LrgpV1, PascalFrancis, Curation, bibRecord, 000A83

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Identifieur interne : 000A83 ( PascalFrancis/Curation ); précédent : 000A82; suivant : 000A84

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Auteurs : Casimir Togbe [Allemagne] ; Luc-Sy Tran [France] ; DONG LIU [Allemagne] ; Daniel Felsmann [Allemagne] ; Patrick Osswald [Allemagne] ; Pierre-Alexandre Glaude [France] ; Baptiste Sirjean [France] ; René Fournet [France] ; Frédérique Battin-Leclerc [France] ; Katharina Kohse-Höinghaus [Allemagne]

Source :

Combustion and flame [ 0010-2180 ] ; 2014.

RBID : Pascal:14-0107739

Descripteurs français

Pascal (Inist)
- Combustion, Structure flamme, Spectrométrie masse, Dérivé du furane, Biocarburant, Mécanisme réaction, Faisceau moléculaire, Chromatographie phase gazeuse, Basse pression, Modèle cinétique, Condition opératoire, Modélisation, Furane(2,5-diméthyl).

English descriptors

KwdEn :
- Biofuel, Combustion, Flame structure, Furan derivatives, Gas chromatography, Kinetic model, Low pressure, Mass spectrometry, Modeling, Molecular beam, Operating conditions, Reaction mechanism.

Abstract

This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.

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A08	`01`	`1`	`ENG`	`@1 Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran`
A09	`01`	`1`	`ENG`	`@1 Special Issue on Alternative Fuels`
A11	`01`	`1`		`@1 TOGBE (Casimir)`
A11	`02`	`1`		`@1 TRAN (Luc-Sy)`
A11	`03`	`1`		`@1 DONG LIU`
A11	`04`	`1`		`@1 FELSMANN (Daniel)`
A11	`05`	`1`		`@1 OSSWALD (Patrick)`
A11	`06`	`1`		`@1 GLAUDE (Pierre-Alexandre)`
A11	`07`	`1`		`@1 SIRJEAN (Baptiste)`
A11	`08`	`1`		`@1 FOURNET (René)`
A11	`09`	`1`		`@1 BATTIN-LECLERC (Frédérique)`
A11	`10`	`1`		`@1 KOHSE-HÖINGHAUS (Katharina)`
A12	`01`	`1`		`@1 DAGAUT (Philippe) @9 limin.`
A12	`02`	`1`		`@1 EGOLFOPOULOS (Fokion N.) @9 limin.`
A14	`01`			`@1 Department of Chemistry, Bielefeld University, Universitätsstrasse 25 @2 33615 Bielefeld @3 DEU @Z 1 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut. @Z 10 aut.`
A14	`02`			`@1 Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451 @2 54001 Nancy @3 FRA @Z 2 aut. @Z 6 aut. @Z 7 aut. @Z 8 aut. @Z 9 aut.`
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A15	`02`			`@1 Department of Aerospace and Mechanical Engineering, University of Southern California @2 Los Angeles, CA 90089-1453 @3 USA @Z 2 aut.`
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A21				`@1 2014`
A23	`01`			`@0 ENG`
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C01	`01`		`ENG`	@0 This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
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C02	`04`	`X`		`@0 215`
C02	`05`	`X`		`@0 230`
C03	`01`	`X`	`FRE`	`@0 Combustion @5 01`
C03	`01`	`X`	`ENG`	`@0 Combustion @5 01`
C03	`01`	`X`	`SPA`	`@0 Combustión @5 01`
C03	`02`	`X`	`FRE`	`@0 Structure flamme @5 02`
C03	`02`	`X`	`ENG`	`@0 Flame structure @5 02`
C03	`02`	`X`	`SPA`	`@0 Estructura llama @5 02`
C03	`03`	`X`	`FRE`	`@0 Spectrométrie masse @5 03`
C03	`03`	`X`	`ENG`	`@0 Mass spectrometry @5 03`
C03	`03`	`X`	`SPA`	`@0 Espectrometría masa @5 03`
C03	`04`	`X`	`FRE`	`@0 Dérivé du furane @5 04`
C03	`04`	`X`	`ENG`	`@0 Furan derivatives @5 04`
C03	`04`	`X`	`SPA`	`@0 Furano derivado @5 04`
C03	`05`	`X`	`FRE`	`@0 Biocarburant @5 05`
C03	`05`	`X`	`ENG`	`@0 Biofuel @5 05`
C03	`05`	`X`	`SPA`	`@0 Biocarburante @5 05`
C03	`06`	`X`	`FRE`	`@0 Mécanisme réaction @5 06`
C03	`06`	`X`	`ENG`	`@0 Reaction mechanism @5 06`
C03	`06`	`X`	`SPA`	`@0 Mecanismo reacción @5 06`
C03	`07`	`X`	`FRE`	`@0 Faisceau moléculaire @5 08`
C03	`07`	`X`	`ENG`	`@0 Molecular beam @5 08`
C03	`07`	`X`	`SPA`	`@0 Haz molecular @5 08`
C03	`08`	`X`	`FRE`	`@0 Chromatographie phase gazeuse @5 09`
C03	`08`	`X`	`ENG`	`@0 Gas chromatography @5 09`
C03	`08`	`X`	`SPA`	`@0 Cromatografía fase gaseosa @5 09`
C03	`09`	`X`	`FRE`	`@0 Basse pression @5 10`
C03	`09`	`X`	`ENG`	`@0 Low pressure @5 10`
C03	`09`	`X`	`SPA`	`@0 Baja presión @5 10`
C03	`10`	`X`	`FRE`	`@0 Modèle cinétique @5 12`
C03	`10`	`X`	`ENG`	`@0 Kinetic model @5 12`
C03	`10`	`X`	`SPA`	`@0 Modelo cinético @5 12`
C03	`11`	`X`	`FRE`	`@0 Condition opératoire @5 32`
C03	`11`	`X`	`ENG`	`@0 Operating conditions @5 32`
C03	`11`	`X`	`SPA`	`@0 Condición operatoria @5 32`
C03	`12`	`X`	`FRE`	`@0 Modélisation @5 33`
C03	`12`	`X`	`ENG`	`@0 Modeling @5 33`
C03	`12`	`X`	`SPA`	`@0 Modelización @5 33`
C03	`13`	`X`	`FRE`	`@0 Furane(2,5-diméthyl) @2 NK @4 INC @5 76`
N21				`@1 146`

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Le document en format XML

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<author><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</title>
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<author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name>
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<author><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name>
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<author><name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
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<country>France</country>
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<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
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<country>France</country>
</affiliation>
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<author><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1>
<s2>33615 Bielefeld</s2>
<s3>DEU</s3>
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<series><title level="j" type="main">Combustion and flame</title>
<title level="j" type="abbreviated">Combust. flame</title>
<idno type="ISSN">0010-2180</idno>
<imprint><date when="2014">2014</date>
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<seriesStmt><title level="j" type="main">Combustion and flame</title>
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<idno type="ISSN">0010-2180</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term>
<term>Combustion</term>
<term>Flame structure</term>
<term>Furan derivatives</term>
<term>Gas chromatography</term>
<term>Kinetic model</term>
<term>Low pressure</term>
<term>Mass spectrometry</term>
<term>Modeling</term>
<term>Molecular beam</term>
<term>Operating conditions</term>
<term>Reaction mechanism</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Combustion</term>
<term>Structure flamme</term>
<term>Spectrométrie masse</term>
<term>Dérivé du furane</term>
<term>Biocarburant</term>
<term>Mécanisme réaction</term>
<term>Faisceau moléculaire</term>
<term>Chromatographie phase gazeuse</term>
<term>Basse pression</term>
<term>Modèle cinétique</term>
<term>Condition opératoire</term>
<term>Modélisation</term>
<term>Furane(2,5-diméthyl)</term>
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<front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div>
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<fC02 i1="03" i2="X"><s0>001C04B01</s0>
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<fC02 i1="04" i2="X"><s0>215</s0>
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<fC02 i1="05" i2="X"><s0>230</s0>
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<s5>12</s5>
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Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

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