Tetra-kis(μ(2)-3,4-dimethoxy-phenyl-acetato)-κO,O':O';κO:O:O';κO:O';κO:O'-bis-[(3,4-dimethoxy-phenyl-acetato-κO,O')(1,10-phenanthroline-κN,N)thulium(III)].
Identifieur interne : 000557 ( PubMed/Corpus ); précédent : 000556; suivant : 000558Tetra-kis(μ(2)-3,4-dimethoxy-phenyl-acetato)-κO,O':O';κO:O:O';κO:O';κO:O'-bis-[(3,4-dimethoxy-phenyl-acetato-κO,O')(1,10-phenanthroline-κN,N)thulium(III)].
Auteurs : Jia-Lu Liu ; Hua-Qiong Li ; Guo-Liang ZhaoSource :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2009.
Abstract
In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging and bridging tridentate modes.
DOI: 10.1107/S1600536809051435
PubMed: 21579980
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<author><name sortKey="Liu, Jia Lu" sort="Liu, Jia Lu" uniqKey="Liu J" first="Jia-Lu" last="Liu">Jia-Lu Liu</name>
<affiliation><nlm:affiliation>Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.</nlm:affiliation>
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<author><name sortKey="Li, Hua Qiong" sort="Li, Hua Qiong" uniqKey="Li H" first="Hua-Qiong" last="Li">Hua-Qiong Li</name>
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<author><name sortKey="Zhao, Guo Liang" sort="Zhao, Guo Liang" uniqKey="Zhao G" first="Guo-Liang" last="Zhao">Guo-Liang Zhao</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en">Tetra-kis(μ(2)-3,4-dimethoxy-phenyl-acetato)-κO,O':O';κO:O:O';κO:O';κO:O'-bis-[(3,4-dimethoxy-phenyl-acetato-κO,O')(1,10-phenanthroline-κN,N)thulium(III)].</title>
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<affiliation><nlm:affiliation>Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.</nlm:affiliation>
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<front><div type="abstract" xml:lang="en">In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging and bridging tridentate modes.</div>
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<CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Inorg Chem. 2006 Jun 12;45(12):4801-10</RefSource>
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<CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</RefSource>
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