CobaltMaghrebV1, PascalFrancis, Corpus, bibRecord, 000306

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

Identifieur interne : 000306 ( PascalFrancis/Corpus ); précédent : 000305; suivant : 000307

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

Auteurs : J. Derouet ; L. Beaury ; P. Porcher ; R. Olazcuaga ; J. M. Dance ; G. Le Flem ; A. El Bouari ; A. El Jazouli

Source :

Journal of solid state chemistry [ 0022-4596 ] ; 1999.

RBID : Pascal:99-0185620

Descripteurs français

Pascal (Inist)
- Etude théorique, Cobalt phosphate, Titane phosphate, Composé quaternaire, Susceptibilité magnétique, Modèle phénoménologique, Méthode semiempirique, Niveau énergie, Facteur g, Champ cristallin, Polycristal, 7170C, 7530C, Co0,5Ti2(PO4)3, Co O P Ti.

English descriptors

KwdEn :
- Cobalt phosphates, Crystal field, Energy levels, Magnetic susceptibility, Phenomenological model, Polycrystals, Quaternary compounds, Semiempirical method, Theoretical study, Titanium phosphates, g-factor.

Abstract

The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co_0.5Ti₂(PO₄)₃ were simultaneously reproduced by use of a crystal field theory involving a set of F^k,ζ, free ion, and B^k_q crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0022-4596`
A02	`01`			`@0 JSSCBI`
A03		`1`		`@0 J. solid state chem.`
A05				`@2 143`
A06				`@2 2`
A08	`01`	`1`	`ENG`	`@1 A new nasicon-type phosphate : Co_0.5Ti₂(PO₄)₃. II. Simulation of optical and magnetic properties`
A11	`01`	`1`		`@1 DEROUET (J.)`
A11	`02`	`1`		`@1 BEAURY (L.)`
A11	`03`	`1`		`@1 PORCHER (P.)`
A11	`04`	`1`		`@1 OLAZCUAGA (R.)`
A11	`05`	`1`		`@1 DANCE (J. M.)`
A11	`06`	`1`		`@1 LE FLEM (G.)`
A11	`07`	`1`		`@1 EL BOUARI (A.)`
A11	`08`	`1`		`@1 EL JAZOULI (A.)`
A14	`01`			`@1 Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie @2 75231 Paris @3 FRA @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer @2 33608 Pessac @3 FRA @Z 4 aut. @Z 5 aut. @Z 6 aut.`
A14	`03`			`@1 Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621 @2 Casablanca @3 MAR @Z 7 aut. @Z 8 aut.`
A20				`@1 230-238`
A21				`@1 1999`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14677 @5 354000083351930110`
A44				`@0 0000 @1 © 1999 INIST-CNRS. All rights reserved.`
A45				`@0 28 ref.`
A47	`01`	`1`		`@0 99-0185620`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of solid state chemistry`
A66	`01`			`@0 USA`
C01	`01`		`ENG`	`@0 The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co_0.5Ti₂(PO₄)₃ were simultaneously reproduced by use of a crystal field theory involving a set of F^k,ζ, free ion, and B^k_q crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.`
C02	`01`	`3`		`@0 001B70A70C`
C02	`02`	`3`		`@0 001B70E30C`
C03	`01`	`3`	`FRE`	`@0 Etude théorique @5 01`
C03	`01`	`3`	`ENG`	`@0 Theoretical study @5 01`
C03	`02`	`3`	`FRE`	`@0 Cobalt phosphate @2 NK @5 02`
C03	`02`	`3`	`ENG`	`@0 Cobalt phosphates @2 NK @5 02`
C03	`03`	`3`	`FRE`	`@0 Titane phosphate @2 NK @5 03`
C03	`03`	`3`	`ENG`	`@0 Titanium phosphates @2 NK @5 03`
C03	`04`	`3`	`FRE`	`@0 Composé quaternaire @5 04`
C03	`04`	`3`	`ENG`	`@0 Quaternary compounds @5 04`
C03	`05`	`3`	`FRE`	`@0 Susceptibilité magnétique @5 05`
C03	`05`	`3`	`ENG`	`@0 Magnetic susceptibility @5 05`
C03	`06`	`X`	`FRE`	`@0 Modèle phénoménologique @5 06`
C03	`06`	`X`	`ENG`	`@0 Phenomenological model @5 06`
C03	`06`	`X`	`SPA`	`@0 Modelo fenomenológico @5 06`
C03	`07`	`X`	`FRE`	`@0 Méthode semiempirique @5 07`
C03	`07`	`X`	`ENG`	`@0 Semiempirical method @5 07`
C03	`07`	`X`	`SPA`	`@0 Método semiempírico @5 07`
C03	`08`	`3`	`FRE`	`@0 Niveau énergie @5 08`
C03	`08`	`3`	`ENG`	`@0 Energy levels @5 08`
C03	`09`	`3`	`FRE`	`@0 Facteur g @5 09`
C03	`09`	`3`	`ENG`	`@0 g-factor @5 09`
C03	`10`	`3`	`FRE`	`@0 Champ cristallin @5 10`
C03	`10`	`3`	`ENG`	`@0 Crystal field @5 10`
C03	`11`	`3`	`FRE`	`@0 Polycristal @5 11`
C03	`11`	`3`	`ENG`	`@0 Polycrystals @5 11`
C03	`12`	`3`	`FRE`	`@0 7170C @2 PAC @4 INC @5 56`
C03	`13`	`3`	`FRE`	`@0 7530C @2 PAC @4 INC @5 57`
C03	`14`	`3`	`FRE`	`@0 Co0,5Ti2(PO4)3 @4 INC @5 92`
C03	`15`	`3`	`FRE`	`@0 Co O P Ti @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 16`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 16`
C07	`02`	`3`	`FRE`	`@0 Métal transition composé @5 17`
C07	`02`	`3`	`ENG`	`@0 Transition element compounds @5 17`
N21				`@1 116`

Format Inist (serveur)

NO :	PASCAL 99-0185620 INIST
ET :	A new nasicon-type phosphate : Co_0.5Ti₂(PO₄)₃. II. Simulation of optical and magnetic properties
AU :	DEROUET (J.); BEAURY (L.); PORCHER (P.); OLAZCUAGA (R.); DANCE (J. M.); LE FLEM (G.); EL BOUARI (A.); EL JAZOULI (A.)
AF :	Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie/75231 Paris/France (1 aut., 2 aut., 3 aut.); Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer/33608 Pessac/France (4 aut., 5 aut., 6 aut.); Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621/Casablanca/Maroc (7 aut., 8 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 1999; Vol. 143; No. 2; Pp. 230-238; Bibl. 28 ref.
LA :	Anglais
EA :	The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co_0.5Ti₂(PO₄)₃ were simultaneously reproduced by use of a crystal field theory involving a set of F^k,ζ, free ion, and B^k_q crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.
CC :	001B70A70C; 001B70E30C
FD :	Etude théorique; Cobalt phosphate; Titane phosphate; Composé quaternaire; Susceptibilité magnétique; Modèle phénoménologique; Méthode semiempirique; Niveau énergie; Facteur g; Champ cristallin; Polycristal; 7170C; 7530C; Co0,5Ti2(PO4)3; Co O P Ti
FG :	Composé minéral; Métal transition composé
ED :	Theoretical study; Cobalt phosphates; Titanium phosphates; Quaternary compounds; Magnetic susceptibility; Phenomenological model; Semiempirical method; Energy levels; g-factor; Crystal field; Polycrystals
EG :	Inorganic compounds; Transition element compounds
SD :	Modelo fenomenológico; Método semiempírico
LO :	INIST-14677.354000083351930110
ID :	99-0185620

Links to Exploration step

Pascal:99-0185620

Le document en format XML

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Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">A new nasicon-type phosphate : Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</title>
<author><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J." last="Derouet">J. Derouet</name>
<affiliation><inist:fA14 i1="01"><s1>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie</s1>
<s2>75231 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
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<author><name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L." last="Beaury">L. Beaury</name>
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<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
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</author>
<author><name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P." last="Porcher">P. Porcher</name>
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<s2>75231 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
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<sZ>3 aut.</sZ>
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</affiliation>
</author>
<author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
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<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
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<s3>FRA</s3>
<sZ>4 aut.</sZ>
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<author><name sortKey="Le Flem, G" sort="Le Flem, G" uniqKey="Le Flem G" first="G." last="Le Flem">G. Le Flem</name>
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<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
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</author>
<author><name sortKey="El Bouari, A" sort="El Bouari, A" uniqKey="El Bouari A" first="A." last="El Bouari">A. El Bouari</name>
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<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
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</affiliation>
</author>
<author><name sortKey="El Jazouli, A" sort="El Jazouli, A" uniqKey="El Jazouli A" first="A." last="El Jazouli">A. El Jazouli</name>
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<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
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<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
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<imprint><date when="1999">1999</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt phosphates</term>
<term>Crystal field</term>
<term>Energy levels</term>
<term>Magnetic susceptibility</term>
<term>Phenomenological model</term>
<term>Polycrystals</term>
<term>Quaternary compounds</term>
<term>Semiempirical method</term>
<term>Theoretical study</term>
<term>Titanium phosphates</term>
<term>g-factor</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude théorique</term>
<term>Cobalt phosphate</term>
<term>Titane phosphate</term>
<term>Composé quaternaire</term>
<term>Susceptibilité magnétique</term>
<term>Modèle phénoménologique</term>
<term>Méthode semiempirique</term>
<term>Niveau énergie</term>
<term>Facteur g</term>
<term>Champ cristallin</term>
<term>Polycristal</term>
<term>7170C</term>
<term>7530C</term>
<term>Co0,5Ti2(PO4)3</term>
<term>Co O P Ti</term>
</keywords>
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<front><div type="abstract" xml:lang="en">The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-4596</s0>
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<fA08 i1="01" i2="1" l="ENG"><s1>A new nasicon-type phosphate : Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>DEROUET (J.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BEAURY (L.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>PORCHER (P.)</s1>
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<fA11 i1="04" i2="1"><s1>OLAZCUAGA (R.)</s1>
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<fA11 i1="05" i2="1"><s1>DANCE (J. M.)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>LE FLEM (G.)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>EL BOUARI (A.)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>EL JAZOULI (A.)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie</s1>
<s2>75231 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer</s1>
<s2>33608 Pessac</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621</s1>
<s2>Casablanca</s2>
<s3>MAR</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA20><s1>230-238</s1>
</fA20>
<fA21><s1>1999</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>14677</s2>
<s5>354000083351930110</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 1999 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>28 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>99-0185620</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0>
</fA64>
<fA66 i1="01"><s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70A70C</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70E30C</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Etude théorique</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Theoretical study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Cobalt phosphates</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Titane phosphate</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Titanium phosphates</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Composé quaternaire</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Quaternary compounds</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Magnetic susceptibility</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Modèle phénoménologique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Phenomenological model</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Modelo fenomenológico</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Méthode semiempirique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Semiempirical method</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Método semiempírico</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Niveau énergie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Energy levels</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Facteur g</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>g-factor</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Champ cristallin</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Crystal field</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Polycristal</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Polycrystals</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>7170C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>7530C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Co0,5Ti2(PO4)3</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Co O P Ti</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>17</s5>
</fC07>
<fN21><s1>116</s1>
</fN21>
</pA>
</standard>
<server><NO>PASCAL 99-0185620 INIST</NO>
<ET>A new nasicon-type phosphate : Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</ET>
<AU>DEROUET (J.); BEAURY (L.); PORCHER (P.); OLAZCUAGA (R.); DANCE (J. M.); LE FLEM (G.); EL BOUARI (A.); EL JAZOULI (A.)</AU>
<AF>Laboratoire de Chimie Appliquée de l'Etat Solide, ENSCP, 11 rue Pierre et Marie Curie/75231 Paris/France (1 aut., 2 aut., 3 aut.); Institut de Chimie de la Matière Condensée, CNRS-UPR9048, Av. Dr Schweitzer/33608 Pessac/France (4 aut., 5 aut., 6 aut.); Département de Chimie, Faculté des Sciences M'Sik Sidi Othmane, BP 6621/Casablanca/Maroc (7 aut., 8 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of solid state chemistry; ISSN 0022-4596; Coden JSSCBI; Etats-Unis; Da. 1999; Vol. 143; No. 2; Pp. 230-238; Bibl. 28 ref.</SO>
<LA>Anglais</LA>
<EA>The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</EA>
<CC>001B70A70C; 001B70E30C</CC>
<FD>Etude théorique; Cobalt phosphate; Titane phosphate; Composé quaternaire; Susceptibilité magnétique; Modèle phénoménologique; Méthode semiempirique; Niveau énergie; Facteur g; Champ cristallin; Polycristal; 7170C; 7530C; Co0,5Ti2(PO4)3; Co O P Ti</FD>
<FG>Composé minéral; Métal transition composé</FG>
<ED>Theoretical study; Cobalt phosphates; Titanium phosphates; Quaternary compounds; Magnetic susceptibility; Phenomenological model; Semiempirical method; Energy levels; g-factor; Crystal field; Polycrystals</ED>
<EG>Inorganic compounds; Transition element compounds</EG>
<SD>Modelo fenomenológico; Método semiempírico</SD>
<LO>INIST-14677.354000083351930110</LO>
<ID>99-0185620</ID>
</server>
</inist>
</record>

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A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

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