Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran
Identifieur interne : 000245 ( Hal/Corpus ); précédent : 000244; suivant : 000246Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran
Auteurs : Luc-Sy Tran ; Casimir Togbé ; Dong Liu ; Daniel Felsmann ; Patrick Osswald ; Pierre-Alexandre Glaude ; René Fournet ; Baptiste Sirjean ; Frédérique Battin-Leclerc ; Katharina Kohse-HoeinghausSource :
- Combustion and Flame [ 0010-2180 ] ; 2014-03.
Abstract
This is Part II of a series of three papers which jointly address the combustion chemistry of furan and its alkylated derivatives 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) under premixed low-pressure flame conditions. Some of them are considered to be promising biofuels. With furan as a common basis studied in Part I of this series, the present paper addresses two laminar premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of MF which were studied with electron ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) for equivalence ratios phi = 1.0 and 1.7, identical conditions to those for the previously reported furan flames. Mole fractions of reactants, products as well as stable and reactive intermediates were measured as a function of the distance above the burner. Kinetic modeling was performed using a comprehensive reaction mechanism for all three fuels given in Part I and described in the three parts of this series. A comparison of the experimental results and the simulation shows reasonable agreement, as also seen for the furan flames in Part I before. This set of experiments is thus considered to be a valuable additional basis for the validation of the model. The main reaction pathways of MF consumption have been derived from reaction flow analyses, and differences to furan combustion chemistry under the same conditions are discussed.
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DOI: 10.1016/j.combustflame.2013.05.027
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Part II: 2-Methylfuran</title><author><name sortKey="Tran, Luc Sy" sort="Tran, Luc Sy" uniqKey="Tran L" first="Luc-Sy" last="Tran">Luc-Sy Tran</name><affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno><idno type="RNSR">201320573K</idno><idno type="IdUnivLorraine">[UL]RQC--</idno><orgName>Laboratoire Réactions et Génie des Procédés</orgName><orgName type="acronym">LRGP</orgName><date type="start">2013-01-01</date><desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine><country key="FR"></country></address><ref type="url">http://lrgp.univ-lorraine.fr/</ref></desc><listRelation><relation active="#struct-413289" type="direct"></relation><relation name="UMR7274" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno><idno type="IdUnivLorraine">[UL]100--</idno><orgName>Université de Lorraine</orgName><orgName type="acronym">UL</orgName><date type="start">2012-01-01</date><desc><address><addrLine>34 cours Léopold - 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ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine><country key="FR"></country></address><ref type="url">http://lrgp.univ-lorraine.fr/</ref></desc><listRelation><relation active="#struct-413289" type="direct"></relation><relation name="UMR7274" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno><idno type="IdUnivLorraine">[UL]100--</idno><orgName>Université de Lorraine</orgName><orgName type="acronym">UL</orgName><date type="start">2012-01-01</date><desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine><country key="FR"></country></address><ref type="url">http://www.univ-lorraine.fr/</ref></desc></org></tutelle><tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno><idno type="IdRef">02636817X</idno><orgName>Centre National de la Recherche Scientifique</orgName><orgName type="acronym">CNRS</orgName><date type="start">1939-10-19</date><desc><address><country key="FR"></country></address><ref type="url">http://www.cnrs.fr/</ref></desc></org></tutelle></tutelles></hal:affiliation></affiliation></author><author><name sortKey="Fournet, Rene" sort="Fournet, Rene" uniqKey="Fournet R" first="René" last="Fournet">René Fournet</name><affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno><idno type="RNSR">201320573K</idno><idno type="IdUnivLorraine">[UL]RQC--</idno><orgName>Laboratoire Réactions et Génie des Procédés</orgName><orgName type="acronym">LRGP</orgName><date type="start">2013-01-01</date><desc><address><addrLine>Université de Lorraine - 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Some of them are considered to be promising biofuels. With furan as a common basis studied in Part I of this series, the present paper addresses two laminar premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of MF which were studied with electron ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) for equivalence ratios phi = 1.0 and 1.7, identical conditions to those for the previously reported furan flames. Mole fractions of reactants, products as well as stable and reactive intermediates were measured as a function of the distance above the burner. Kinetic modeling was performed using a comprehensive reaction mechanism for all three fuels given in Part I and described in the three parts of this series. A comparison of the experimental results and the simulation shows reasonable agreement, as also seen for the furan flames in Part I before. This set of experiments is thus considered to be a valuable additional basis for the validation of the model. The main reaction pathways of MF consumption have been derived from reaction flow analyses, and differences to furan combustion chemistry under the same conditions are discussed.</div></front></TEI><hal api="V3"><titleStmt><title xml:lang="en">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran</title><author role="aut"><persName><forename type="first">Luc-Sy</forename><surname>Tran</surname></persName><email></email><idno type="halauthor">1182623</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Casimir</forename><surname>Togbé</surname></persName><email></email><idno type="halauthor">892545</idno></author><author role="aut"><persName><forename type="first">Dong</forename><surname>Liu</surname></persName><email></email><idno type="halauthor">330287</idno></author><author role="aut"><persName><forename type="first">Daniel</forename><surname>Felsmann</surname></persName><email></email><idno type="halauthor">1296351</idno></author><author role="aut"><persName><forename type="first">Patrick</forename><surname>Osswald</surname></persName><email></email><idno type="halauthor">1296352</idno></author><author role="rsp"><persName><forename type="first">Pierre-Alexandre</forename><surname>Glaude</surname></persName><email>pierre-alexandre.glaude@univ-lorraine.fr</email><idno type="halauthor">879633</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">René</forename><surname>Fournet</surname></persName><email>rene.fournet@univ-lorraine.fr</email><idno type="halauthor">807196</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Baptiste</forename><surname>Sirjean</surname></persName><email>baptiste.sirjean@univ-lorraine.fr</email><idno type="halauthor">826296</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Frédérique</forename><surname>Battin-Leclerc</surname></persName><email>frederique.battin-leclerc@univ-lorraine.fr</email><idno type="halauthor">755940</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Katharina</forename><surname>Kohse-Hoeinghaus</surname></persName><email></email><idno type="halauthor">299984</idno></author><editor role="depositor"><persName><forename>LRGP</forename><surname>UL</surname></persName><email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email></editor></titleStmt><editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2016-02-18 14:59:44</date><date type="whenModified">2016-05-10 16:53:27</date><date type="whenReleased">2016-02-18 14:59:44</date><date type="whenProduced">2014-03</date></edition><respStmt><resp>contributor</resp><name key="329568"><persName><forename>LRGP</forename><surname>UL</surname></persName><email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email></name></respStmt></editionStmt><publicationStmt><distributor>CCSD</distributor><idno type="halId">hal-01275925</idno><idno type="halUri">https://hal.univ-lorraine.fr/hal-01275925</idno><idno type="halBibtex">tran:hal-01275925</idno><idno type="halRefHtml">Combustion and Flame, Elsevier, 2014, 161 (3), pp.766-779. <10.1016/j.combustflame.2013.05.027></idno><idno type="halRef">Combustion and Flame, Elsevier, 2014, 161 (3), pp.766-779. <10.1016/j.combustflame.2013.05.027></idno></publicationStmt><seriesStmt><idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno><idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno><idno type="stamp" n="LRGP-UL">LRGP</idno></seriesStmt><notesStmt><note type="audience" n="2">International</note><note type="popular" n="0">No</note><note type="peer" n="1">Yes</note></notesStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Combustion chemistry and flame structure of furan group biofuels using molecular-beam mass spectrometry and gas chromatography - Part II: 2-Methylfuran</title><author role="aut"><persName><forename type="first">Luc-Sy</forename><surname>Tran</surname></persName><idno type="halAuthorId">1182623</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Casimir</forename><surname>Togbé</surname></persName><idno type="halAuthorId">892545</idno></author><author role="aut"><persName><forename type="first">Dong</forename><surname>Liu</surname></persName><idno type="halAuthorId">330287</idno></author><author role="aut"><persName><forename type="first">Daniel</forename><surname>Felsmann</surname></persName><idno type="halAuthorId">1296351</idno></author><author role="aut"><persName><forename type="first">Patrick</forename><surname>Osswald</surname></persName><idno type="halAuthorId">1296352</idno></author><author role="rsp"><persName><forename type="first">Pierre-Alexandre</forename><surname>Glaude</surname></persName><email>pierre-alexandre.glaude@univ-lorraine.fr</email><idno type="halAuthorId">879633</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">René</forename><surname>Fournet</surname></persName><email>rene.fournet@univ-lorraine.fr</email><idno type="halAuthorId">807196</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Baptiste</forename><surname>Sirjean</surname></persName><email>baptiste.sirjean@univ-lorraine.fr</email><idno type="halAuthorId">826296</idno><affiliation ref="#struct-211875"></affiliation></author><author role="rsp"><persName><forename type="first">Frédérique</forename><surname>Battin-Leclerc</surname></persName><email>frederique.battin-leclerc@univ-lorraine.fr</email><idno type="halAuthorId">755940</idno><affiliation ref="#struct-211875"></affiliation></author><author role="aut"><persName><forename type="first">Katharina</forename><surname>Kohse-Hoeinghaus</surname></persName><idno type="halAuthorId">299984</idno></author></analytic><monogr><idno type="halJournalId" status="VALID">11902</idno><idno type="issn">0010-2180</idno><title level="j">Combustion and Flame</title><imprint><publisher>Elsevier</publisher><biblScope unit="volume">161</biblScope><biblScope unit="issue">3</biblScope><biblScope unit="pp">766-779</biblScope><date type="datePub">2014-03</date></imprint></monogr><idno type="doi">10.1016/j.combustflame.2013.05.027</idno></biblStruct></sourceDesc><profileDesc><langUsage><language ident="en">English</language></langUsage><textClass><classCode scheme="halDomain" n="chim">Chemical Sciences</classCode><classCode scheme="halTypology" n="ART">Journal articles</classCode></textClass><abstract xml:lang="en">This is Part II of a series of three papers which jointly address the combustion chemistry of furan and its alkylated derivatives 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) under premixed low-pressure flame conditions. Some of them are considered to be promising biofuels. With furan as a common basis studied in Part I of this series, the present paper addresses two laminar premixed low-pressure (20 and 40 mbar) flat argon-diluted (50%) flames of MF which were studied with electron ionization molecular-beam mass spectrometry (EI-MBMS) and gas chromatography (GC) for equivalence ratios phi = 1.0 and 1.7, identical conditions to those for the previously reported furan flames. Mole fractions of reactants, products as well as stable and reactive intermediates were measured as a function of the distance above the burner. Kinetic modeling was performed using a comprehensive reaction mechanism for all three fuels given in Part I and described in the three parts of this series. A comparison of the experimental results and the simulation shows reasonable agreement, as also seen for the furan flames in Part I before. This set of experiments is thus considered to be a valuable additional basis for the validation of the model. The main reaction pathways of MF consumption have been derived from reaction flow analyses, and differences to furan combustion chemistry under the same conditions are discussed.</abstract></profileDesc></hal></record>Pour manipuler ce document sous Unix (Dilib)
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