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Structural and photoluminescence study of the quaternary alloys system CuIn(SxSe1-x)2

Identifieur interne : 012821 ( Main/Repository ); précédent : 012820; suivant : 012822

Structural and photoluminescence study of the quaternary alloys system CuIn(SxSe1-x)2

Auteurs : RBID : Pascal:00-0126103

Descripteurs français

Pascal (Inist)
- Photoluminescence, Diffraction RX, Défaut cristallin, Paramètre cristallin, Distorsion réseau, Exciton, Exciton lié, Energie liaison, Transition niveau énergie, Energie activation, Cuivre Sulfoséléniure, Indium Sulfoséléniure, Matériau semiconducteur, Composé minéral, Composé quaternaire, Polycristal, Etude expérimentale, CuIn(SxSe1-x)2, Cu In S Se.
Wicri :
- concept : Composé minéral.

English descriptors

KwdEn :
- Activation energy, Binding energy, Bound exciton, Copper Selenides sulfides, Crystal defects, Energy-level transitions, Excitons, Experimental study, Indium Selenides sulfides, Inorganic compounds, Lattice distortion, Lattice parameters, Photoluminescence, Polycrystals, Quaternary compounds, Semiconductor materials, XRD.

Abstract

The full composition range CuIn(S_xSe_1-x)₂ alloy system has been studied using 40 mm length crystal cuts from 10 mm diameter ingots grown by the classical Bridgman method. X-ray diffraction diffractographs show that the CuIn(S_xSe_1-x)₂ compounds have a chalcopyrite structure for each composition x, they exhibit an expansion on the unit cell characteristics by the tetragonal distortion which depends linearly on the electronegativity of the atoms. The photoluminescence spectra is investigated as a function of various compositions, temperature and excitation intensities. Photoluminescence spectra shows a wide variation in the dominant peak location and an overall blue shift with the increase of sulphur content. Photoluminescence CuInS₂ and CuIn(S_0.72 Se_0.28)₂ have been studied in detail.

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Pascal:00-0126103

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Structural and photoluminescence study of the quaternary alloys system CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
</title>
<author><name sortKey="Zeaiter, K" uniqKey="Zeaiter K">K. Zeaiter</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Centre d'Electronique et de Microoptoelectronique de Montpellier, CEM2, CNRS 5507, Université de Montpellier II, Case courier 084, Place Eugene Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Llinares, Y" uniqKey="Llinares Y">Y. Llinares</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Centre d'Electronique et de Microoptoelectronique de Montpellier, CEM2, CNRS 5507, Université de Montpellier II, Case courier 084, Place Eugene Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Llinares, C" uniqKey="Llinares C">C. Llinares</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Centre d'Electronique et de Microoptoelectronique de Montpellier, CEM2, CNRS 5507, Université de Montpellier II, Case courier 084, Place Eugene Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">00-0126103</idno>
<date when="2000">2000</date>
<idno type="stanalyst">PASCAL 00-0126103 INIST</idno>
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<seriesStmt><idno type="ISSN">0927-0248</idno>
<title level="j" type="abbreviated">Sol. energy mater. sol. cells</title>
<title level="j" type="main">Solar energy materials and solar cells</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Activation energy</term>
<term>Binding energy</term>
<term>Bound exciton</term>
<term>Copper Selenides sulfides</term>
<term>Crystal defects</term>
<term>Energy-level transitions</term>
<term>Excitons</term>
<term>Experimental study</term>
<term>Indium Selenides sulfides</term>
<term>Inorganic compounds</term>
<term>Lattice distortion</term>
<term>Lattice parameters</term>
<term>Photoluminescence</term>
<term>Polycrystals</term>
<term>Quaternary compounds</term>
<term>Semiconductor materials</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Diffraction RX</term>
<term>Défaut cristallin</term>
<term>Paramètre cristallin</term>
<term>Distorsion réseau</term>
<term>Exciton</term>
<term>Exciton lié</term>
<term>Energie liaison</term>
<term>Transition niveau énergie</term>
<term>Energie activation</term>
<term>Cuivre Sulfoséléniure</term>
<term>Indium Sulfoséléniure</term>
<term>Matériau semiconducteur</term>
<term>Composé minéral</term>
<term>Composé quaternaire</term>
<term>Polycristal</term>
<term>Etude expérimentale</term>
<term>CuIn(SxSe1-x)2</term>
<term>Cu In S Se</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Composé minéral</term>
</keywords>
</textClass>
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</teiHeader>
<front><div type="abstract" xml:lang="en">The full composition range CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
 alloy system has been studied using 40 mm length crystal cuts from 10 mm diameter ingots grown by the classical Bridgman method. X-ray diffraction diffractographs show that the CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
 compounds have a chalcopyrite structure for each composition x, they exhibit an expansion on the unit cell characteristics by the tetragonal distortion which depends linearly on the electronegativity of the atoms. The photoluminescence spectra is investigated as a function of various compositions, temperature and excitation intensities. Photoluminescence spectra shows a wide variation in the dominant peak location and an overall blue shift with the increase of sulphur content. Photoluminescence CuInS<sub>2</sub>
 and CuIn(S<sub>0.72</sub>
 Se<sub>0.28</sub>
)<sub>2</sub>
 have been studied in detail.</div>
</front>
</TEI>
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<fA05><s2>61</s2>
</fA05>
<fA06><s2>3</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Structural and photoluminescence study of the quaternary alloys system CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>ZEAITER (K.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>LLINARES (Y.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>LLINARES (C.)</s1>
</fA11>
<fA14 i1="01"><s1>Centre d'Electronique et de Microoptoelectronique de Montpellier, CEM2, CNRS 5507, Université de Montpellier II, Case courier 084, Place Eugene Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>313-329</s1>
</fA20>
<fA21><s1>2000</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>18016</s2>
<s5>354000086648570080</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2000 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>35 ref.</s0>
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<fA47 i1="01" i2="1"><s0>00-0126103</s0>
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<fA60><s1>P</s1>
<s3>CR</s3>
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<fA61><s0>A</s0>
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<fA64 i1="01" i2="1"><s0>Solar energy materials and solar cells</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The full composition range CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
 alloy system has been studied using 40 mm length crystal cuts from 10 mm diameter ingots grown by the classical Bridgman method. X-ray diffraction diffractographs show that the CuIn(S<sub>x</sub>
Se<sub>1-x</sub>
)<sub>2</sub>
 compounds have a chalcopyrite structure for each composition x, they exhibit an expansion on the unit cell characteristics by the tetragonal distortion which depends linearly on the electronegativity of the atoms. The photoluminescence spectra is investigated as a function of various compositions, temperature and excitation intensities. Photoluminescence spectra shows a wide variation in the dominant peak location and an overall blue shift with the increase of sulphur content. Photoluminescence CuInS<sub>2</sub>
 and CuIn(S<sub>0.72</sub>
 Se<sub>0.28</sub>
)<sub>2</sub>
 have been studied in detail.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70H55E</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Photoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Défaut cristallin</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Crystal defects</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Paramètre cristallin</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Lattice parameters</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Distorsion réseau</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Lattice distortion</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Distorsión red</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Exciton</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Excitons</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Exciton lié</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Bound exciton</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Excitón ligado</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Energie liaison</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Binding energy</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Transition niveau énergie</s0>
<s5>14</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Energy-level transitions</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Energie activation</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Activation energy</s0>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Cuivre Sulfoséléniure</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Copper Selenides sulfides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Seleniuro sulfuro</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Indium Sulfoséléniure</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Indium Selenides sulfides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Seleniuro sulfuro</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Matériau semiconducteur</s0>
<s5>18</s5>
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<s5>18</s5>
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<fC03 i1="14" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>19</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>20</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Polycristal</s0>
<s5>21</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>Polycrystals</s0>
<s5>21</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>22</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>22</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>CuIn(SxSe1-x)2</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Cu In S Se</s0>
<s4>INC</s4>
<s5>73</s5>
</fC03>
<fN21><s1>094</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Structural and photoluminescence study of the quaternary alloys system CuIn(SxSe1-x)2

Structural and photoluminescence study of the quaternary alloys system CuIn(SxSe1-x)2

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri