ThuliumV1, Main, Curation, bibRecord, 000F18

Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]

Identifieur interne : 000F18 ( Main/Curation ); précédent : 000F17; suivant : 000F19

Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]

Auteurs : Jia-Lu Liu [République populaire de Chine] ; Hua-Qiong Li [République populaire de Chine] ; Guo-Liang Zhao [République populaire de Chine]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2009.

RBID : PMC:2979998

Abstract

In the title centrosymmetric dinuclear complex, [Tm₂(C₁₀H₁₁O₄)₆(C₁₂H₈N₂)₂], the unique Tm^III ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in the bis-chelate, bridging and bridging tridentate modes.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979998

DOI: 10.1107/S1600536809051435
PubMed: 21579980
PubMed Central: 2979998

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PMC:2979998

Le document en format XML

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-3,4-dimethoxyphenylacetato)-κ<sup>3</sup>
<italic>O</italic>
,<italic>O</italic>
′:<italic>O</italic>
′;κ<sup>3</sup>
<italic>O</italic>
:<italic>O</italic>
:<italic>O</italic>
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:<italic>O</italic>
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<italic>N</italic>
,<italic>N</italic>
)thulium(III)]</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Tetrakis(μ<sub>2</sub>
-3,4-dimethoxyphenylacetato)-κ<sup>3</sup>
<italic>O</italic>
,<italic>O</italic>
′:<italic>O</italic>
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<front><div type="abstract" xml:lang="en"><p>In the title centrosymmetric dinuclear complex, [Tm<sub>2</sub>
(C<sub>10</sub>
H<sub>11</sub>
O<sub>4</sub>
)<sub>6</sub>
(C<sub>12</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>2</sub>
], the unique Tm<sup>III</sup>
 ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand <italic>via</italic>
 seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in the bis-chelate, bridging and bridging tridentate modes.</p>
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Tetra­kis(μ2-3,4-dimethoxy­phenyl­acetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis­[(3,4-dimethoxy­phenyl­acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]

Tetra­kis(μ2-3,4-dimethoxy­phenyl­acetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis­[(3,4-dimethoxy­phenyl­acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]

Source :

Abstract

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Pour générer des pages wiki

Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]

Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]