ThuliumV1, Ncbi, Curation, bibRecord, 000486

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Identifieur interne : 000486 ( Ncbi/Curation ); précédent : 000485; suivant : 000487

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Auteurs : Zhu-Qing Gao [République populaire de Chine] ; Dong-Yu Lv [République populaire de Chine] ; Jin-Zhong Gu [République populaire de Chine] ; Hong-Jin Li [République populaire de Chine]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3099919

Abstract

In the title coordination polymer, {[Tm(C₇H₂NO₅)(H₂O)₃]·H₂O}_n, the Tm^III atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO₇ coordination geometry. The anions bridge adjacent Tm^III ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099919

DOI: 10.1107/S1600536811007628
PubMed: 21753941
PubMed Central: 3099919

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PMC:3099919

Le document en format XML

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-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
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-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]</title>
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<front><div type="abstract" xml:lang="en"><p>In the title coordination polymer, {[Tm(C<sub>7</sub>
H<sub>2</sub>
NO<sub>5</sub>
)(H<sub>2</sub>
O)<sub>3</sub>
]·H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
, the Tm<sup>III</sup>
 atom is eight-coordinated by a tridentate 4-oxidopyridine-2,6-dicarboxylate trianion, two monodentate anions and three water molecules, forming a distorted bicapped trigonal–prismatic TmNO<sub>7</sub>
 coordination geometry. The anions bridge adjacent Tm<sup>III</sup>
 ions into double chains. Adjacent chains are further connected into sheets. O—H⋯O hydrogen bonds involving both coordinated and uncoordinated water molecules generate a three-dimensional supramolecular framework.</p>
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Serveur d'exploration sur le thulium

Poly[[triaqua­(μ3-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

Poly[[triaqua­(μ3-4-oxidopyridine-2,6-dicarboxyl­ato)thulium(III)] monohydrate]

Source :

Abstract

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Links to Exploration step

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Pour générer des pages wiki

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]

Poly[[triaqua(μ3-4-oxidopyridine-2,6-dicarboxylato)thulium(III)] monohydrate]