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Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization

Identifieur interne : 001018 ( Main/Repository ); précédent : 001017; suivant : 001019

Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization

Auteurs : RBID : Pascal:13-0134359

Descripteurs français

Pascal (Inist)
- Indium, Structure cristalline, Synthèse hydrothermale, Pipérazine, Analyse diffraction RX, Réseau hexagonal, Groupe espace, Réseau orthorhombique, Structure lamellaire, Réseau Kagomé, Topologie, Oxalate, Monocristal, In, 6166.

English descriptors

KwdEn :
- Crystal structure, Hexagonal lattices, Hydrothermal synthesis, Indium, Kagomé lattices, Lamellar structure, Monocrystals, Orthorhombic lattices, Oxalates, Piperazines, Space groups, Topology, X-ray diffraction analysis.

Abstract

Two novel anionic indium phosphites, formulated as [H₃O][In(HPO₃)₂] (1) and [C₄H₁₂N₂][In₂(HPO₃)₃ (C₂O₄)] (2), were prepared under hydrothermal conditions by using piperazine (PIP) as a structure-directing agent (SDA). Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 crystallize in the hexagonal space group P6₃mc (No. 186) and orthorhombic space group Cmcm (No. 63), respectively. Compound 1, constructed from InO₆ octahedra and HP0₃ pseudo-pyramids, exhibits a rare (3,6)-connected layer structure with kgd (Kagome dual) topology. Compound 2, on the other hand, features a 3D phosphite-oxalate hybrid structure with intersecting 8- and 12-MRs channels. From a topological perspective 2 can be regarded as a (3, 5)-connected binodal net with the Schläfli symbol (4².6)(4².6⁵.8³).

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Pascal:13-0134359

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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization</title>
<author><name>HUIDUAN LI</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry and Life Science, Chuxiong Normal University</s1>
<s2>Chuxiong 675000</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Chuxiong 675000</wicri:noRegion>
</affiliation>
</author>
<author><name>LIRONG ZHANG</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name>QISHENG HUO</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name>YUNLING LIU</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">13-0134359</idno>
<date when="2013">2013</date>
<idno type="stanalyst">PASCAL 13-0134359 INIST</idno>
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<title level="j" type="abbreviated">J. solid state chem. : (Print)</title>
<title level="j" type="main">Journal of solid state chemistry : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Crystal structure</term>
<term>Hexagonal lattices</term>
<term>Hydrothermal synthesis</term>
<term>Indium</term>
<term>Kagomé lattices</term>
<term>Lamellar structure</term>
<term>Monocrystals</term>
<term>Orthorhombic lattices</term>
<term>Oxalates</term>
<term>Piperazines</term>
<term>Space groups</term>
<term>Topology</term>
<term>X-ray diffraction analysis</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Indium</term>
<term>Structure cristalline</term>
<term>Synthèse hydrothermale</term>
<term>Pipérazine</term>
<term>Analyse diffraction RX</term>
<term>Réseau hexagonal</term>
<term>Groupe espace</term>
<term>Réseau orthorhombique</term>
<term>Structure lamellaire</term>
<term>Réseau Kagomé</term>
<term>Topologie</term>
<term>Oxalate</term>
<term>Monocristal</term>
<term>In</term>
<term>6166</term>
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<front><div type="abstract" xml:lang="en">Two novel anionic indium phosphites, formulated as [H<sub>3</sub>
O][In(HPO<sub>3</sub>
)<sub>2</sub>
] (1) and [C<sub>4</sub>
H<sub>12</sub>
N<sub>2</sub>
][In<sub>2</sub>
(HPO<sub>3</sub>
)<sub>3</sub>
 (C<sub>2</sub>
O<sub>4</sub>
)] (2), were prepared under hydrothermal conditions by using piperazine (PIP) as a structure-directing agent (SDA). Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 crystallize in the hexagonal space group P6<sub>3</sub>
mc (No. 186) and orthorhombic space group Cmcm (No. 63), respectively. Compound 1, constructed from InO<sub>6</sub>
 octahedra and HP0<sub>3</sub>
 pseudo-pyramids, exhibits a rare (3,6)-connected layer structure with kgd (Kagome dual) topology. Compound 2, on the other hand, features a 3D phosphite-oxalate hybrid structure with intersecting 8- and 12-MRs channels. From a topological perspective 2 can be regarded as a (3, 5)-connected binodal net with the Schläfli symbol (4<sup>2</sup>
.6)(4<sup>2</sup>
.6<sup>5</sup>
.8<sup>3</sup>
).</div>
</front>
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<fA11 i1="01" i2="1"><s1>HUIDUAN LI</s1>
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<fA11 i1="02" i2="1"><s1>LIRONG ZHANG</s1>
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<sZ>4 aut.</sZ>
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<fA14 i1="02"><s1>Department of Chemistry and Life Science, Chuxiong Normal University</s1>
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<sZ>1 aut.</sZ>
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O][In(HPO<sub>3</sub>
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] (1) and [C<sub>4</sub>
H<sub>12</sub>
N<sub>2</sub>
][In<sub>2</sub>
(HPO<sub>3</sub>
)<sub>3</sub>
 (C<sub>2</sub>
O<sub>4</sub>
)] (2), were prepared under hydrothermal conditions by using piperazine (PIP) as a structure-directing agent (SDA). Single-crystal X-ray diffraction analysis reveals that compounds 1 and 2 crystallize in the hexagonal space group P6<sub>3</sub>
mc (No. 186) and orthorhombic space group Cmcm (No. 63), respectively. Compound 1, constructed from InO<sub>6</sub>
 octahedra and HP0<sub>3</sub>
 pseudo-pyramids, exhibits a rare (3,6)-connected layer structure with kgd (Kagome dual) topology. Compound 2, on the other hand, features a 3D phosphite-oxalate hybrid structure with intersecting 8- and 12-MRs channels. From a topological perspective 2 can be regarded as a (3, 5)-connected binodal net with the Schläfli symbol (4<sup>2</sup>
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Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization

Construction of two novel indium phosphites with (3,6)- and (3,5)-connected frameworks: Synthesis, structure and characterization

Descripteurs français

English descriptors

Abstract

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Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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