LrgpV1, PascalFrancis, Corpus, bibRecord, 000026

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Identifieur interne : 000026 ( PascalFrancis/Corpus ); précédent : 000025; suivant : 000027

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Auteurs : Casimir Togbe ; Luc-Sy Tran ; DONG LIU ; Daniel Felsmann ; Patrick Osswald ; Pierre-Alexandre Glaude ; Baptiste Sirjean ; René Fournet ; Frédérique Battin-Leclerc ; Katharina Kohse-Höinghaus

Source :

Combustion and flame [ 0010-2180 ] ; 2014.

RBID : Pascal:14-0107739

Descripteurs français

Pascal (Inist)
- Combustion, Structure flamme, Spectrométrie masse, Dérivé du furane, Biocarburant, Mécanisme réaction, Faisceau moléculaire, Chromatographie phase gazeuse, Basse pression, Modèle cinétique, Condition opératoire, Modélisation, Furane(2,5-diméthyl).

English descriptors

KwdEn :
- Biofuel, Combustion, Flame structure, Furan derivatives, Gas chromatography, Kinetic model, Low pressure, Mass spectrometry, Modeling, Molecular beam, Operating conditions, Reaction mechanism.

Abstract

This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

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A08	`01`	`1`	`ENG`	`@1 Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran`
A09	`01`	`1`	`ENG`	`@1 Special Issue on Alternative Fuels`
A11	`01`	`1`		`@1 TOGBE (Casimir)`
A11	`02`	`1`		`@1 TRAN (Luc-Sy)`
A11	`03`	`1`		`@1 DONG LIU`
A11	`04`	`1`		`@1 FELSMANN (Daniel)`
A11	`05`	`1`		`@1 OSSWALD (Patrick)`
A11	`06`	`1`		`@1 GLAUDE (Pierre-Alexandre)`
A11	`07`	`1`		`@1 SIRJEAN (Baptiste)`
A11	`08`	`1`		`@1 FOURNET (René)`
A11	`09`	`1`		`@1 BATTIN-LECLERC (Frédérique)`
A11	`10`	`1`		`@1 KOHSE-HÖINGHAUS (Katharina)`
A12	`01`	`1`		`@1 DAGAUT (Philippe) @9 limin.`
A12	`02`	`1`		`@1 EGOLFOPOULOS (Fokion N.) @9 limin.`
A14	`01`			`@1 Department of Chemistry, Bielefeld University, Universitätsstrasse 25 @2 33615 Bielefeld @3 DEU @Z 1 aut. @Z 3 aut. @Z 4 aut. @Z 5 aut. @Z 10 aut.`
A14	`02`			`@1 Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451 @2 54001 Nancy @3 FRA @Z 2 aut. @Z 6 aut. @Z 7 aut. @Z 8 aut. @Z 9 aut.`
A15	`01`			`@1 Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique @2 45071 Orléans @3 FRA @Z 1 aut.`
A15	`02`			`@1 Department of Aerospace and Mechanical Engineering, University of Southern California @2 Los Angeles, CA 90089-1453 @3 USA @Z 2 aut.`
A20				`@1 780-797`
A21				`@1 2014`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 8319 @5 354000506152860120`
A44				`@0 0000 @1 © 2014 INIST-CNRS. All rights reserved.`
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A64	`01`	`1`		`@0 Combustion and flame`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
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C02	`03`	`X`		`@0 001C04B01`
C02	`04`	`X`		`@0 215`
C02	`05`	`X`		`@0 230`
C03	`01`	`X`	`FRE`	`@0 Combustion @5 01`
C03	`01`	`X`	`ENG`	`@0 Combustion @5 01`
C03	`01`	`X`	`SPA`	`@0 Combustión @5 01`
C03	`02`	`X`	`FRE`	`@0 Structure flamme @5 02`
C03	`02`	`X`	`ENG`	`@0 Flame structure @5 02`
C03	`02`	`X`	`SPA`	`@0 Estructura llama @5 02`
C03	`03`	`X`	`FRE`	`@0 Spectrométrie masse @5 03`
C03	`03`	`X`	`ENG`	`@0 Mass spectrometry @5 03`
C03	`03`	`X`	`SPA`	`@0 Espectrometría masa @5 03`
C03	`04`	`X`	`FRE`	`@0 Dérivé du furane @5 04`
C03	`04`	`X`	`ENG`	`@0 Furan derivatives @5 04`
C03	`04`	`X`	`SPA`	`@0 Furano derivado @5 04`
C03	`05`	`X`	`FRE`	`@0 Biocarburant @5 05`
C03	`05`	`X`	`ENG`	`@0 Biofuel @5 05`
C03	`05`	`X`	`SPA`	`@0 Biocarburante @5 05`
C03	`06`	`X`	`FRE`	`@0 Mécanisme réaction @5 06`
C03	`06`	`X`	`ENG`	`@0 Reaction mechanism @5 06`
C03	`06`	`X`	`SPA`	`@0 Mecanismo reacción @5 06`
C03	`07`	`X`	`FRE`	`@0 Faisceau moléculaire @5 08`
C03	`07`	`X`	`ENG`	`@0 Molecular beam @5 08`
C03	`07`	`X`	`SPA`	`@0 Haz molecular @5 08`
C03	`08`	`X`	`FRE`	`@0 Chromatographie phase gazeuse @5 09`
C03	`08`	`X`	`ENG`	`@0 Gas chromatography @5 09`
C03	`08`	`X`	`SPA`	`@0 Cromatografía fase gaseosa @5 09`
C03	`09`	`X`	`FRE`	`@0 Basse pression @5 10`
C03	`09`	`X`	`ENG`	`@0 Low pressure @5 10`
C03	`09`	`X`	`SPA`	`@0 Baja presión @5 10`
C03	`10`	`X`	`FRE`	`@0 Modèle cinétique @5 12`
C03	`10`	`X`	`ENG`	`@0 Kinetic model @5 12`
C03	`10`	`X`	`SPA`	`@0 Modelo cinético @5 12`
C03	`11`	`X`	`FRE`	`@0 Condition opératoire @5 32`
C03	`11`	`X`	`ENG`	`@0 Operating conditions @5 32`
C03	`11`	`X`	`SPA`	`@0 Condición operatoria @5 32`
C03	`12`	`X`	`FRE`	`@0 Modélisation @5 33`
C03	`12`	`X`	`ENG`	`@0 Modeling @5 33`
C03	`12`	`X`	`SPA`	`@0 Modelización @5 33`
C03	`13`	`X`	`FRE`	`@0 Furane(2,5-diméthyl) @2 NK @4 INC @5 76`
N21				`@1 146`

Format Inist (serveur)

NO :	PASCAL 14-0107739 INIST
ET :	Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran
AU :	TOGBE (Casimir); TRAN (Luc-Sy); DONG LIU; FELSMANN (Daniel); OSSWALD (Patrick); GLAUDE (Pierre-Alexandre); SIRJEAN (Baptiste); FOURNET (René); BATTIN-LECLERC (Frédérique); KOHSE-HÖINGHAUS (Katharina); DAGAUT (Philippe); EGOLFOPOULOS (Fokion N.)
AF :	Department of Chemistry, Bielefeld University, Universitätsstrasse 25/33615 Bielefeld/Allemagne (1 aut., 3 aut., 4 aut., 5 aut., 10 aut.); Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451/54001 Nancy/France (2 aut., 6 aut., 7 aut., 8 aut., 9 aut.); Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique/45071 Orléans/France (1 aut.); Department of Aerospace and Mechanical Engineering, University of Southern California/Los Angeles, CA 90089-1453/Etats-Unis (2 aut.)
DT :	Publication en série; Niveau analytique
SO :	Combustion and flame; ISSN 0010-2180; Coden CBFMAO; Pays-Bas; Da. 2014; Vol. 161; No. 3; Pp. 780-797; Bibl. 52 ref.
LA :	Anglais
EA :	This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.
CC :	002A31D04A; 001D06B06E; 001C04B01; 215; 230
FD :	Combustion; Structure flamme; Spectrométrie masse; Dérivé du furane; Biocarburant; Mécanisme réaction; Faisceau moléculaire; Chromatographie phase gazeuse; Basse pression; Modèle cinétique; Condition opératoire; Modélisation; Furane(2,5-diméthyl)
ED :	Combustion; Flame structure; Mass spectrometry; Furan derivatives; Biofuel; Reaction mechanism; Molecular beam; Gas chromatography; Low pressure; Kinetic model; Operating conditions; Modeling
SD :	Combustión; Estructura llama; Espectrometría masa; Furano derivado; Biocarburante; Mecanismo reacción; Haz molecular; Cromatografía fase gaseosa; Baja presión; Modelo cinético; Condición operatoria; Modelización
LO :	INIST-8319.354000506152860120
ID :	14-0107739

Links to Exploration step

Pascal:14-0107739

Le document en format XML

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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</title>
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<author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name>
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<author><name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name>
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<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<affiliation><inist:fA14 i1="02"><s1>Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451</s1>
<s2>54001 Nancy</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
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<sZ>7 aut.</sZ>
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<author><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
<affiliation><inist:fA14 i1="01"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1>
<s2>33615 Bielefeld</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
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<series><title level="j" type="main">Combustion and flame</title>
<title level="j" type="abbreviated">Combust. flame</title>
<idno type="ISSN">0010-2180</idno>
<imprint><date when="2014">2014</date>
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<seriesStmt><title level="j" type="main">Combustion and flame</title>
<title level="j" type="abbreviated">Combust. flame</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term>
<term>Combustion</term>
<term>Flame structure</term>
<term>Furan derivatives</term>
<term>Gas chromatography</term>
<term>Kinetic model</term>
<term>Low pressure</term>
<term>Mass spectrometry</term>
<term>Modeling</term>
<term>Molecular beam</term>
<term>Operating conditions</term>
<term>Reaction mechanism</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Combustion</term>
<term>Structure flamme</term>
<term>Spectrométrie masse</term>
<term>Dérivé du furane</term>
<term>Biocarburant</term>
<term>Mécanisme réaction</term>
<term>Faisceau moléculaire</term>
<term>Chromatographie phase gazeuse</term>
<term>Basse pression</term>
<term>Modèle cinétique</term>
<term>Condition opératoire</term>
<term>Modélisation</term>
<term>Furane(2,5-diméthyl)</term>
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<front><div type="abstract" xml:lang="en">This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</div>
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<fA15 i1="02"><s1>Department of Aerospace and Mechanical Engineering, University of Southern California</s1>
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<sZ>2 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</s0>
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<fC02 i1="02" i2="X"><s0>001D06B06E</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>001C04B01</s0>
</fC02>
<fC02 i1="04" i2="X"><s0>215</s0>
</fC02>
<fC02 i1="05" i2="X"><s0>230</s0>
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<s5>09</s5>
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<s5>10</s5>
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<fC03 i1="09" i2="X" l="ENG"><s0>Low pressure</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Baja presión</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Modèle cinétique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Kinetic model</s0>
<s5>12</s5>
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<fC03 i1="10" i2="X" l="SPA"><s0>Modelo cinético</s0>
<s5>12</s5>
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<fC03 i1="11" i2="X" l="FRE"><s0>Condition opératoire</s0>
<s5>32</s5>
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<fC03 i1="11" i2="X" l="ENG"><s0>Operating conditions</s0>
<s5>32</s5>
</fC03>
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<s5>32</s5>
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<s5>33</s5>
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<s5>33</s5>
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<server><NO>PASCAL 14-0107739 INIST</NO>
<ET>Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran</ET>
<AU>TOGBE (Casimir); TRAN (Luc-Sy); DONG LIU; FELSMANN (Daniel); OSSWALD (Patrick); GLAUDE (Pierre-Alexandre); SIRJEAN (Baptiste); FOURNET (René); BATTIN-LECLERC (Frédérique); KOHSE-HÖINGHAUS (Katharina); DAGAUT (Philippe); EGOLFOPOULOS (Fokion N.)</AU>
<AF>Department of Chemistry, Bielefeld University, Universitätsstrasse 25/33615 Bielefeld/Allemagne (1 aut., 3 aut., 4 aut., 5 aut., 10 aut.); Laboratoire Reactions et Génie des Procédés (LRGP), CNRS, Université de Lorraine, ENSIC, 1 rue Grandville, BP 20451/54001 Nancy/France (2 aut., 6 aut., 7 aut., 8 aut., 9 aut.); Centre National de la Recherche Scientifique (CNRS-INSIS), 1C, Avenue de la Recherche Scientifique/45071 Orléans/France (1 aut.); Department of Aerospace and Mechanical Engineering, University of Southern California/Los Angeles, CA 90089-1453/Etats-Unis (2 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Combustion and flame; ISSN 0010-2180; Coden CBFMAO; Pays-Bas; Da. 2014; Vol. 161; No. 3; Pp. 780-797; Bibl. 52 ref.</SO>
<LA>Anglais</LA>
<EA>This work is the third part of a study focusing on the combustion chemistry and flame structure of furan and selected alkylated derivatives, i.e. furan in Part I,2-methylfuran (MF) in Part II, and 2,5-dimethylfuran (DMF) in the present work. Two premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of DMF were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) under two equivalence ratios (φ = 1.0 and 1.7). Mole fractions of reactants, products, and stable and radical intermediates were measured as a function of the distance to the burner. Kinetic modeling was performed using a reaction mechanism that was further developed in the present series, including Part I and Part II. A reasonable agreement between the present experimental results and the simulation is observed. The main reaction pathways of DMF consumption were derived from a reaction flow analysis. Also, a comparison of the key features for the three flames is presented, as well as a comparison between these flames of furanic compounds and those of other fuels. An a priori surprising ability of DMF to form soot precursors (e.g. 1,3-cyclopentadiene or benzene) compared to less substituted furans and to other fuels has been experimentally observed and is well explained in the model.</EA>
<CC>002A31D04A; 001D06B06E; 001C04B01; 215; 230</CC>
<FD>Combustion; Structure flamme; Spectrométrie masse; Dérivé du furane; Biocarburant; Mécanisme réaction; Faisceau moléculaire; Chromatographie phase gazeuse; Basse pression; Modèle cinétique; Condition opératoire; Modélisation; Furane(2,5-diméthyl)</FD>
<ED>Combustion; Flame structure; Mass spectrometry; Furan derivatives; Biofuel; Reaction mechanism; Molecular beam; Gas chromatography; Low pressure; Kinetic model; Operating conditions; Modeling</ED>
<SD>Combustión; Estructura llama; Espectrometría masa; Furano derivado; Biocarburante; Mecanismo reacción; Haz molecular; Cromatografía fase gaseosa; Baja presión; Modelo cinético; Condición operatoria; Modelización</SD>
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Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part III: 2,5-Dimethylfuran

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