Electrochemical quartz crystal microbalance and spectroelectrochemical studies of the influence of cations on the formation and electroactivity of poly(N-vinylcarbazole) films in acetonitrile solutions
Identifieur interne : 017236 ( Main/Repository ); précédent : 017235; suivant : 017237Electrochemical quartz crystal microbalance and spectroelectrochemical studies of the influence of cations on the formation and electroactivity of poly(N-vinylcarbazole) films in acetonitrile solutions
Auteurs : RBID : Pascal:98-0502622Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Polymérisation électrolytique, Réaction électrochimique, Carbazole(vinyl) polymère, Polymère redox, Polymère conducteur, Propriété électrochimique, Electrode disque tournant, Platine, Or, Indium Oxyde, Etain Oxyde, Effet milieu, Lithium Perchlorate, Solvant organique, Acétonitrile, Microbalance quartz, Spectrométrie UV visible, Cinétique, Electrode ITO, Ammonium(tétrabutyl) perchlorate.
- Wicri :
English descriptors
- KwdEn :
- Acetonitrile, Carbazole(vinyl) polymer, Conducting polymers, Electrochemical polymerization, Electrochemical properties, Electrochemical reaction, Experimental study, Gold, Indium Oxides, Kinetics, Lithium Perchlorates, Medium effect, Organic solvent, Platinum, Quartz microbalance, Redox polymer, Rotating disk electrode, Tin Oxides, Ultraviolet visible spectrometry.
Abstract
Films of poly(N-vinylcarbazole) (PVCz) were prepared and studied in the presence of different cations using spectroelectrochemical and electrochemical quartz crystal microbalance methods. Evidence for the effect of the cation on both formation and redox behaviour has been obtained. The experimental results have been interpreted by considering the presence of different types of ionic species inside the polymers layer (free anion, screened anion, bound anion and cation).
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Electrochemical quartz crystal microbalance and spectroelectrochemical studies of the influence of cations on the formation and electroactivity of poly(N-vinylcarbazole) films in acetonitrile solutions</title><author><name sortKey="Carlier, V" uniqKey="Carlier V">V. Carlier</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Université Libre de Bruxelles, Faculté des Science Service de Chimie Analytique CP255, 2 Boulevard du Triomphe</s1><s2>1050 Bruxelles</s2><s3>BEL</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Belgique</country><placeName><settlement type="city">Bruxelles</settlement><region nuts="2">Région de Bruxelles-Capitale</region></placeName><orgName type="university">Université libre de Bruxelles</orgName><placeName><settlement type="city">Bruxelles</settlement><region type="region" nuts="2">Région de Bruxelles-Capitale</region></placeName></affiliation></author><author><name sortKey="Skompska, M" uniqKey="Skompska M">M. Skompska</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Warsaw University, ul Pasteur 1</s1><s2>02 093 Warsaw</s2><s3>POL</s3><sZ>2 aut.</sZ></inist:fA14><country>Pologne</country><wicri:noRegion>02 093 Warsaw</wicri:noRegion></affiliation></author><author><name sortKey="Buess Herman, C" uniqKey="Buess Herman C">C. Buess-Herman</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Université Libre de Bruxelles, Faculté des Science Service de Chimie Analytique CP255, 2 Boulevard du Triomphe</s1><s2>1050 Bruxelles</s2><s3>BEL</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Belgique</country><placeName><settlement type="city">Bruxelles</settlement><region nuts="2">Région de Bruxelles-Capitale</region></placeName><orgName type="university">Université libre de Bruxelles</orgName><placeName><settlement type="city">Bruxelles</settlement><region type="region" nuts="2">Région de Bruxelles-Capitale</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">98-0502622</idno><date when="1998">1998</date><idno type="stanalyst">PASCAL 98-0502622 INIST</idno><idno type="RBID">Pascal:98-0502622</idno><idno type="wicri:Area/Main/Corpus">015F87</idno><idno type="wicri:Area/Main/Repository">017236</idno></publicationStmt><seriesStmt><title level="j" type="main">Journal of electroanalytical chemistry:(1992)</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetonitrile</term><term>Carbazole(vinyl) polymer</term><term>Conducting polymers</term><term>Electrochemical polymerization</term><term>Electrochemical properties</term><term>Electrochemical reaction</term><term>Experimental study</term><term>Gold</term><term>Indium Oxides</term><term>Kinetics</term><term>Lithium Perchlorates</term><term>Medium effect</term><term>Organic solvent</term><term>Platinum</term><term>Quartz microbalance</term><term>Redox polymer</term><term>Rotating disk electrode</term><term>Tin Oxides</term><term>Ultraviolet visible spectrometry</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Polymérisation électrolytique</term><term>Réaction électrochimique</term><term>Carbazole(vinyl) polymère</term><term>Polymère redox</term><term>Polymère conducteur</term><term>Propriété électrochimique</term><term>Electrode disque tournant</term><term>Platine</term><term>Or</term><term>Indium Oxyde</term><term>Etain Oxyde</term><term>Effet milieu</term><term>Lithium Perchlorate</term><term>Solvant organique</term><term>Acétonitrile</term><term>Microbalance quartz</term><term>Spectrométrie UV visible</term><term>Cinétique</term><term>Electrode ITO</term><term>Ammonium(tétrabutyl) perchlorate</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Platine</term><term>Or</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Films of poly(N-vinylcarbazole) (PVCz) were prepared and studied in the presence of different cations using spectroelectrochemical and electrochemical quartz crystal microbalance methods. Evidence for the effect of the cation on both formation and redox behaviour has been obtained. The experimental results have been interpreted by considering the presence of different types of ionic species inside the polymers layer (free anion, screened anion, bound anion and cation).</div></front></TEI><inist><standard h6="B"><pA><fA05><s2>456</s2></fA05><fA06><s2>1-2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Electrochemical quartz crystal microbalance and spectroelectrochemical studies of the influence of cations on the formation and electroactivity of poly(N-vinylcarbazole) films in acetonitrile solutions</s1></fA08><fA11 i1="01" i2="1"><s1>CARLIER (V.)</s1></fA11><fA11 i1="02" i2="1"><s1>SKOMPSKA (M.)</s1></fA11><fA11 i1="03" i2="1"><s1>BUESS-HERMAN (C.)</s1></fA11><fA14 i1="01"><s1>Université Libre de Bruxelles, Faculté des Science Service de Chimie Analytique CP255, 2 Boulevard du Triomphe</s1><s2>1050 Bruxelles</s2><s3>BEL</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Chemistry, Warsaw University, ul Pasteur 1</s1><s2>02 093 Warsaw</s2><s3>POL</s3><sZ>2 aut.</sZ></fA14><fA20><s1>139-152</s1></fA20><fA21><s1>1998</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>1150</s2><s5>354000071307510150</s5></fA43><fA44><s0>0000</s0><s1>© 1998 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>47 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>98-0502622</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i2="2"><s0>Journal of electroanalytical chemistry:(1992)</s0></fA64><fA66 i1="01"><s0>CHE</s0></fA66><fC01 i1="01" l="ENG"><s0>Films of poly(N-vinylcarbazole) (PVCz) were prepared and studied in the presence of different cations using spectroelectrochemical and electrochemical quartz crystal microbalance methods. Evidence for the effect of the cation on both formation and redox behaviour has been obtained. The experimental results have been interpreted by considering the presence of different types of ionic species inside the polymers layer (free anion, screened anion, bound anion and cation).</s0></fC01><fC02 i1="01" i2="X"><s0>001C01H05</s0></fC02><fC02 i1="02" i2="X"><s0>001D09B01</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="GER"><s0>Experimentelle Untersuchung</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Polymérisation électrolytique</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Electrochemical polymerization</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Polimerización electrolítica</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Réaction électrochimique</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Electrochemical 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