IndiumV3, Main, Repository, bibRecord, 001456

Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation

Identifieur interne : 001456 ( Main/Repository ); précédent : 001455; suivant : 001457

Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation

Auteurs : RBID : Pascal:12-0452518

Descripteurs français

Pascal (Inist)
- Formation motif, Nanosphère, Lithographie, Réduction chimique, In situ, Composé du diazonium, Nanolithographie, Electrode ITO, Electrode, Carbone, Matériau modifié, Or, Dérivé du thiophène, Nanostructure, Réaction électrochimique, Traitement surface, Electrode optiquement transparente, Aniline(4-[5-(2-thiényl)-2-thiényl]), Greffage électrochimique.
Wicri :
- concept : Carbone, Or.

English descriptors

KwdEn :
- Carbon, Chemical reduction, Diazonium compounds, Electrochemical grafting, Electrochemical reaction, Electrodes, Gold, In situ, Indium tin oxide electrode, Lithography, Modified material, Nanolithography, Nanosphere, Nanostructure, Optically transparent electrode, Patterning, Surface treatment, Thiophene derivatives.

Abstract

This work describes the use of colloidal nanolithography followed by the electrografting of organic groups using in situ generated diazonium. As a result, patterned organic layer onto carbon and ITO surfaces could be obtained after the removal of the colloidal. The resulting layer exhibits an electrochemical switch thanks to the use of bithiophene phenyl (BTB) and consists of grafted BTB and free carbon areas generated after dissolution of the colloidal particles. The SEM investigations demonstrate the formation of bi-dimensional well-ordered honeycomb BTB film on ITO and carbon surface. Finally, selective deposition of Au in the imprints of the BTB film, left after the removal of the PS beads, has been successfully achieved.

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Links to Exploration step

Pascal:12-0452518

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation</title>
<author><name sortKey="Santos, Luis" uniqKey="Santos L">Luis Santos</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, Nano-Electro-Chemistry group, 15 rue Jean-Antoine de Baïf</s1>
<s2>75205 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Ghilane, Jalal" uniqKey="Ghilane J">Jalal Ghilane</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, Nano-Electro-Chemistry group, 15 rue Jean-Antoine de Baïf</s1>
<s2>75205 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Lacroix, Jean Christophe" uniqKey="Lacroix J">Jean-Christophe Lacroix</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, Nano-Electro-Chemistry group, 15 rue Jean-Antoine de Baïf</s1>
<s2>75205 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">12-0452518</idno>
<date when="2012">2012</date>
<idno type="stanalyst">PASCAL 12-0452518 INIST</idno>
<idno type="RBID">Pascal:12-0452518</idno>
<idno type="wicri:Area/Main/Corpus">001538</idno>
<idno type="wicri:Area/Main/Repository">001456</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">1388-2481</idno>
<title level="j" type="abbreviated">Electrochem. commun.</title>
<title level="j" type="main">Electrochemistry communications</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carbon</term>
<term>Chemical reduction</term>
<term>Diazonium compounds</term>
<term>Electrochemical grafting</term>
<term>Electrochemical reaction</term>
<term>Electrodes</term>
<term>Gold</term>
<term>In situ</term>
<term>Indium tin oxide electrode</term>
<term>Lithography</term>
<term>Modified material</term>
<term>Nanolithography</term>
<term>Nanosphere</term>
<term>Nanostructure</term>
<term>Optically transparent electrode</term>
<term>Patterning</term>
<term>Surface treatment</term>
<term>Thiophene derivatives</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Formation motif</term>
<term>Nanosphère</term>
<term>Lithographie</term>
<term>Réduction chimique</term>
<term>In situ</term>
<term>Composé du diazonium</term>
<term>Nanolithographie</term>
<term>Electrode ITO</term>
<term>Electrode</term>
<term>Carbone</term>
<term>Matériau modifié</term>
<term>Or</term>
<term>Dérivé du thiophène</term>
<term>Nanostructure</term>
<term>Réaction électrochimique</term>
<term>Traitement surface</term>
<term>Electrode optiquement transparente</term>
<term>Aniline(4-[5-(2-thiényl)-2-thiényl])</term>
<term>Greffage électrochimique</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Carbone</term>
<term>Or</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">This work describes the use of colloidal nanolithography followed by the electrografting of organic groups using in situ generated diazonium. As a result, patterned organic layer onto carbon and ITO surfaces could be obtained after the removal of the colloidal. The resulting layer exhibits an electrochemical switch thanks to the use of bithiophene phenyl (BTB) and consists of grafted BTB and free carbon areas generated after dissolution of the colloidal particles. The SEM investigations demonstrate the formation of bi-dimensional well-ordered honeycomb BTB film on ITO and carbon surface. Finally, selective deposition of Au in the imprints of the BTB film, left after the removal of the PS beads, has been successfully achieved.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1388-2481</s0>
</fA01>
<fA03 i2="1"><s0>Electrochem. commun.</s0>
</fA03>
<fA05><s2>18</s2>
</fA05>
<fA08 i1="01" i2="1" l="ENG"><s1>Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>SANTOS (Luis)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>GHILANE (Jalal)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>LACROIX (Jean-Christophe)</s1>
</fA11>
<fA14 i1="01"><s1>Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS, Nano-Electro-Chemistry group, 15 rue Jean-Antoine de Baïf</s1>
<s2>75205 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA20><s1>20-23</s1>
</fA20>
<fA21><s1>2012</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>26863</s2>
<s5>354000507734400060</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>21 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0452518</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Electrochemistry communications</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>This work describes the use of colloidal nanolithography followed by the electrografting of organic groups using in situ generated diazonium. As a result, patterned organic layer onto carbon and ITO surfaces could be obtained after the removal of the colloidal. The resulting layer exhibits an electrochemical switch thanks to the use of bithiophene phenyl (BTB) and consists of grafted BTB and free carbon areas generated after dissolution of the colloidal particles. The SEM investigations demonstrate the formation of bi-dimensional well-ordered honeycomb BTB film on ITO and carbon surface. Finally, selective deposition of Au in the imprints of the BTB film, left after the removal of the PS beads, has been successfully achieved.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01H01</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Formation motif</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Patterning</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Formacíon motivo</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Nanosphère</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Nanosphere</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Nanosfera</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Lithographie</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Lithography</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Litografía</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Réduction chimique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Chemical reduction</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Reducción química</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>In situ</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>In situ</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>In situ</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Composé du diazonium</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Diazonium compounds</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Diazonio compuesto</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Nanolithographie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Nanolithography</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Electrode ITO</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Indium tin oxide electrode</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Electrodo ITO</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Electrode</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Electrodes</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Electrodo</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Carbone</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Carbon</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Carbono</s0>
<s2>NC</s2>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Matériau modifié</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Modified material</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Material modificado</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Or</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Gold</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Oro</s0>
<s2>NC</s2>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Dérivé du thiophène</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Thiophene derivatives</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Tiofeno derivado</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Nanostructure</s0>
<s5>32</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Nanostructure</s0>
<s5>32</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Nanoestructura</s0>
<s5>32</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Réaction électrochimique</s0>
<s5>33</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Electrochemical reaction</s0>
<s5>33</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Reacción electroquímica</s0>
<s5>33</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Traitement surface</s0>
<s5>34</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Surface treatment</s0>
<s5>34</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Tratamiento superficie</s0>
<s5>34</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Electrode optiquement transparente</s0>
<s5>35</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Optically transparent electrode</s0>
<s5>35</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Electrodo ópticamente transparente</s0>
<s5>35</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Aniline(4-[5-(2-thiényl)-2-thiényl])</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>76</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Greffage électrochimique</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Electrochemical grafting</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Métal transition</s0>
<s2>NC</s2>
<s5>53</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Transition metal</s0>
<s2>NC</s2>
<s5>53</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Metal transición</s0>
<s2>NC</s2>
<s5>53</s5>
</fC07>
<fN21><s1>353</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation

Surface patterning based on nanosphere lithography and electroreduction of in situ generated diazonium cation

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri