CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000307

A new nasicon-type phosphate Co0.5Ti2(PO4)3 : I. Elaboration, optical and magnetic properties

Identifieur interne : 000307 ( PascalFrancis/Corpus ); précédent : 000306; suivant : 000308

A new nasicon-type phosphate Co0.5Ti2(PO4)3 : I. Elaboration, optical and magnetic properties

Auteurs : R. Olazcuaga ; J. M. Dance ; G. Le Flem ; J. Derouet ; L. Beaury ; P. Porcher ; A. El Bouari ; A. El Jazouli

Source :

Journal of solid state chemistry [ 0022-4596 ] ; 1999.

RBID : Pascal:99-0184869

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Structure cristalline, RPE, Champ cristallin, Spectre absorption, Cobalt phosphate, Titane phosphate, Composé quaternaire, Propriété magnétique, 7630, 7530, 6166F, Co0,5Ti2(PO4)3, Co O P Ti.

English descriptors

KwdEn :
- Absorption spectra, Cobalt phosphates, Crystal field, Crystal structure, ESR, Experimental study, Magnetic properties, Quaternary compounds, Titanium phosphates.

Abstract

A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO₄ tetrahedra sharing corners with TiO₆ octahedra. Co²⁺ is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0022-4596`
A02	`01`			`@0 JSSCBI`
A03		`1`		`@0 J. solid state chem.`
A05				`@2 143`
A06				`@2 2`
A08	`01`	`1`	`ENG`	`@1 A new nasicon-type phosphate Co_0.5Ti₂(PO₄)₃ : I. Elaboration, optical and magnetic properties`
A11	`01`	`1`		`@1 OLAZCUAGA (R.)`
A11	`02`	`1`		`@1 DANCE (J. M.)`
A11	`03`	`1`		`@1 LE FLEM (G.)`
A11	`04`	`1`		`@1 DEROUET (J.)`
A11	`05`	`1`		`@1 BEAURY (L.)`
A11	`06`	`1`		`@1 PORCHER (P.)`
A11	`07`	`1`		`@1 EL BOUARI (A.)`
A11	`08`	`1`		`@1 EL JAZOULI (A.)`
A14	`01`			`@1 Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer @2 33608 Pessac @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand @2 92195 Meudon @3 FRA @Z 4 aut. @Z 5 aut. @Z 6 aut.`
A14	`03`			`@1 Laboratoire de Chimie des Matériaux Solides. Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, BP 6621 @2 Casablanca @3 MAR @Z 7 aut. @Z 8 aut.`
A20				`@1 224-229`
A21				`@1 1999`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14677 @5 354000083351930100`
A44				`@0 0000 @1 © 1999 INIST-CNRS. All rights reserved.`
A45				`@0 25 ref.`
A47	`01`	`1`		`@0 99-0184869`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of solid state chemistry`
A66	`01`			`@0 USA`
C01	`01`		`ENG`	@0 A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO₄ tetrahedra sharing corners with TiO₆ octahedra. Co²⁺ is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.
C02	`01`	`3`		`@0 001B70F30`
C02	`02`	`3`		`@0 001B70E30`
C02	`03`	`3`		`@0 001B60A66F4`
C03	`01`	`3`	`FRE`	`@0 Etude expérimentale @5 01`
C03	`01`	`3`	`ENG`	`@0 Experimental study @5 01`
C03	`02`	`3`	`FRE`	`@0 Structure cristalline @5 02`
C03	`02`	`3`	`ENG`	`@0 Crystal structure @5 02`
C03	`03`	`3`	`FRE`	`@0 RPE @5 03`
C03	`03`	`3`	`ENG`	`@0 ESR @5 03`
C03	`04`	`3`	`FRE`	`@0 Champ cristallin @5 04`
C03	`04`	`3`	`ENG`	`@0 Crystal field @5 04`
C03	`05`	`3`	`FRE`	`@0 Spectre absorption @5 05`
C03	`05`	`3`	`ENG`	`@0 Absorption spectra @5 05`
C03	`06`	`3`	`FRE`	`@0 Cobalt phosphate @2 NK @5 06`
C03	`06`	`3`	`ENG`	`@0 Cobalt phosphates @2 NK @5 06`
C03	`07`	`3`	`FRE`	`@0 Titane phosphate @2 NK @5 07`
C03	`07`	`3`	`ENG`	`@0 Titanium phosphates @2 NK @5 07`
C03	`08`	`3`	`FRE`	`@0 Composé quaternaire @5 08`
C03	`08`	`3`	`ENG`	`@0 Quaternary compounds @5 08`
C03	`09`	`3`	`FRE`	`@0 Propriété magnétique @5 09`
C03	`09`	`3`	`ENG`	`@0 Magnetic properties @5 09`
C03	`10`	`3`	`FRE`	`@0 7630 @2 PAC @4 INC @5 56`
C03	`11`	`3`	`FRE`	`@0 7530 @2 PAC @4 INC @5 57`
C03	`12`	`3`	`FRE`	`@0 6166F @2 PAC @4 INC @5 58`
C03	`13`	`3`	`FRE`	`@0 Co0,5Ti2(PO4)3 @4 INC @5 92`
C03	`14`	`3`	`FRE`	`@0 Co O P Ti @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 16`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 16`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 17`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 17`
N21				`@1 116`

Format Inist (serveur)

NO :	PASCAL 99-0184869 INIST
ET :	A new nasicon-type phosphate Co_0.5Ti₂(PO₄)₃ : I. Elaboration, optical and magnetic properties
AU :	OLAZCUAGA (R.); DANCE (J. M.); LE FLEM (G.); DEROUET (J.); BEAURY (L.); PORCHER (P.); EL BOUARI (A.); EL JAZOULI (A.)
AF :	Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer/33608 Pessac/France (1 aut., 2 aut., 3 aut.); Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand/92195 Meudon/France (4 aut., 5 aut., 6 aut.); Laboratoire de Chimie des Matériaux Solides. Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, BP 6621/Casablanca/Maroc (7 aut., 8 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 1999; Vol. 143; No. 2; Pp. 224-229; Bibl. 25 ref.
LA :	Anglais
EA :	A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO₄ tetrahedra sharing corners with TiO₆ octahedra. Co²⁺ is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.
CC :	001B70F30; 001B70E30; 001B60A66F4
FD :	Etude expérimentale; Structure cristalline; RPE; Champ cristallin; Spectre absorption; Cobalt phosphate; Titane phosphate; Composé quaternaire; Propriété magnétique; 7630; 7530; 6166F; Co0,5Ti2(PO4)3; Co O P Ti
FG :	Composé minéral; Métal transition composé
ED :	Experimental study; Crystal structure; ESR; Crystal field; Absorption spectra; Cobalt phosphates; Titanium phosphates; Quaternary compounds; Magnetic properties
EG :	Inorganic compounds; Transition element compounds
LO :	INIST-14677.354000083351930100
ID :	99-0184869

Links to Exploration step

Pascal:99-0184869

Le document en format XML

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Ti<sub>2</sub>
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)<sub>3</sub>
 : I. Elaboration, optical and magnetic properties</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">A new nasicon-type phosphate Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 : I. Elaboration, optical and magnetic properties</title>
<author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
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<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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</author>
<author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
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<s3>FRA</s3>
<sZ>1 aut.</sZ>
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<sZ>3 aut.</sZ>
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<s3>FRA</s3>
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<sZ>3 aut.</sZ>
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<s3>FRA</s3>
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<s2>92195 Meudon</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
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<s2>92195 Meudon</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="El Bouari, A" sort="El Bouari, A" uniqKey="El Bouari A" first="A." last="El Bouari">A. El Bouari</name>
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<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="El Jazouli, A" sort="El Jazouli, A" uniqKey="El Jazouli A" first="A." last="El Jazouli">A. El Jazouli</name>
<affiliation><inist:fA14 i1="03"><s1>Laboratoire de Chimie des Matériaux Solides. Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, BP 6621</s1>
<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
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<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
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<imprint><date when="1999">1999</date>
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<seriesStmt><title level="j" type="main">Journal of solid state chemistry</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectra</term>
<term>Cobalt phosphates</term>
<term>Crystal field</term>
<term>Crystal structure</term>
<term>ESR</term>
<term>Experimental study</term>
<term>Magnetic properties</term>
<term>Quaternary compounds</term>
<term>Titanium phosphates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Structure cristalline</term>
<term>RPE</term>
<term>Champ cristallin</term>
<term>Spectre absorption</term>
<term>Cobalt phosphate</term>
<term>Titane phosphate</term>
<term>Composé quaternaire</term>
<term>Propriété magnétique</term>
<term>7630</term>
<term>7530</term>
<term>6166F</term>
<term>Co0,5Ti2(PO4)3</term>
<term>Co O P Ti</term>
</keywords>
</textClass>
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<front><div type="abstract" xml:lang="en">A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO<sub>4</sub>
 tetrahedra sharing corners with TiO<sub>6</sub>
 octahedra. Co<sup>2+</sup>
 is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>A new nasicon-type phosphate Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 : I. Elaboration, optical and magnetic properties</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>OLAZCUAGA (R.)</s1>
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<fA11 i1="02" i2="1"><s1>DANCE (J. M.)</s1>
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<fA11 i1="05" i2="1"><s1>BEAURY (L.)</s1>
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<fA11 i1="06" i2="1"><s1>PORCHER (P.)</s1>
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<fA11 i1="07" i2="1"><s1>EL BOUARI (A.)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>EL JAZOULI (A.)</s1>
</fA11>
<fA14 i1="01"><s1>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand</s1>
<s2>92195 Meudon</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Laboratoire de Chimie des Matériaux Solides. Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, BP 6621</s1>
<s2>Casablanca</s2>
<s3>MAR</s3>
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<sZ>8 aut.</sZ>
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<fA43 i1="01"><s1>INIST</s1>
<s2>14677</s2>
<s5>354000083351930100</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 1999 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>25 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>99-0184869</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO<sub>4</sub>
 tetrahedra sharing corners with TiO<sub>6</sub>
 octahedra. Co<sup>2+</sup>
 is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70F30</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70E30</s0>
</fC02>
<fC02 i1="03" i2="3"><s0>001B60A66F4</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>RPE</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>ESR</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Champ cristallin</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Crystal field</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Spectre absorption</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Absorption spectra</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Titane phosphate</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Titanium phosphates</s0>
<s2>NK</s2>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Propriété magnétique</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Magnetic properties</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>7630</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>7530</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Co0,5Ti2(PO4)3</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Co O P Ti</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>17</s5>
</fC07>
<fN21><s1>116</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 99-0184869 INIST</NO>
<ET>A new nasicon-type phosphate Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 : I. Elaboration, optical and magnetic properties</ET>
<AU>OLAZCUAGA (R.); DANCE (J. M.); LE FLEM (G.); DEROUET (J.); BEAURY (L.); PORCHER (P.); EL BOUARI (A.); EL JAZOULI (A.)</AU>
<AF>Institut de Chimie de la Matière Condensée de Bordeaux, CNRS - UPR 9048, 87, Avenue du Dr. A. Schweitzer/33608 Pessac/France (1 aut., 2 aut., 3 aut.); Laboratoire de Chimie Métallurgique et Spectroscopie des Terres Rares, CNRS - UPR 209, 1, Place Aristide Briand/92195 Meudon/France (4 aut., 5 aut., 6 aut.); Laboratoire de Chimie des Matériaux Solides. Département de Chimie, Faculté des Sciences Ben M'Sik, Sidi Othmane, BP 6621/Casablanca/Maroc (7 aut., 8 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 1999; Vol. 143; No. 2; Pp. 224-229; Bibl. 25 ref.</SO>
<LA>Anglais</LA>
<EA>A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with the R3 or the R32 space groups. The atomic arrangement is a three-dimensional framework formed by PO<sub>4</sub>
 tetrahedra sharing corners with TiO<sub>6</sub>
 octahedra. Co<sup>2+</sup>
 is located in half of the antiprism M(1) sites in a centered (R3) or off-centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co-O bond.</EA>
<CC>001B70F30; 001B70E30; 001B60A66F4</CC>
<FD>Etude expérimentale; Structure cristalline; RPE; Champ cristallin; Spectre absorption; Cobalt phosphate; Titane phosphate; Composé quaternaire; Propriété magnétique; 7630; 7530; 6166F; Co0,5Ti2(PO4)3; Co O P Ti</FD>
<FG>Composé minéral; Métal transition composé</FG>
<ED>Experimental study; Crystal structure; ESR; Crystal field; Absorption spectra; Cobalt phosphates; Titanium phosphates; Quaternary compounds; Magnetic properties</ED>
<EG>Inorganic compounds; Transition element compounds</EG>
<LO>INIST-14677.354000083351930100</LO>
<ID>99-0184869</ID>
</server>
</inist>
</record>

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A new nasicon-type phosphate Co0.5Ti2(PO4)3 : I. Elaboration, optical and magnetic properties

A new nasicon-type phosphate Co0.5Ti2(PO4)3 : I. Elaboration, optical and magnetic properties

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