LrgpV1, Main, Exploration, bibRecord, 000481

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran

Identifieur interne : 000481 ( Main/Exploration ); précédent : 000480; suivant : 000482

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran

Auteurs : Luc-Sy Tran [France] ; Casimir Togbe [Allemagne] ; DONG LIU [Allemagne] ; Daniel Felsmann [Allemagne] ; Patrick Osswald [Allemagne] ; Pierre-Alexandre Glaude [France] ; René Fournet [France] ; Baptiste Sirjean [France] ; Frédérique Battin-Leclerc [France] ; Katharina Kohse-Höinghaus [Allemagne]

Source :

Combustion and flame [ 0010-2180 ] ; 2014.

RBID : Pascal:14-0107774

Descripteurs français

Pascal (Inist)
- Combustion, Structure flamme, Spectrométrie masse, Dérivé du furane, Biocarburant, Mécanisme réaction, Faisceau moléculaire, Chromatographie phase gazeuse, Basse pression, Modèle cinétique, Condition opératoire, Modélisation, Furane(2-méthyl).

English descriptors

KwdEn :
- Biofuel, Combustion, Flame structure, Furan derivatives, Gas chromatography, Kinetic model, Low pressure, Mass spectrometry, Modeling, Molecular beam, Operating conditions, Reaction mechanism.

Abstract

This is Part II of a series of three papers which jointly address the combustion chemistry of furan and its alkylated derivatives 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) under premixed low-pressure flame conditions. Some of them are considered to be promising biofuels. With furan as a common basis studied in Part I of this series, the present paper addresses two laminar premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of MF which were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) for equivalence ratios φ = 1.0 and 1.7, identical conditions to those for the previously reported furan flames. Mole fractions of reactants, products as well as stable and reactive intermediates were measured as a function of the distance above the burner. Kinetic modeling was performed using a comprehensive reaction mechanism for all three fuels given in Part I and described in the three parts of this series. A comparison of the experimental results and the simulation shows reasonable agreement, as also seen for the furan flames in Part I before. This set of experiments is thus considered to be a valuable additional basis for the validation of the model. The main reaction pathways of MF consumption have been derived from reaction flow analyses, and differences to furan combustion chemistry under the same conditions are discussed.

Url:

Affiliations:

Le document en format XML

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</author>
<author><name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Bielefeld University, Universitätsstrasse 25</s1>
<s2>33615 Bielefeld</s2>
<s3>DEU</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>10 aut.</sZ>
</inist:fA14>
<country>Allemagne</country>
<wicri:noRegion>33615 Bielefeld</wicri:noRegion>
<wicri:noRegion>Universitätsstrasse 25</wicri:noRegion>
<wicri:noRegion>33615 Bielefeld</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Combustion and flame</title>
<title level="j" type="abbreviated">Combust. flame</title>
<idno type="ISSN">0010-2180</idno>
<imprint><date when="2014">2014</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Combustion and flame</title>
<title level="j" type="abbreviated">Combust. flame</title>
<idno type="ISSN">0010-2180</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biofuel</term>
<term>Combustion</term>
<term>Flame structure</term>
<term>Furan derivatives</term>
<term>Gas chromatography</term>
<term>Kinetic model</term>
<term>Low pressure</term>
<term>Mass spectrometry</term>
<term>Modeling</term>
<term>Molecular beam</term>
<term>Operating conditions</term>
<term>Reaction mechanism</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Combustion</term>
<term>Structure flamme</term>
<term>Spectrométrie masse</term>
<term>Dérivé du furane</term>
<term>Biocarburant</term>
<term>Mécanisme réaction</term>
<term>Faisceau moléculaire</term>
<term>Chromatographie phase gazeuse</term>
<term>Basse pression</term>
<term>Modèle cinétique</term>
<term>Condition opératoire</term>
<term>Modélisation</term>
<term>Furane(2-méthyl)</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">This is Part II of a series of three papers which jointly address the combustion chemistry of furan and its alkylated derivatives 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) under premixed low-pressure flame conditions. Some of them are considered to be promising biofuels. With furan as a common basis studied in Part I of this series, the present paper addresses two laminar premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of MF which were studied with electron-ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) for equivalence ratios φ = 1.0 and 1.7, identical conditions to those for the previously reported furan flames. Mole fractions of reactants, products as well as stable and reactive intermediates were measured as a function of the distance above the burner. Kinetic modeling was performed using a comprehensive reaction mechanism for all three fuels given in Part I and described in the three parts of this series. A comparison of the experimental results and the simulation shows reasonable agreement, as also seen for the furan flames in Part I before. This set of experiments is thus considered to be a valuable additional basis for the validation of the model. The main reaction pathways of MF consumption have been derived from reaction flow analyses, and differences to furan combustion chemistry under the same conditions are discussed.</div>
</front>
</TEI>
<affiliations><list><country><li>Allemagne</li>
<li>France</li>
</country>
<region><li>Grand Est</li>
<li>Lorraine (région)</li>
</region>
<settlement><li>Nancy</li>
</settlement>
<orgName><li>Centre national de la recherche scientifique</li>
<li>Laboratoire réactions et génie des procédés</li>
<li>Université de Lorraine</li>
</orgName>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name>
</region>
<name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
<name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name>
<name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name>
<name sortKey="Sirjean, Baptiste" sort="Sirjean, Baptiste" uniqKey="Sirjean B" first="Baptiste" last="Sirjean">Baptiste Sirjean</name>
</country>
<country name="Allemagne"><noRegion><name sortKey="Togbe, Casimir" sort="Togbe, Casimir" uniqKey="Togbe C" first="Casimir" last="Togbe">Casimir Togbe</name>
</noRegion>
<name sortKey="Dong Liu" sort="Dong Liu" uniqKey="Dong Liu" last="Dong Liu">DONG LIU</name>
<name sortKey="Felsmann, Daniel" sort="Felsmann, Daniel" uniqKey="Felsmann D" first="Daniel" last="Felsmann">Daniel Felsmann</name>
<name sortKey="Kohse Hoinghaus, Katharina" sort="Kohse Hoinghaus, Katharina" uniqKey="Kohse Hoinghaus K" first="Katharina" last="Kohse-Höinghaus">Katharina Kohse-Höinghaus</name>
<name sortKey="Osswald, Patrick" sort="Osswald, Patrick" uniqKey="Osswald P" first="Patrick" last="Osswald">Patrick Osswald</name>
</country>
</tree>
</affiliations>
</record>

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Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran

Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran

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