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Thermal stability of In2(MoO4)3 and phase equilibria in the MoO3-In2O3 system

Identifieur interne : 001349 ( Main/Repository ); précédent : 001348; suivant : 001350

Thermal stability of In2(MoO4)3 and phase equilibria in the MoO3-In2O3 system

Auteurs : RBID : Pascal:13-0060617

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English descriptors

Abstract

Thermal stability of a compound forming in a binary system MoO3-In2O3 was investigated by DTA/TG, XRD and SEM methods in this study. For the first time, the diagram of phase equilibria established in the whole range of concentrations of this system's components has been constructed. The temperature and concentration ranges of the components of MoO3-In2O3 system in which the compound In2(MoO4)3 co-exists in solid state with MoO3 or In2O3 or with the liquid were determined. The composition and melting point of the eutectic mixture consisting of In2(MoO4)3 and MoO3 were found.

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Pascal:13-0060617

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<title xml:lang="en" level="a">Thermal stability of In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
and phase equilibria in the MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
system</title>
<author>
<name sortKey="Filipek, E" uniqKey="Filipek E">E. Filipek</name>
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<s1>Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42</s1>
<s2>71-065 Szczecin</s2>
<s3>POL</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Pologne</country>
<wicri:noRegion>71-065 Szczecin</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Rychlowska Himmel, I" uniqKey="Rychlowska Himmel I">I. Rychlowska-Himmel</name>
<affiliation wicri:level="1">
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<s1>Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42</s1>
<s2>71-065 Szczecin</s2>
<s3>POL</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Pologne</country>
<wicri:noRegion>71-065 Szczecin</wicri:noRegion>
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<author>
<name sortKey="Paczesna, A" uniqKey="Paczesna A">A. Paczesna</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42</s1>
<s2>71-065 Szczecin</s2>
<s3>POL</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Pologne</country>
<wicri:noRegion>71-065 Szczecin</wicri:noRegion>
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<idno type="inist">13-0060617</idno>
<date when="2012">2012</date>
<idno type="stanalyst">PASCAL 13-0060617 INIST</idno>
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<idno type="ISSN">1388-6150</idno>
<title level="j" type="abbreviated">J. therm. anal. calorim.</title>
<title level="j" type="main">Journal of thermal analysis and calorimetry</title>
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<term>Differential thermal analysis</term>
<term>Indium Molybdates</term>
<term>Indium Oxides</term>
<term>Molybdenum Compounds</term>
<term>Molybdenum Oxides</term>
<term>Morphology</term>
<term>Phase diagram</term>
<term>Phase equilibrium</term>
<term>Pyrolysis</term>
<term>Scanning electron microscopy</term>
<term>Surface structure</term>
<term>Thermal analysis</term>
<term>Thermal stability</term>
<term>Thermogravimetry</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Stabilité thermique</term>
<term>Indium Molybdate</term>
<term>Equilibre phase</term>
<term>Molybdène Oxyde</term>
<term>Indium Oxyde</term>
<term>Microscopie électronique balayage</term>
<term>Analyse thermique différentielle</term>
<term>Pyrolyse</term>
<term>Diffraction RX</term>
<term>Thermogravimétrie</term>
<term>Diagramme phase</term>
<term>Molybdène Composé</term>
<term>Analyse thermique</term>
<term>Structure surface</term>
<term>Morphologie</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">Thermal stability of a compound forming in a binary system MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
was investigated by DTA/TG, XRD and SEM methods in this study. For the first time, the diagram of phase equilibria established in the whole range of concentrations of this system's components has been constructed. The temperature and concentration ranges of the components of MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
system in which the compound In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
co-exists in solid state with MoO
<sub>3</sub>
or In
<sub>2</sub>
O
<sub>3</sub>
or with the liquid were determined. The composition and melting point of the eutectic mixture consisting of In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
and MoO
<sub>3</sub>
were found.</div>
</front>
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<fA01 i1="01" i2="1">
<s0>1388-6150</s0>
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<s2>109</s2>
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<s1>Thermal stability of In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
and phase equilibria in the MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
system</s1>
</fA08>
<fA11 i1="01" i2="1">
<s1>FILIPEK (E.)</s1>
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<s1>RYCHLOWSKA-HIMMEL (I.)</s1>
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<s1>PACZESNA (A.)</s1>
</fA11>
<fA14 i1="01">
<s1>Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42</s1>
<s2>71-065 Szczecin</s2>
<s3>POL</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
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<s1>711-716</s1>
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<fA21>
<s1>2012</s1>
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<s1>INIST</s1>
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<s0>0000</s0>
<s1>© 2013 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45>
<s0>26 ref.</s0>
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<s0>13-0060617</s0>
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<s1>P</s1>
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<s0>A</s0>
</fA61>
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</fA64>
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<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Thermal stability of a compound forming in a binary system MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
was investigated by DTA/TG, XRD and SEM methods in this study. For the first time, the diagram of phase equilibria established in the whole range of concentrations of this system's components has been constructed. The temperature and concentration ranges of the components of MoO
<sub>3</sub>
-In
<sub>2</sub>
O
<sub>3</sub>
system in which the compound In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
co-exists in solid state with MoO
<sub>3</sub>
or In
<sub>2</sub>
O
<sub>3</sub>
or with the liquid were determined. The composition and melting point of the eutectic mixture consisting of In
<sub>2</sub>
(MoO
<sub>4</sub>
)
<sub>3</sub>
and MoO
<sub>3</sub>
were found.</s0>
</fC01>
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<s0>001C01C01</s0>
</fC02>
<fC02 i1="02" i2="X">
<s0>001C02B06</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE">
<s0>Stabilité thermique</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG">
<s0>Thermal stability</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA">
<s0>Estabilidad térmica</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE">
<s0>Indium Molybdate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG">
<s0>Indium Molybdates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA">
<s0>Indio Molibdato</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE">
<s0>Equilibre phase</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG">
<s0>Phase equilibrium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA">
<s0>Equilibrio fase</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Molybdène Oxyde</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Molybdenum Oxides</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Molibdeno Óxido</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Indium Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Indium Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Indio Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Microscopie électronique balayage</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Scanning electron microscopy</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Microscopía electrónica barrido</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Analyse thermique différentielle</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Differential thermal analysis</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Análisis térmico diferencial</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Pyrolyse</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Pyrolysis</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Pirólisis</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Diffraction RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>X ray diffraction</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Difracción RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Thermogravimétrie</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Thermogravimetry</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Termogravimetría</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Diagramme phase</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Phase diagram</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Diagrama fase</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Molybdène Composé</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>32</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Molybdenum Compounds</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>32</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Molibdeno Compuesto</s0>
<s2>NC</s2>
<s2>FX</s2>
<s2>NA</s2>
<s5>32</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Analyse thermique</s0>
<s5>33</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Thermal analysis</s0>
<s5>33</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Análisis térmico</s0>
<s5>33</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Structure surface</s0>
<s5>34</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Surface structure</s0>
<s5>34</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Estructura superficie</s0>
<s5>34</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Morphologie</s0>
<s5>35</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Morphology</s0>
<s5>35</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Morfología</s0>
<s5>35</s5>
</fC03>
<fN21>
<s1>035</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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