CobaltMaghrebV1, PascalFrancis, Checkpoint, bibRecord, 000306

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

Identifieur interne : 000306 ( PascalFrancis/Checkpoint ); précédent : 000305; suivant : 000307

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

Auteurs : J. Derouet [France] ; L. Beaury [France] ; P. Porcher [France] ; R. Olazcuaga [France] ; J. M. Dance [France] ; G. Le Flem [France] ; A. El Bouari [Maroc] ; A. El Jazouli [Maroc]

Source :

Journal of solid state chemistry [ 0022-4596 ] ; 1999.

RBID : Pascal:99-0185620

Descripteurs français

Pascal (Inist)
- Etude théorique, Cobalt phosphate, Titane phosphate, Composé quaternaire, Susceptibilité magnétique, Modèle phénoménologique, Méthode semiempirique, Niveau énergie, Facteur g, Champ cristallin, Polycristal, 7170C, 7530C, Co0,5Ti2(PO4)3, Co O P Ti.

English descriptors

KwdEn :
- Cobalt phosphates, Crystal field, Energy levels, Magnetic susceptibility, Phenomenological model, Polycrystals, Quaternary compounds, Semiempirical method, Theoretical study, Titanium phosphates, g-factor.

Abstract

The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co_0.5Ti₂(PO₄)₃ were simultaneously reproduced by use of a crystal field theory involving a set of F^k,ζ, free ion, and B^k_q crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.

Affiliations:

France, Maroc
Aquitaine, Nouvelle-Aquitaine, Île-de-France
Paris, Pessac

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Pascal:99-0185620

Le document en format XML

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Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">A new nasicon-type phosphate : Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</title>
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<author><name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
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<author><name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
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<series><title level="j" type="main">Journal of solid state chemistry</title>
<title level="j" type="abbreviated">J. solid state chem.</title>
<idno type="ISSN">0022-4596</idno>
<imprint><date when="1999">1999</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt phosphates</term>
<term>Crystal field</term>
<term>Energy levels</term>
<term>Magnetic susceptibility</term>
<term>Phenomenological model</term>
<term>Polycrystals</term>
<term>Quaternary compounds</term>
<term>Semiempirical method</term>
<term>Theoretical study</term>
<term>Titanium phosphates</term>
<term>g-factor</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude théorique</term>
<term>Cobalt phosphate</term>
<term>Titane phosphate</term>
<term>Composé quaternaire</term>
<term>Susceptibilité magnétique</term>
<term>Modèle phénoménologique</term>
<term>Méthode semiempirique</term>
<term>Niveau énergie</term>
<term>Facteur g</term>
<term>Champ cristallin</term>
<term>Polycristal</term>
<term>7170C</term>
<term>7530C</term>
<term>Co0,5Ti2(PO4)3</term>
<term>Co O P Ti</term>
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<front><div type="abstract" xml:lang="en">The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co<sub>0.5</sub>
Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</div>
</front>
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Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. II. Simulation of optical and magnetic properties</s1>
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Ti<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 were simultaneously reproduced by use of a crystal field theory involving a set of F<sup>k</sup>
,ζ, free ion, and B<sup>k</sup>
<sub>q</sub>
 crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure.</s0>
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<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>g-factor</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Champ cristallin</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Crystal field</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Polycristal</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Polycrystals</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>7170C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>7530C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Co0,5Ti2(PO4)3</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Co O P Ti</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition composé</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element compounds</s0>
<s5>17</s5>
</fC07>
<fN21><s1>116</s1>
</fN21>
</pA>
</standard>
</inist>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
<region><li>Aquitaine</li>
<li>Nouvelle-Aquitaine</li>
<li>Île-de-France</li>
</region>
<settlement><li>Paris</li>
<li>Pessac</li>
</settlement>
</list>
<tree><country name="France"><region name="Île-de-France"><name sortKey="Derouet, J" sort="Derouet, J" uniqKey="Derouet J" first="J." last="Derouet">J. Derouet</name>
</region>
<name sortKey="Beaury, L" sort="Beaury, L" uniqKey="Beaury L" first="L." last="Beaury">L. Beaury</name>
<name sortKey="Dance, J M" sort="Dance, J M" uniqKey="Dance J" first="J. M." last="Dance">J. M. Dance</name>
<name sortKey="Le Flem, G" sort="Le Flem, G" uniqKey="Le Flem G" first="G." last="Le Flem">G. Le Flem</name>
<name sortKey="Olazcuaga, R" sort="Olazcuaga, R" uniqKey="Olazcuaga R" first="R." last="Olazcuaga">R. Olazcuaga</name>
<name sortKey="Porcher, P" sort="Porcher, P" uniqKey="Porcher P" first="P." last="Porcher">P. Porcher</name>
</country>
<country name="Maroc"><noRegion><name sortKey="El Bouari, A" sort="El Bouari, A" uniqKey="El Bouari A" first="A." last="El Bouari">A. El Bouari</name>
</noRegion>
<name sortKey="El Jazouli, A" sort="El Jazouli, A" uniqKey="El Jazouli A" first="A." last="El Jazouli">A. El Jazouli</name>
</country>
</tree>
</affiliations>
</record>

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

A new nasicon-type phosphate : Co0.5Ti2(PO4)3. II. Simulation of optical and magnetic properties

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