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Crystal growth of KInO2 from a hydroxide flux

Identifieur interne : 004532 ( Main/Repository ); précédent : 004531; suivant : 004533

Crystal growth of KInO2 from a hydroxide flux

Auteurs : RBID : Pascal:11-0016116

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English descriptors

Abstract

Single crystals of KInO2 were obtained from a reactive potassium hydroxide flux at 700 °C. KInO2 crystallizes in the R-3m crystal system with a=3.2998(10) Å, c=18.322(10) Å and V=172.78(12) Å3. The crystal structure is isotypic with that of α-NaFeO2 and consists of the (1 1 1) layers being occupied alternately by KO6 and InO6 octahedra. Three different AlnO2 structure types are discussed.

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Pascal:11-0016116

Le document en format XML

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<title xml:lang="en" level="a">Crystal growth of KInO
<sub>2</sub>
from a hydroxide flux</title>
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<name sortKey="Bharathy, M" uniqKey="Bharathy M">M. Bharathy</name>
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<name sortKey="Zhao, Q" uniqKey="Zhao Q">Q. Zhao</name>
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<s1>Department of Chemistry and Biochemistry, University of South Carolina</s1>
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<div type="abstract" xml:lang="en">Single crystals of KInO
<sub>2</sub>
were obtained from a reactive potassium hydroxide flux at 700 °C. KInO
<sub>2</sub>
crystallizes in the R-3m crystal system with a=3.2998(10) Å, c=18.322(10) Å and V=172.78(12) Å
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. The crystal structure is isotypic with that of α-NaFeO
<sub>2</sub>
and consists of the (1 1 1) layers being occupied alternately by KO
<sub>6</sub>
and InO
<sub>6</sub>
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<sub>2</sub>
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<s0>Single crystals of KInO
<sub>2</sub>
were obtained from a reactive potassium hydroxide flux at 700 °C. KInO
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crystallizes in the R-3m crystal system with a=3.2998(10) Å, c=18.322(10) Å and V=172.78(12) Å
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<sub>6</sub>
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