Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]
Identifieur interne : 000F18 ( Main/Exploration ); précédent : 000F17; suivant : 000F19Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]
Auteurs : Jia-Lu Liu [République populaire de Chine] ; Hua-Qiong Li [République populaire de Chine] ; Guo-Liang Zhao [République populaire de Chine]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.
Abstract
In the title centrosymmetric dinuclear complex, [Tm2(C10H11O4)6(C12H8N2)2], the unique TmIII ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand
Url:
DOI: 10.1107/S1600536809051435
PubMed: 21579980
PubMed Central: 2979998
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en"><p>In the title centrosymmetric dinuclear complex, [Tm<sub>2</sub>
(C<sub>10</sub>
H<sub>11</sub>
O<sub>4</sub>
)<sub>6</sub>
(C<sub>12</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>2</sub>
], the unique Tm<sup>III</sup>
ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand <italic>via</italic>
seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in the bis-chelate, bridging and bridging tridentate modes.</p>
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