Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]
Identifieur interne : 000966 ( Main/Exploration ); précédent : 000965; suivant : 000967Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]
Auteurs : Zhu-Qing Gao [République populaire de Chine] ; Dong-Yu Lv [République populaire de Chine] ; Jin-Zhong Gu [République populaire de Chine] ; Hong-Jin Li [République populaire de Chine]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.
Abstract
In the title coordination polymer, {[Tm(C7H2NO5)(H2O)3]·H2O}
Url:
DOI: 10.1107/S1600536811007628
PubMed: 21753941
PubMed Central: 3099919
Affiliations:
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Le document en format XML
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-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Poly[[triaqua(μ<sub>3</sub>
-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
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<front><div type="abstract" xml:lang="en"><p>In the title coordination polymer, {[Tm(C<sub>7</sub>
H<sub>2</sub>
NO<sub>5</sub>
)(H<sub>2</sub>
O)<sub>3</sub>
]·H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, the Tm<sup>III</sup>
atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO<sub>7</sub>
coordination geometry. The anions bridge adjacent Tm<sup>III</sup>
ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.</p>
</div>
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