Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Identifieur interne : 000026 ( PascalFrancis/Corpus ); précédent : 000025; suivant : 000027Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
Auteurs : Casimir Togbe ; Luc-Sy Tran ; DONG LIU ; Daniel Felsmann ; Patrick Osswald ; Pierre-Alexandre Glaude ; Baptiste Sirjean ; René Fournet ; Frédérique Battin-Leclerc ; Katharina Kohse-HöinghausSource :
- Combustion and flame [ 0010-2180 ] ; 2014.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
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Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 14-0107739 INIST |
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ET : | Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran |
AU : | TOGBE (Casimir); TRAN (Luc-Sy); DONG LIU; FELSMANN (Daniel); OSSWALD (Patrick); GLAUDE (Pierre-Alexandre); SIRJEAN (Baptiste); FOURNET (René); BATTIN-LECLERC (Frédérique); KOHSE-HÖINGHAUS (Katharina); DAGAUT (Philippe); EGOLFOPOULOS (Fokion N.) |
AF : | Department of Chemistry, Bielefeld University, Universitätsstrasse 25/33615 Bielefeld/Allemagne (1 aut., 3 aut., 4 aut., 5 aut., 10 aut.); Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451/54001 Nancy/France (2 aut., 6 aut., 7 aut., 8 aut., 9 aut.); Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique/45071 Orléans/France (1 aut.); Department of Aerospace and Mechanical Engineering, University of Southern California/Los Angeles, CA 90089-1453/Etats-Unis (2 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Combustion and flame; ISSN 0010-2180; Coden CBFMAO; Pays-Bas; Da. 2014; Vol. 161; No. 3; Pp. 780-797; Bibl. 52 ref. |
LA : | Anglais |
EA : | This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model. |
CC : | 002A31D04A; 001D06B06E; 001C04B01; 215; 230 |
FD : | Combustion; Structure flamme; Spectrométrie masse; Dérivé du furane; Biocarburant; Mécanisme réaction; Faisceau moléculaire; Chromatographie phase gazeuse; Basse pression; Modèle cinétique; Condition opératoire; Modélisation; Furane(2,5-diméthyl) |
ED : | Combustion; Flame structure; Mass spectrometry; Furan derivatives; Biofuel; Reaction mechanism; Molecular beam; Gas chromatography; Low pressure; Kinetic model; Operating conditions; Modeling |
SD : | Combustión; Estructura llama; Espectrometría masa; Furano derivado; Biocarburante; Mecanismo reacción; Haz molecular; Cromatografía fase gaseosa; Baja presión; Modelo cinético; Condición operatoria; Modelización |
LO : | INIST-8319.354000506152860120 |
ID : | 14-0107739 |
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Pascal:14-0107739Le document en format XML
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term>
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<term>Flame structure</term>
<term>Furan derivatives</term>
<term>Gas chromatography</term>
<term>Kinetic model</term>
<term>Low pressure</term>
<term>Mass spectrometry</term>
<term>Modeling</term>
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<term>Biocarburant</term>
<term>Mécanisme réaction</term>
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<front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div>
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<sZ>2 aut.</sZ>
</fA15>
<fA20><s1>780-797</s1>
</fA20>
<fA21><s1>2014</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>8319</s2>
<s5>354000506152860120</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2014 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>52 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>14-0107739</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Combustion and flame</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>002A31D04A</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001D06B06E</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>001C04B01</s0>
</fC02>
<fC02 i1="04" i2="X"><s0>215</s0>
</fC02>
<fC02 i1="05" i2="X"><s0>230</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Combustion</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Combustion</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Combustión</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Structure flamme</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Flame structure</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Estructura llama</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Spectrométrie masse</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Mass spectrometry</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Espectrometría masa</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Dérivé du furane</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Furan derivatives</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Furano derivado</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Biocarburant</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Biofuel</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Biocarburante</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Mécanisme réaction</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Reaction mechanism</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Mecanismo reacción</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Faisceau moléculaire</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Molecular beam</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Haz molecular</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Chromatographie phase gazeuse</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Gas chromatography</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Cromatografía fase gaseosa</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Basse pression</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Low pressure</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Baja presión</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Modèle cinétique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Kinetic model</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Modelo cinético</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Condition opératoire</s0>
<s5>32</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Operating conditions</s0>
<s5>32</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Condición operatoria</s0>
<s5>32</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Modélisation</s0>
<s5>33</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Modeling</s0>
<s5>33</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Modelización</s0>
<s5>33</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Furane(2,5-diméthyl)</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>76</s5>
</fC03>
<fN21><s1>146</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 14-0107739 INIST</NO>
<ET>Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</ET>
<AU>TOGBE (Casimir); TRAN (Luc-Sy); DONG LIU; FELSMANN (Daniel); OSSWALD (Patrick); GLAUDE (Pierre-Alexandre); SIRJEAN (Baptiste); FOURNET (René); BATTIN-LECLERC (Frédérique); KOHSE-HÖINGHAUS (Katharina); DAGAUT (Philippe); EGOLFOPOULOS (Fokion N.)</AU>
<AF>Department of Chemistry, Bielefeld University, Universitätsstrasse 25/33615 Bielefeld/Allemagne (1 aut., 3 aut., 4 aut., 5 aut., 10 aut.); Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451/54001 Nancy/France (2 aut., 6 aut., 7 aut., 8 aut., 9 aut.); Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique/45071 Orléans/France (1 aut.); Department of Aerospace and Mechanical Engineering, University of Southern California/Los Angeles, CA 90089-1453/Etats-Unis (2 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Combustion and flame; ISSN 0010-2180; Coden CBFMAO; Pays-Bas; Da. 2014; Vol. 161; No. 3; Pp. 780-797; Bibl. 52 ref.</SO>
<LA>Anglais</LA>
<EA>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</EA>
<CC>002A31D04A; 001D06B06E; 001C04B01; 215; 230</CC>
<FD>Combustion; Structure flamme; Spectrométrie masse; Dérivé du furane; Biocarburant; Mécanisme réaction; Faisceau moléculaire; Chromatographie phase gazeuse; Basse pression; Modèle cinétique; Condition opératoire; Modélisation; Furane(2,5-diméthyl)</FD>
<ED>Combustion; Flame structure; Mass spectrometry; Furan derivatives; Biofuel; Reaction mechanism; Molecular beam; Gas chromatography; Low pressure; Kinetic model; Operating conditions; Modeling</ED>
<SD>Combustión; Estructura llama; Espectrometría masa; Furano derivado; Biocarburante; Mecanismo reacción; Haz molecular; Cromatografía fase gaseosa; Baja presión; Modelo cinético; Condición operatoria; Modelización</SD>
<LO>INIST-8319.354000506152860120</LO>
<ID>14-0107739</ID>
</server>
</inist>
</record>
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