Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Identifieur interne : 000028 ( PascalFrancis/Checkpoint ); précédent : 000027; suivant : 000029Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Auteurs : Casimir Togbe [Allemagne] ; Luc-Sy Tran [France] ; DONG LIU [Allemagne] ; Daniel Felsmann [Allemagne] ; Patrick Osswald [Allemagne] ; Pierre-Alexandre Glaude [France] ; Baptiste Sirjean [France] ; René Fournet [France] ; Frédérique Battin-Leclerc [France] ; Katharina Kohse-Höinghaus [Allemagne]Source :
- Combustion and flame [ 0010-2180 ] ; 2014.
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- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
Affiliations:
- Allemagne, France
- Grand Est, Lorraine (région)
- Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine
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2,5-Dimethylfuran</title><author><name sortKey="Togbe, Casimir" sort="Togbe, Casimir" uniqKey="Togbe C" first="Casimir" last="Togbe">Casimir Togbe</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1><s2>33615 Bielefeld</s2><s3>DEU</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Allemagne</country><wicri:noRegion>33615 Bielefeld</wicri:noRegion><wicri:noRegion>Universitätsstrasse 25</wicri:noRegion><wicri:noRegion>33615 Bielefeld</wicri:noRegion></affiliation></author><author><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 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25</wicri:noRegion><wicri:noRegion>33615 Bielefeld</wicri:noRegion></affiliation></author><author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Université de Lorraine</orgName></affiliation></author><author><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Université de Lorraine</orgName></affiliation></author><author><name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Université de Lorraine</orgName></affiliation></author><author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Université de Lorraine</orgName><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation></author><author><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1><s2>33615 Bielefeld</s2><s3>DEU</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Allemagne</country><wicri:noRegion>33615 Bielefeld</wicri:noRegion><wicri:noRegion>Universitätsstrasse 25</wicri:noRegion><wicri:noRegion>33615 Bielefeld</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Combustion and flame</title><title level="j" type="abbreviated">Combust. flame</title><idno type="ISSN">0010-2180</idno><imprint><date when="2014">2014</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Combustion and flame</title><title level="j" type="abbreviated">Combust. flame</title><idno type="ISSN">0010-2180</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term><term>Combustion</term><term>Flame structure</term><term>Furan derivatives</term><term>Gas chromatography</term><term>Kinetic model</term><term>Low pressure</term><term>Mass spectrometry</term><term>Modeling</term><term>Molecular beam</term><term>Operating conditions</term><term>Reaction mechanism</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Combustion</term><term>Structure flamme</term><term>Spectrométrie masse</term><term>Dérivé du furane</term><term>Biocarburant</term><term>Mécanisme réaction</term><term>Faisceau moléculaire</term><term>Chromatographie phase gazeuse</term><term>Basse pression</term><term>Modèle cinétique</term><term>Condition opératoire</term><term>Modélisation</term><term>Furane(2,5-diméthyl)</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0010-2180</s0></fA01><fA02 i1="01"><s0>CBFMAO</s0></fA02><fA03 i2="1"><s0>Combust. flame</s0></fA03><fA05><s2>161</s2></fA05><fA06><s2>3</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>Special Issue on Alternative Fuels</s1></fA09><fA11 i1="01" i2="1"><s1>TOGBE (Casimir)</s1></fA11><fA11 i1="02" i2="1"><s1>TRAN (Luc-Sy)</s1></fA11><fA11 i1="03" i2="1"><s1>DONG LIU</s1></fA11><fA11 i1="04" i2="1"><s1>FELSMANN (Daniel)</s1></fA11><fA11 i1="05" i2="1"><s1>OSSWALD (Patrick)</s1></fA11><fA11 i1="06" i2="1"><s1>GLAUDE (Pierre-Alexandre)</s1></fA11><fA11 i1="07" i2="1"><s1>SIRJEAN (Baptiste)</s1></fA11><fA11 i1="08" i2="1"><s1>FOURNET (René)</s1></fA11><fA11 i1="09" i2="1"><s1>BATTIN-LECLERC (Frédérique)</s1></fA11><fA11 i1="10" i2="1"><s1>KOHSE-HÖINGHAUS (Katharina)</s1></fA11><fA12 i1="01" i2="1"><s1>DAGAUT (Philippe)</s1><s9>limin.</s9></fA12><fA12 i1="02" i2="1"><s1>EGOLFOPOULOS (Fokion N.)</s1><s9>limin.</s9></fA12><fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1><s2>33615 Bielefeld</s2><s3>DEU</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>10 aut.</sZ></fA14><fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1><s2>54001 Nancy</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></fA14><fA15 i1="01"><s1>Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique</s1><s2>45071 Orléans</s2><s3>FRA</s3><sZ>1 aut.</sZ></fA15><fA15 i1="02"><s1>Department of Aerospace and Mechanical Engineering, University of Southern California</s1><s2>Los Angeles, CA 90089-1453</s2><s3>USA</s3><sZ>2 aut.</sZ></fA15><fA20><s1>780-797</s1></fA20><fA21><s1>2014</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>8319</s2><s5>354000506152860120</s5></fA43><fA44><s0>0000</s0><s1>© 2014 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>52 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>14-0107739</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Combustion and flame</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</s0></fC01><fC02 i1="01" i2="X"><s0>002A31D04A</s0></fC02><fC02 i1="02" i2="X"><s0>001D06B06E</s0></fC02><fC02 i1="03" i2="X"><s0>001C04B01</s0></fC02><fC02 i1="04" i2="X"><s0>215</s0></fC02><fC02 i1="05" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Combustion</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Combustion</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Combustión</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Structure flamme</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Flame structure</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Estructura llama</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Spectrométrie masse</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Mass spectrometry</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Espectrometría masa</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Dérivé du furane</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Furan derivatives</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Furano derivado</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Biocarburant</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Biofuel</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Biocarburante</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Mécanisme réaction</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Reaction mechanism</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Mecanismo reacción</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Faisceau moléculaire</s0><s5>08</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Molecular beam</s0><s5>08</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Haz molecular</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Chromatographie phase gazeuse</s0><s5>09</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Gas chromatography</s0><s5>09</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Cromatografía fase gaseosa</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Basse pression</s0><s5>10</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Low pressure</s0><s5>10</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Baja presión</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Modèle cinétique</s0><s5>12</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Kinetic model</s0><s5>12</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Modelo cinético</s0><s5>12</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Condition opératoire</s0><s5>32</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Operating conditions</s0><s5>32</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Condición operatoria</s0><s5>32</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Modélisation</s0><s5>33</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Modeling</s0><s5>33</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Modelización</s0><s5>33</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Furane(2,5-diméthyl)</s0><s2>NK</s2><s4>INC</s4><s5>76</s5></fC03><fN21><s1>146</s1></fN21></pA></standard></inist><affiliations><list><country><li>Allemagne</li><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Université de Lorraine</li></orgName></list><tree><country name="Allemagne"><noRegion><name sortKey="Togbe, Casimir" sort="Togbe, Casimir" uniqKey="Togbe C" first="Casimir" last="Togbe">Casimir Togbe</name></noRegion><name sortKey="Dong Liu" sort="Dong Liu" uniqKey="Dong Liu" last="Dong Liu">DONG LIU</name><name sortKey="Felsmann, Daniel" sort="Felsmann, Daniel" uniqKey="Felsmann D" first="Daniel" last="Felsmann">Daniel Felsmann</name><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name><name sortKey="Osswald, Patrick" sort="Osswald, Patrick" uniqKey="Osswald P" first="Patrick" last="Osswald">Patrick Osswald</name></country><country name="France"><region name="Grand Est"><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name></region><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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