communications</title><idno type="eISSN">1600-5759</idno><imprint><date when="2007" type="published">2007</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The two isomorphous lanthanide coordination polymers, {[Ln(2)(C(6)H(4)NO(2))(2)(C(8)H(4)O(4))(OH)(2)(H(2)O)].H(2)O}(n) (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight-coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by mu(3)-OH groups and carboxylate groups of isonicotinate and benzene-1,2-dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)-3.894 (4) and 3.599 (7)-3.873 (1) A, respectively. Adjacent chains are further connected through hydrogen bonds and pi-pi interactions into a three-dimensional supramolecular framework.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">17989474</PMID><DateCreated><Year>2007</Year><Month>11</Month><Day>08</Day></DateCreated><DateCompleted><Year>2008</Year><Month>01</Month><Day>25</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5759</ISSN><JournalIssue CitedMedium="Internet"><Volume>63</Volume><Issue>Pt 11</Issue><PubDate><Year>2007</Year><Month>Nov</Month></PubDate></JournalIssue><Title>Acta crystallographica. Section C, Crystal structure communications</Title><ISOAbbreviation>Acta Crystallogr C</ISOAbbreviation></Journal><ArticleTitle>Poly[aqua(mu3-benzene-1,2-dicarboxylato)bis(mu3-hydroxido)bis(mu2-isonicotinato)dierbium(III) monohydrate] and the thulium analogue.</ArticleTitle><Pagination><MedlinePgn>m531-3</MedlinePgn></Pagination><Abstract><AbstractText>The two isomorphous lanthanide coordination polymers, {[Ln(2)(C(6)H(4)NO(2))(2)(C(8)H(4)O(4))(OH)(2)(H(2)O)].H(2)O}(n) (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight-coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by mu(3)-OH groups and carboxylate groups of isonicotinate and benzene-1,2-dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)-3.894 (4) and 3.599 (7)-3.873 (1) A, respectively. Adjacent chains are further connected through hydrogen bonds and pi-pi interactions into a three-dimensional supramolecular framework.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Wang</LastName><ForeName>Guo Ming</ForeName><Initials>GM</Initials><AffiliationInfo><Affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China. gmwang_pub@163.com</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Huang</LastName><ForeName>Hai Lan</ForeName><Initials>HL</Initials></Author><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Hui</ForeName><Initials>H</Initials></Author><Author ValidYN="Y"><LastName>Zheng</LastName><ForeName>Qing Hua</ForeName><Initials>QH</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2007</Year><Month>10</Month><Day>24</Day></ArticleDate></Article><MedlineJournalInfo><Country>Denmark</Country><MedlineTA>Acta Crystallogr C</MedlineTA><NlmUniqueID>8305826</NlmUniqueID><ISSNLinking>0108-2701</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2007</Year><Month>9</Month><Day>05</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2007</Year><Month>9</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2007</Year><Month>10</Month><Day>24</Day></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2007</Year><Month>11</Month><Day>9</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2007</Year><Month>11</Month><Day>9</Day><Hour>9</Hour><Minute>1</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2007</Year><Month>11</Month><Day>9</Day><Hour>9</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pii">S0108270107047403</ArticleId><ArticleId IdType="doi">10.1107/S0108270107047403</ArticleId><ArticleId IdType="pubmed">17989474</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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