Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)
Identifieur interne : 000178 ( PascalFrancis/Checkpoint ); précédent : 000177; suivant : 000179Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)
Auteurs : A. Ait Salah [Maroc] ; K. Benkhouja [Maroc] ; K. Jaafari [Maroc] ; J. Romero De Paz [Espagne] ; E. Climent [Espagne] ; R. Saez Puche [Espagne]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 2005.
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Abstract
Divanadates of general formula ZnMV2O7 (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV2O7and ZnNiV2O7 crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P21/c, while the third member of this family of vanadates ZnCuV2O7 shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M2V2O7 vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn2+ to give the ZnMV2O7 samples studied in the present work.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>O<sub>7</sub> (M = Co, Ni and Cu)</title><author><name sortKey="Ait Salah, A" sort="Ait Salah, A" uniqKey="Ait Salah A" first="A." last="Ait Salah">A. Ait Salah</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Romero De Paz, J" sort="Romero De Paz, J" uniqKey="Romero De Paz J" first="J." last="Romero De Paz">J. Romero De Paz</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author><author><name sortKey="Climent, E" sort="Climent, E" uniqKey="Climent E" first="E." last="Climent">E. Climent</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author><author><name sortKey="Saez Puche, R" sort="Saez Puche, R" uniqKey="Saez Puche R" first="R." last="Saez Puche">R. Saez Puche</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">05-0465553</idno><date when="2005">2005</date><idno type="stanalyst">PASCAL 05-0465553 INIST</idno><idno type="RBID">Pascal:05-0465553</idno><idno type="wicri:Area/PascalFrancis/Corpus">000176</idno><idno type="wicri:Area/PascalFrancis/Curation">000119</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000178</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000178</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>O<sub>7</sub> (M = Co, Ni and Cu)</title><author><name sortKey="Ait Salah, A" sort="Ait Salah, A" uniqKey="Ait Salah A" first="A." last="Ait Salah">A. Ait Salah</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Maroc</country><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author><author><name sortKey="Romero De Paz, J" sort="Romero De Paz, J" uniqKey="Romero De Paz J" first="J." last="Romero De Paz">J. Romero De Paz</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author><author><name sortKey="Climent, E" sort="Climent, E" uniqKey="Climent E" first="E." last="Climent">E. Climent</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author><author><name sortKey="Saez Puche, R" sort="Saez Puche, R" uniqKey="Saez Puche R" first="R." last="Saez Puche">R. Saez Puche</name><affiliation wicri:level="2"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté de Madrid</region></placeName></affiliation></author></analytic><series><title level="j" type="main">Journal of alloys and compounds</title><title level="j" type="abbreviated">J. alloys compd.</title><idno type="ISSN">0925-8388</idno><imprint><date when="2005">2005</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of alloys and compounds</title><title level="j" type="abbreviated">J. alloys compd.</title><idno type="ISSN">0925-8388</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetic materials</term><term>Chemical synthesis</term><term>Crystal structure</term><term>Magnetic properties</term><term>Magnetic susceptibility</term><term>Monoclinic lattices</term><term>Neel temperature</term><term>Specific heat</term><term>Vanadates</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Propriété magnétique</term><term>Structure cristalline</term><term>Susceptibilité magnétique</term><term>Chaleur massique</term><term>Point Néel</term><term>Synthèse chimique</term><term>Diffraction RX</term><term>Réseau monoclinique</term><term>Vanadate</term><term>Matériau antiferromagnétique</term><term>7550E</term><term>6166F</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Divanadates of general formula ZnMV<sub>2</sub>O<sub>7</sub> (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>O<sub>7</sub>and ZnNiV<sub>2</sub>O<sub>7</sub> crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>O<sub>7</sub> shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>V<sub>2</sub>O<sub>7</sub> vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup> to give the ZnMV<sub>2</sub>O<sub>7</sub> samples studied in the present work.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0925-8388</s0></fA01><fA03 i2="1"><s0>J. alloys compd.</s0></fA03><fA05><s2>402</s2></fA05><fA06><s2>1-2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>O<sub>7</sub> (M = Co, Ni and Cu)</s1></fA08><fA11 i1="01" i2="1"><s1>AIT SALAH (A.)</s1></fA11><fA11 i1="02" i2="1"><s1>BENKHOUJA (K.)</s1></fA11><fA11 i1="03" i2="1"><s1>JAAFARI (K.)</s1></fA11><fA11 i1="04" i2="1"><s1>ROMERO DE PAZ (J.)</s1></fA11><fA11 i1="05" i2="1"><s1>CLIMENT (E.)</s1></fA11><fA11 i1="06" i2="1"><s1>SAEZ PUCHE (R.)</s1></fA11><fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1><s2>El Jadida</s2><s3>MAR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1><s2>28040 Madrid</s2><s3>ESP</s3><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></fA14><fA20><s1>213-218</s1></fA20><fA21><s1>2005</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>1151</s2><s5>354000131993370380</s5></fA43><fA44><s0>0000</s0><s1>© 2005 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>11 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>05-0465553</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal of alloys and compounds</s0></fA64><fA66 i1="01"><s0>CHE</s0></fA66><fC01 i1="01" l="ENG"><s0>Divanadates of general formula ZnMV<sub>2</sub>O<sub>7</sub> (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>O<sub>7</sub>and ZnNiV<sub>2</sub>O<sub>7</sub> crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>O<sub>7</sub> shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>V<sub>2</sub>O<sub>7</sub> vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup> to give the ZnMV<sub>2</sub>O<sub>7</sub> samples studied in the present work.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66F</s0></fC02><fC02 i1="02" i2="3"><s0>001B70E50E</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Propriété magnétique</s0><s5>02</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Magnetic properties</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>03</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Crystal structure</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0><s5>05</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Magnetic susceptibility</s0><s5>05</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Chaleur massique</s0><s5>06</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Specific heat</s0><s5>06</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Point Néel</s0><s5>07</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Neel temperature</s0><s5>07</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Synthèse chimique</s0><s5>08</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Chemical synthesis</s0><s5>08</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Síntesis química</s0><s5>08</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Diffraction RX</s0><s5>09</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>XRD</s0><s5>09</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>Réseau monoclinique</s0><s5>18</s5></fC03><fC03 i1="08" i2="3" l="ENG"><s0>Monoclinic lattices</s0><s5>18</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Vanadate</s0><s2>NA</s2><s5>19</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Vanadates</s0><s2>NA</s2><s5>19</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>Matériau antiferromagnétique</s0><s5>20</s5></fC03><fC03 i1="10" i2="3" l="ENG"><s0>Antiferromagnetic materials</s0><s5>20</s5></fC03><fC03 i1="11" i2="3" l="FRE"><s0>7550E</s0><s4>INC</s4><s5>60</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>6166F</s0><s4>INC</s4><s5>61</s5></fC03><fN21><s1>325</s1></fN21></pA></standard></inist><affiliations><list><country><li>Espagne</li><li>Maroc</li></country><region><li>Communauté de Madrid</li></region></list><tree><country name="Maroc"><noRegion><name sortKey="Ait Salah, A" sort="Ait Salah, A" uniqKey="Ait Salah A" first="A." last="Ait Salah">A. Ait Salah</name></noRegion><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name></country><country name="Espagne"><region name="Communauté de Madrid"><name sortKey="Romero De Paz, J" sort="Romero De Paz, J" uniqKey="Romero De Paz J" first="J." last="Romero De Paz">J. Romero De Paz</name></region><name sortKey="Climent, E" sort="Climent, E" uniqKey="Climent E" first="E." last="Climent">E. Climent</name><name sortKey="Saez Puche, R" sort="Saez Puche, R" uniqKey="Saez Puche R" first="R." last="Saez Puche">R. Saez Puche</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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