Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Identifieur interne : 000028 ( PascalFrancis/Checkpoint ); précédent : 000027; suivant : 000029Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Auteurs : Casimir Togbe [Allemagne] ; Luc-Sy Tran [France] ; DONG LIU [Allemagne] ; Daniel Felsmann [Allemagne] ; Patrick Osswald [Allemagne] ; Pierre-Alexandre Glaude [France] ; Baptiste Sirjean [France] ; René Fournet [France] ; Frédérique Battin-Leclerc [France] ; Katharina Kohse-Höinghaus [Allemagne]Source :
- Combustion and flame [ 0010-2180 ] ; 2014.
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Abstract
This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
Affiliations:
- Allemagne, France
- Grand Est, Lorraine (région)
- Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term>
<term>Combustion</term>
<term>Flame structure</term>
<term>Furan derivatives</term>
<term>Gas chromatography</term>
<term>Kinetic model</term>
<term>Low pressure</term>
<term>Mass spectrometry</term>
<term>Modeling</term>
<term>Molecular beam</term>
<term>Operating conditions</term>
<term>Reaction mechanism</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Combustion</term>
<term>Structure flamme</term>
<term>Spectrométrie masse</term>
<term>Dérivé du furane</term>
<term>Biocarburant</term>
<term>Mécanisme réaction</term>
<term>Faisceau moléculaire</term>
<term>Chromatographie phase gazeuse</term>
<term>Basse pression</term>
<term>Modèle cinétique</term>
<term>Condition opératoire</term>
<term>Modélisation</term>
<term>Furane(2,5-diméthyl)</term>
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<front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0010-2180</s0>
</fA01>
<fA02 i1="01"><s0>CBFMAO</s0>
</fA02>
<fA03 i2="1"><s0>Combust. flame</s0>
</fA03>
<fA05><s2>161</s2>
</fA05>
<fA06><s2>3</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</s1>
</fA08>
<fA09 i1="01" i2="1" l="ENG"><s1>Special Issue on Alternative Fuels</s1>
</fA09>
<fA11 i1="01" i2="1"><s1>TOGBE (Casimir)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>TRAN (Luc-Sy)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>DONG LIU</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>FELSMANN (Daniel)</s1>
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<fA11 i1="05" i2="1"><s1>OSSWALD (Patrick)</s1>
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<fA11 i1="06" i2="1"><s1>GLAUDE (Pierre-Alexandre)</s1>
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<fA11 i1="07" i2="1"><s1>SIRJEAN (Baptiste)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>FOURNET (René)</s1>
</fA11>
<fA11 i1="09" i2="1"><s1>BATTIN-LECLERC (Frédérique)</s1>
</fA11>
<fA11 i1="10" i2="1"><s1>KOHSE-HÖINGHAUS (Katharina)</s1>
</fA11>
<fA12 i1="01" i2="1"><s1>DAGAUT (Philippe)</s1>
<s9>limin.</s9>
</fA12>
<fA12 i1="02" i2="1"><s1>EGOLFOPOULOS (Fokion N.)</s1>
<s9>limin.</s9>
</fA12>
<fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1>
<s2>33615 Bielefeld</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>10 aut.</sZ>
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<fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
<sZ>9 aut.</sZ>
</fA14>
<fA15 i1="01"><s1>Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique</s1>
<s2>45071 Orléans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
</fA15>
<fA15 i1="02"><s1>Department of Aerospace and Mechanical Engineering, University of Southern California</s1>
<s2>Los Angeles, CA 90089-1453</s2>
<s3>USA</s3>
<sZ>2 aut.</sZ>
</fA15>
<fA20><s1>780-797</s1>
</fA20>
<fA21><s1>2014</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>8319</s2>
<s5>354000506152860120</s5>
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<fA44><s0>0000</s0>
<s1>© 2014 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>52 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>14-0107739</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Combustion and flame</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>002A31D04A</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001D06B06E</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>001C04B01</s0>
</fC02>
<fC02 i1="04" i2="X"><s0>215</s0>
</fC02>
<fC02 i1="05" i2="X"><s0>230</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Combustion</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Combustion</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Combustión</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Structure flamme</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Flame structure</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Estructura llama</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Spectrométrie masse</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Mass spectrometry</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Espectrometría masa</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Dérivé du furane</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Furan derivatives</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Furano derivado</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Biocarburant</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Biofuel</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Biocarburante</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Mécanisme réaction</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Reaction mechanism</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Mecanismo reacción</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Faisceau moléculaire</s0>
<s5>08</s5>
</fC03>
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<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Haz molecular</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Chromatographie phase gazeuse</s0>
<s5>09</s5>
</fC03>
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<s5>09</s5>
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<fC03 i1="08" i2="X" l="SPA"><s0>Cromatografía fase gaseosa</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Basse pression</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Low pressure</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Baja presión</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Modèle cinétique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Kinetic model</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Modelo cinético</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Condition opératoire</s0>
<s5>32</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Operating conditions</s0>
<s5>32</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Condición operatoria</s0>
<s5>32</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Modélisation</s0>
<s5>33</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Modeling</s0>
<s5>33</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Modelización</s0>
<s5>33</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Furane(2,5-diméthyl)</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>76</s5>
</fC03>
<fN21><s1>146</s1>
</fN21>
</pA>
</standard>
</inist>
<affiliations><list><country><li>Allemagne</li>
<li>France</li>
</country>
<region><li>Grand Est</li>
<li>Lorraine (région)</li>
</region>
<settlement><li>Nancy</li>
</settlement>
<orgName><li>Centre national de la recherche scientifique</li>
<li>Laboratoire réactions et génie des procédés</li>
<li>Université de Lorraine</li>
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</list>
<tree><country name="Allemagne"><noRegion><name sortKey="Togbe, Casimir" sort="Togbe, Casimir" uniqKey="Togbe C" first="Casimir" last="Togbe">Casimir Togbe</name>
</noRegion>
<name sortKey="Dong Liu" sort="Dong Liu" uniqKey="Dong Liu" last="Dong Liu">DONG LIU</name>
<name sortKey="Felsmann, Daniel" sort="Felsmann, Daniel" uniqKey="Felsmann D" first="Daniel" last="Felsmann">Daniel Felsmann</name>
<name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
<name sortKey="Osswald, Patrick" sort="Osswald, Patrick" uniqKey="Osswald P" first="Patrick" last="Osswald">Patrick Osswald</name>
</country>
<country name="France"><region name="Grand Est"><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name>
</region>
<name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name>
<name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name>
<name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name>
</country>
</tree>
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