Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue
Identifieur interne : 002957 ( Istex/Corpus ); précédent : 002956; suivant : 002958Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue
Auteurs : Guo-Ming Wang ; Hai-Lan Huang ; Hui Li ; Qing-Hua ZhengSource :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2007-11.
English descriptors
- KwdEn :
- Acta, Acta cryst, Adjacent chains, Aqua ligand, Bond lengths, Bruker, Carboxylate, Chem, Coordination polymers, Cryst, Crystal structures, Data collection siemems, Different coordination environments, Diffractometer absorption correction, Eddaoudi, Hydrogen bonds, Inorg, Intensity measurements, Ligand, Parameters parameters, Polymer, Sheldrick, Symmetry codes, Title compounds, Tmin tmax, Wang, Zhang.
- Teeft :
- Acta, Acta cryst, Adjacent chains, Aqua ligand, Bond lengths, Bruker, Carboxylate, Chem, Coordination polymers, Cryst, Crystal structures, Data collection siemems, Different coordination environments, Diffractometer absorption correction, Eddaoudi, Hydrogen bonds, Inorg, Intensity measurements, Ligand, Parameters parameters, Polymer, Sheldrick, Symmetry codes, Title compounds, Tmin tmax, Wang, Zhang.
Abstract
The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.
Url:
DOI: 10.1107/S0108270107047403
Links to Exploration step
ISTEX:BB9B73A098F6E3E6E39E5A45D773C42230115C13Le document en format XML
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Li</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author><author><name sortKey="Zheng, Qing Ua" sort="Zheng, Qing Ua" uniqKey="Zheng Q" first="Qing-Hua" last="Zheng">Qing-Hua Zheng</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:BB9B73A098F6E3E6E39E5A45D773C42230115C13</idno><date when="2007" year="2007">2007</date><idno type="doi">10.1107/S0108270107047403</idno><idno type="url">https://api.istex.fr/document/BB9B73A098F6E3E6E39E5A45D773C42230115C13/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">002957</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002957</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main">Poly[aqua(μ<hi rend="subscript">3</hi>‐benzene‐1,2‐dicarboxylato)bis(μ<hi rend="subscript">3</hi>‐hydroxido)bis(μ<hi rend="subscript">2</hi>‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title><author><name sortKey="Wang, Guo Ing" sort="Wang, Guo Ing" uniqKey="Wang G" first="Guo-Ming" last="Wang">Guo-Ming Wang</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author><author><name sortKey="Huang, Hai An" sort="Huang, Hai An" uniqKey="Huang H" first="Hai-Lan" last="Huang">Hai-Lan Huang</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author><author><name sortKey="Li, Hui" sort="Li, Hui" uniqKey="Li H" first="Hui" last="Li">Hui Li</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author><author><name sortKey="Zheng, Qing Ua" sort="Zheng, Qing Ua" uniqKey="Zheng Q" first="Qing-Hua" last="Zheng">Qing-Hua Zheng</name><affiliation><mods:affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Acta Crystallographica Section C</title><title level="j" type="alt">ACTA CRYSTALLOGRAPHICA C</title><idno type="ISSN">0108-2701</idno><idno type="eISSN">1600-5759</idno><imprint><biblScope unit="vol">63</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="m531">m531</biblScope><biblScope unit="page" to="m533">m533</biblScope><publisher>Blackwell Publishing Ltd</publisher><pubPlace>5 Abbey Square, Chester, Cheshire CH1 2HU, England</pubPlace><date type="published" when="2007-11">2007-11</date></imprint><idno type="ISSN">0108-2701</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0108-2701</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acta</term><term>Acta cryst</term><term>Adjacent chains</term><term>Aqua ligand</term><term>Bond lengths</term><term>Bruker</term><term>Carboxylate</term><term>Chem</term><term>Coordination polymers</term><term>Cryst</term><term>Crystal structures</term><term>Data collection siemems</term><term>Different coordination environments</term><term>Diffractometer absorption correction</term><term>Eddaoudi</term><term>Hydrogen bonds</term><term>Inorg</term><term>Intensity measurements</term><term>Ligand</term><term>Parameters parameters</term><term>Polymer</term><term>Sheldrick</term><term>Symmetry codes</term><term>Title compounds</term><term>Tmin tmax</term><term>Wang</term><term>Zhang</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Acta</term><term>Acta cryst</term><term>Adjacent chains</term><term>Aqua ligand</term><term>Bond lengths</term><term>Bruker</term><term>Carboxylate</term><term>Chem</term><term>Coordination polymers</term><term>Cryst</term><term>Crystal structures</term><term>Data collection siemems</term><term>Different coordination environments</term><term>Diffractometer absorption correction</term><term>Eddaoudi</term><term>Hydrogen bonds</term><term>Inorg</term><term>Intensity measurements</term><term>Ligand</term><term>Parameters parameters</term><term>Polymer</term><term>Sheldrick</term><term>Symmetry codes</term><term>Title compounds</term><term>Tmin tmax</term><term>Wang</term><term>Zhang</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>ligand</json:string><json:string>sheldrick</json:string><json:string>carboxylate</json:string><json:string>bruker</json:string><json:string>acta</json:string><json:string>symmetry codes</json:string><json:string>zhang</json:string><json:string>inorg</json:string><json:string>eddaoudi</json:string><json:string>cryst</json:string><json:string>acta cryst</json:string><json:string>wang</json:string><json:string>title compounds</json:string><json:string>adjacent chains</json:string><json:string>coordination polymers</json:string><json:string>crystal structures</json:string><json:string>hydrogen bonds</json:string><json:string>diffractometer absorption correction</json:string><json:string>intensity measurements</json:string><json:string>different coordination environments</json:string><json:string>tmin tmax</json:string><json:string>parameters parameters</json:string><json:string>bond lengths</json:string><json:string>aqua ligand</json:string><json:string>data collection siemems</json:string><json:string>polymer</json:string></teeft></keywords><author><json:item><name>Guo‐Ming Wang</name><affiliations><json:string>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</json:string></affiliations></json:item><json:item><name>Hai‐Lan Huang</name><affiliations><json:string>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</json:string></affiliations></json:item><json:item><name>Hui Li</name><affiliations><json:string>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</json:string></affiliations></json:item><json:item><name>Qing‐Hua Zheng</name><affiliations><json:string>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</json:string></affiliations></json:item></author><articleId><json:string>AYCBG3054</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>miscellaneous</json:string></originalGenre><abstract>The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</abstract><qualityIndicators><score>2.503</score><pdfVersion>1.2</pdfVersion><pdfPageSize>610 x 794 pts</pdfPageSize><refBibsNative>false</refBibsNative><abstractCharCount>694</abstractCharCount><pdfWordCount>1483</pdfWordCount><pdfCharCount>9328</pdfCharCount><pdfPageCount>3</pdfPageCount><abstractWordCount>85</abstractWordCount></qualityIndicators><title>Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title><genre><json:string>other</json:string></genre><host><title>Acta Crystallographica Section 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rend="subscript">2</hi>‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>Blackwell Publishing Ltd</publisher><pubPlace>5 Abbey Square, Chester, Cheshire CH1 2HU, England</pubPlace><date type="published" when="2007-11"></date></publicationStmt><notesStmt><note type="content-type" subtype="other" source="miscellaneous" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-7474895G-0">other</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="other"><analytic><title level="a" type="main">Poly[aqua(μ<hi rend="subscript">3</hi>‐benzene‐1,2‐dicarboxylato)bis(μ<hi rend="subscript">3</hi>‐hydroxido)bis(μ<hi rend="subscript">2</hi>‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title><title level="a" type="short">[Er2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O and [Tm2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O</title><author xml:id="author-0000"><persName><forename type="first">Guo‐Ming</forename><surname>Wang</surname></persName><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Hai‐Lan</forename><surname>Huang</surname></persName><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Hui</forename><surname>Li</surname></persName><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Qing‐Hua</forename><surname>Zheng</surname></persName><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China<address><country key="CN"></country></address></affiliation></author><idno type="istex">BB9B73A098F6E3E6E39E5A45D773C42230115C13</idno><idno type="ark">ark:/67375/WNG-PV7DFCNM-R</idno><idno type="DOI">10.1107/S0108270107047403</idno><idno type="unit">AYCBG3054</idno><idno type="society">bg3054</idno><idno type="toTypesetVersion">file:AYC.AYCBG3054.pdf</idno></analytic><monogr><title level="j" type="main">Acta Crystallographica Section C</title><title level="j" type="alt">ACTA CRYSTALLOGRAPHICA C</title><idno type="pISSN">0108-2701</idno><idno type="eISSN">1600-5759</idno><idno type="book-DOI">10.1111/(ISSN)1600-5759</idno><idno type="book-part-DOI">10.1111/ayc.2007.63.issue-11</idno><idno type="product">AYC</idno><imprint><biblScope unit="vol">63</biblScope><biblScope unit="issue">11</biblScope><biblScope unit="page" from="m531">m531</biblScope><biblScope unit="page" to="m533">m533</biblScope><publisher>Blackwell Publishing Ltd</publisher><pubPlace>5 Abbey Square, Chester, Cheshire CH1 2HU, England</pubPlace><date type="published" when="2007-11"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><p>The two isomorphous lanthanide coordination polymers, {[Ln<hi rend="subscript">2</hi>(C<hi rend="subscript">6</hi>H<hi rend="subscript">4</hi>NO<hi rend="subscript">2</hi>)<hi rend="subscript">2</hi>(C<hi rend="subscript">8</hi>H<hi rend="subscript">4</hi>O<hi rend="subscript">4</hi>)(OH)<hi rend="subscript">2</hi>(H<hi rend="subscript">2</hi>O)]·H<hi rend="subscript">2</hi>O}<hi rend="subscript"><hi rend="italic">n</hi></hi> (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ<hi rend="subscript">3</hi>‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</p></abstract><textClass><keywords rend="tocHeading1"><term>metal‐organic compounds</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/BB9B73A098F6E3E6E39E5A45D773C42230115C13/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Blackwell Publishing Ltd</publisherName><publisherLoc>5 Abbey Square, Chester, Cheshire CH1 2HU, England</publisherLoc></publisherInfo><doi origin="wiley" registered="yes">10.1111/(ISSN)1600-5759</doi><issn type="print">0108-2701</issn><issn type="electronic">1600-5759</issn><idGroup><id type="product" value="AYC"></id></idGroup><titleGroup><title type="main" sort="ACTA CRYSTALLOGRAPHICA C">Acta Crystallographica Section C</title><title type="short">Acta Cryst. C</title></titleGroup></publicationMeta><publicationMeta level="part" position="11011"><doi origin="wiley">10.1111/ayc.2007.63.issue-11</doi><numberingGroup><numbering type="journalVolume" number="63">63</numbering><numbering type="journalIssue" number="11">11</numbering></numberingGroup><coverDate startDate="2007-11">November 2007</coverDate></publicationMeta><publicationMeta level="unit" type="miscellaneous" position="24" status="forIssue"><doi origin="wiley">10.1107/S0108270107047403</doi><idGroup><id type="unit" value="AYCBG3054"></id><id type="society" value="bg3054"></id></idGroup><titleGroup><title type="tocHeading1">metal‐organic compounds</title></titleGroup><eventGroup><event type="firstOnline" date="2007-11-19"></event><event type="publishedOnlineFinalForm" date="2007-11-19"></event><event type="xmlConverted" agent="Converter:BPG_TO_WML3G version:2.3.2 mode:FullText source:Header result:Header" date="2010-02-27"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-06"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-14"></event></eventGroup><numberingGroup><numbering type="pageFirst">m531</numbering><numbering type="pageLast">m533</numbering></numberingGroup><correspondenceTo>Guo‐Ming Wang, e‐mail: <email>gmwang_pub@163.com</email></correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:AYC.AYCBG3054.pdf"></link></linkGroup></publicationMeta><contentMeta><unparsedEditorialHistory>Received 5 September 2007, accepted 26 September 2007</unparsedEditorialHistory><countGroup><count type="figureTotal" number="0"></count><count type="tableTotal" number="0"></count><count type="formulaTotal" number="0"></count><count type="wordTotal" number="0"></count><count type="referenceTotal" number="0"></count><count type="linksCrossRef" number="0"></count><count type="linksPubMed" number="0"></count></countGroup><titleGroup><title type="main">Poly[aqua(μ<sub>3</sub>‐benzene‐1,2‐dicarboxylato)bis(μ<sub>3</sub>‐hydroxido)bis(μ<sub>2</sub>‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title><title type="shortAuthors">Wang <i>et al.</i></title><title type="short">[Er<sub>2</sub>(C<sub>6</sub>H<sub>4</sub>NO<sub>2</sub>)<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)(OH)<sub>2</sub>(H<sub>2</sub>O)]·H<sub>2</sub>O and [Tm<sub>2</sub>(C<sub>6</sub>H<sub>4</sub>NO<sub>2</sub>)<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)(OH)<sub>2</sub>(H<sub>2</sub>O)]·H<sub>2</sub>O</title></titleGroup><creators><creator creatorRole="author" xml:id="cr1" affiliationRef="#a1"><personName><givenNames>Guo‐Ming</givenNames><familyName>Wang</familyName></personName></creator><creator creatorRole="author" xml:id="cr2" affiliationRef="#a1"><personName><givenNames>Hai‐Lan</givenNames><familyName>Huang</familyName></personName></creator><creator creatorRole="author" xml:id="cr3" affiliationRef="#a1"><personName><givenNames>Hui</givenNames><familyName>Li</familyName></personName></creator><creator creatorRole="author" xml:id="cr4" affiliationRef="#a1"><personName><givenNames>Qing‐Hua</givenNames><familyName>Zheng</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="CN"><unparsedAffiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="main" xml:lang="en"><p>The two isomorphous lanthanide coordination polymers, {[Ln<sub>2</sub>(C<sub>6</sub>H<sub>4</sub>NO<sub>2</sub>)<sub>2</sub>(C<sub>8</sub>H<sub>4</sub>O<sub>4</sub>)(OH)<sub>2</sub>(H<sub>2</sub>O)]·H<sub>2</sub>O}<sub><i>n</i></sub> (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ<sub>3</sub>‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>[Er2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O and [Tm2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Poly[aqua(μ3‐benzene‐1,2‐dicarboxylato)bis(μ3‐hydroxido)bis(μ2‐isonicotinato)dierbium(III) monohydrate] and the thulium analogue</title></titleInfo><name type="personal"><namePart type="given">Guo‐Ming</namePart><namePart type="family">Wang</namePart><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Hai‐Lan</namePart><namePart type="family">Huang</namePart><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Hui</namePart><namePart type="family">Li</namePart><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Qing‐Hua</namePart><namePart type="family">Zheng</namePart><affiliation>Department of Chemistry, Teachers' College of Qingdao University, Qingdao, Shandong 266071, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="miscellaneous" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Blackwell Publishing Ltd</publisher><place><placeTerm type="text">5 Abbey Square, Chester, Cheshire CH1 2HU, England</placeTerm></place><dateIssued encoding="w3cdtf">2007-11</dateIssued><edition>Received 5 September 2007, accepted 26 September 2007</edition><copyrightDate encoding="w3cdtf">2007</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">0</extent><extent unit="tables">0</extent><extent unit="formulas">0</extent><extent unit="references">0</extent><extent unit="linksCrossRef">0</extent><extent unit="words">0</extent></physicalDescription><abstract lang="en">The two isomorphous lanthanide coordination polymers, {[Ln2(C6H4NO2)2(C8H4O4)(OH)2(H2O)]·H2O}n (Ln = Er and Tm), contain two crystallographically independent Ln ions which are both eight‐coordinated by O atoms, but with quite different coordination environments. In both crystal structures, adjacent Ln atoms are bridged by μ3‐OH groups and carboxylate groups of isonicotinate and benzene‐1,2‐dicarboxylate ligands, forming infinite chains in which the Er...Er and Tm...Tm distances are in the ranges 3.622 (3)–3.894 (4) and 3.599 (7)–3.873 (1) Å, respectively. Adjacent chains are further connected through hydrogen bonds and π–π interactions into a three‐dimensional supramolecular framework.</abstract><relatedItem type="host"><titleInfo><title>Acta Crystallographica Section C</title></titleInfo><titleInfo type="abbreviated"><title>Acta Cryst. C</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><identifier type="ISSN">0108-2701</identifier><identifier type="eISSN">1600-5759</identifier><identifier type="DOI">10.1111/(ISSN)1600-5759</identifier><identifier type="PublisherID">AYC</identifier><part><date>2007</date><detail type="volume"><caption>vol.</caption><number>63</number></detail><detail type="issue"><caption>no.</caption><number>11</number></detail><extent unit="pages"><start>m531</start><end>m533</end></extent></part></relatedItem><identifier type="istex">BB9B73A098F6E3E6E39E5A45D773C42230115C13</identifier><identifier type="ark">ark:/67375/WNG-PV7DFCNM-R</identifier><identifier type="DOI">10.1107/S0108270107047403</identifier><identifier type="ArticleID">AYCBG3054</identifier><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Blackwell Publishing Ltd</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/BB9B73A098F6E3E6E39E5A45D773C42230115C13/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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