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Effect of Bi addition on the electrical properties of a-Ge-Se-In thin films

Identifieur interne : 006971 ( Main/Repository ); précédent : 006970; suivant : 006972

Effect of Bi addition on the electrical properties of a-Ge-Se-In thin films

Auteurs : RBID : Pascal:08-0464443

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English descriptors

Abstract

This paper reports on the steady state and transient photoconductivity of Ge20Se70-xIn10Bix (x = 2, 4, 6, 8, 10) thermally evaporated thin films. The dark conductivity (σd) increases with the increase in the Bi content. The value of σd increases slowly from x = 2 to x = 6, but for x ≥ 8 the increase is quite abrupt. Photoconductivity (σph) also increases with the increase in the Bi content. The dark activation energy (ΔEd) decreases with the increase in the Bi content. There is a drop in the photosensitivity (σphd) of films with the increase in Bi addition. The result of the intensity dependent steady state photoconductivity (σph) follows the power law with intensity (F), i.e. σphαFγ where the value of y is close to 0.5, suggesting the predominance of bimolecular recombination in these materials. The rise and decay of photocurrent show the increase in the differential lifetime (τd), with the increase in the Bi content, indicating a delay in the recombination rate of photo-generated charge carriers. This change is governed by the photo-generated carriers trapped in the intrinsic defects or light induced defect creation through structural changes. One can therefore also expect that the density of states increases with the increase in the Bi content in amorphous thin films. The dispersion parameter (α) of the localized state energy distribution, determined from the decay curves, is also reported.

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<name sortKey="Kumar, Akshay" uniqKey="Kumar A">Akshay Kumar</name>
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<term>Charge carrier generation</term>
<term>Chemical composition</term>
<term>Dark conductivity</term>
<term>Defect formation</term>
<term>Localized states</term>
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<div type="abstract" xml:lang="en">This paper reports on the steady state and transient photoconductivity of Ge
<sub>20</sub>
Se
<sub>70-x</sub>
In
<sub>10</sub>
Bi
<sub>x</sub>
(x = 2, 4, 6, 8, 10) thermally evaporated thin films. The dark conductivity (σ
<sub>d</sub>
) increases with the increase in the Bi content. The value of σ
<sub>d</sub>
increases slowly from x = 2 to x = 6, but for x ≥ 8 the increase is quite abrupt. Photoconductivity (σ
<sub>ph</sub>
) also increases with the increase in the Bi content. The dark activation energy (ΔE
<sub>d</sub>
) decreases with the increase in the Bi content. There is a drop in the photosensitivity (σ
<sub>ph</sub>
<sub>d</sub>
) of films with the increase in Bi addition. The result of the intensity dependent steady state photoconductivity (σ
<sub>ph</sub>
) follows the power law with intensity (F), i.e. σ
<sub>ph</sub>
αF
<sup>γ</sup>
where the value of y is close to 0.5, suggesting the predominance of bimolecular recombination in these materials. The rise and decay of photocurrent show the increase in the differential lifetime (τ
<sub>d</sub>
), with the increase in the Bi content, indicating a delay in the recombination rate of photo-generated charge carriers. This change is governed by the photo-generated carriers trapped in the intrinsic defects or light induced defect creation through structural changes. One can therefore also expect that the density of states increases with the increase in the Bi content in amorphous thin films. The dispersion parameter (α) of the localized state energy distribution, determined from the decay curves, is also reported.</div>
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<sZ>4 aut.</sZ>
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<s0>This paper reports on the steady state and transient photoconductivity of Ge
<sub>20</sub>
Se
<sub>70-x</sub>
In
<sub>10</sub>
Bi
<sub>x</sub>
(x = 2, 4, 6, 8, 10) thermally evaporated thin films. The dark conductivity (σ
<sub>d</sub>
) increases with the increase in the Bi content. The value of σ
<sub>d</sub>
increases slowly from x = 2 to x = 6, but for x ≥ 8 the increase is quite abrupt. Photoconductivity (σ
<sub>ph</sub>
) also increases with the increase in the Bi content. The dark activation energy (ΔE
<sub>d</sub>
) decreases with the increase in the Bi content. There is a drop in the photosensitivity (σ
<sub>ph</sub>
<sub>d</sub>
) of films with the increase in Bi addition. The result of the intensity dependent steady state photoconductivity (σ
<sub>ph</sub>
) follows the power law with intensity (F), i.e. σ
<sub>ph</sub>
αF
<sup>γ</sup>
where the value of y is close to 0.5, suggesting the predominance of bimolecular recombination in these materials. The rise and decay of photocurrent show the increase in the differential lifetime (τ
<sub>d</sub>
), with the increase in the Bi content, indicating a delay in the recombination rate of photo-generated charge carriers. This change is governed by the photo-generated carriers trapped in the intrinsic defects or light induced defect creation through structural changes. One can therefore also expect that the density of states increases with the increase in the Bi content in amorphous thin films. The dispersion parameter (α) of the localized state energy distribution, determined from the decay curves, is also reported.</s0>
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<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Dark conductivity</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Energie activation</s0>
<s5>06</s5>
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<s0>Activation energy</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Photosensibilité</s0>
<s5>07</s5>
</fC03>
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<s0>Photosensitivity</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
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<s5>08</s5>
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<s0>Power law</s0>
<s5>08</s5>
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<fC03 i1="07" i2="X" l="SPA">
<s0>Ley poder</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Formation défaut</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Defect formation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Formación defecto</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Etat localisé</s0>
<s5>10</s5>
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<s0>Localized states</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Génération porteur charge</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Charge carrier generation</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Generación portador carga</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Bismuth Indium Germanium Séléniure Mixte</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Bismuth Indium Germanium Selenides Mixed</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
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<s0>Mixto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
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<s0>Etat amorphe</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Amorphous state</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Couche mince</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Thin films</s0>
<s5>16</s5>
</fC03>
<fN21>
<s1>301</s1>
</fN21>
</pA>
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