CobaltMaghrebV1, PascalFrancis, Curation, bibRecord, 000119

Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)

Identifieur interne : 000119 ( PascalFrancis/Curation ); précédent : 000118; suivant : 000120

Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)

Auteurs : A. Ait Salah [Maroc] ; K. Benkhouja [Maroc] ; K. Jaafari [Maroc] ; J. Romero De Paz [Espagne] ; E. Climent [Espagne] ; R. Saez Puche [Espagne]

Source :

Journal of alloys and compounds [ 0925-8388 ] ; 2005.

RBID : Pascal:05-0465553

Descripteurs français

Pascal (Inist)
- Propriété magnétique, Structure cristalline, Susceptibilité magnétique, Chaleur massique, Point Néel, Synthèse chimique, Diffraction RX, Réseau monoclinique, Vanadate, Matériau antiferromagnétique, 7550E, 6166F.

English descriptors

KwdEn :
- Antiferromagnetic materials, Chemical synthesis, Crystal structure, Magnetic properties, Magnetic susceptibility, Monoclinic lattices, Neel temperature, Specific heat, Vanadates, XRD.

Abstract

Divanadates of general formula ZnMV₂O₇ (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV₂O₇and ZnNiV₂O₇ crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2₁/c, while the third member of this family of vanadates ZnCuV₂O₇ shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M₂V₂O₇ vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn²⁺ to give the ZnMV₂O₇ samples studied in the present work.

A01	`01`	`1`		`@0 0925-8388`
A03		`1`		`@0 J. alloys compd.`
A05				`@2 402`
A06				`@2 1-2`
A08	`01`	`1`	`ENG`	`@1 Structural characterization and magnetic properties of divanadates ZnMV₂O₇ (M = Co, Ni and Cu)`
A11	`01`	`1`		`@1 AIT SALAH (A.)`
A11	`02`	`1`		`@1 BENKHOUJA (K.)`
A11	`03`	`1`		`@1 JAAFARI (K.)`
A11	`04`	`1`		`@1 ROMERO DE PAZ (J.)`
A11	`05`	`1`		`@1 CLIMENT (E.)`
A11	`06`	`1`		`@1 SAEZ PUCHE (R.)`
A14	`01`			`@1 L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065 @2 El Jadida @3 MAR @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n @2 28040 Madrid @3 ESP @Z 4 aut. @Z 5 aut. @Z 6 aut.`
A20				`@1 213-218`
A21				`@1 2005`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 1151 @5 354000131993370380`
A44				`@0 0000 @1 © 2005 INIST-CNRS. All rights reserved.`
A45				`@0 11 ref.`
A47	`01`	`1`		`@0 05-0465553`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of alloys and compounds`
A66	`01`			`@0 CHE`
C01	`01`		`ENG`	@0 Divanadates of general formula ZnMV₂O₇ (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV₂O₇and ZnNiV₂O₇ crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2₁/c, while the third member of this family of vanadates ZnCuV₂O₇ shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M₂V₂O₇ vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn²⁺ to give the ZnMV₂O₇ samples studied in the present work.
C02	`01`	`3`		`@0 001B60A66F`
C02	`02`	`3`		`@0 001B70E50E`
C03	`01`	`3`	`FRE`	`@0 Propriété magnétique @5 02`
C03	`01`	`3`	`ENG`	`@0 Magnetic properties @5 02`
C03	`02`	`3`	`FRE`	`@0 Structure cristalline @5 03`
C03	`02`	`3`	`ENG`	`@0 Crystal structure @5 03`
C03	`03`	`3`	`FRE`	`@0 Susceptibilité magnétique @5 05`
C03	`03`	`3`	`ENG`	`@0 Magnetic susceptibility @5 05`
C03	`04`	`3`	`FRE`	`@0 Chaleur massique @5 06`
C03	`04`	`3`	`ENG`	`@0 Specific heat @5 06`
C03	`05`	`3`	`FRE`	`@0 Point Néel @5 07`
C03	`05`	`3`	`ENG`	`@0 Neel temperature @5 07`
C03	`06`	`X`	`FRE`	`@0 Synthèse chimique @5 08`
C03	`06`	`X`	`ENG`	`@0 Chemical synthesis @5 08`
C03	`06`	`X`	`SPA`	`@0 Síntesis química @5 08`
C03	`07`	`3`	`FRE`	`@0 Diffraction RX @5 09`
C03	`07`	`3`	`ENG`	`@0 XRD @5 09`
C03	`08`	`3`	`FRE`	`@0 Réseau monoclinique @5 18`
C03	`08`	`3`	`ENG`	`@0 Monoclinic lattices @5 18`
C03	`09`	`3`	`FRE`	`@0 Vanadate @2 NA @5 19`
C03	`09`	`3`	`ENG`	`@0 Vanadates @2 NA @5 19`
C03	`10`	`3`	`FRE`	`@0 Matériau antiferromagnétique @5 20`
C03	`10`	`3`	`ENG`	`@0 Antiferromagnetic materials @5 20`
C03	`11`	`3`	`FRE`	`@0 7550E @4 INC @5 60`
C03	`12`	`3`	`FRE`	`@0 6166F @4 INC @5 61`
N21				`@1 325`

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Le document en format XML

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O<sub>7</sub>
 (M = Co, Ni and Cu)</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>
O<sub>7</sub>
 (M = Co, Ni and Cu)</title>
<author><name sortKey="Ait Salah, A" sort="Ait Salah, A" uniqKey="Ait Salah A" first="A." last="Ait Salah">A. Ait Salah</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Benkhouja, K" sort="Benkhouja, K" uniqKey="Benkhouja K" first="K." last="Benkhouja">K. Benkhouja</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Jaafari, K" sort="Jaafari, K" uniqKey="Jaafari K" first="K." last="Jaafari">K. Jaafari</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
</affiliation>
</author>
<author><name sortKey="Romero De Paz, J" sort="Romero De Paz, J" uniqKey="Romero De Paz J" first="J." last="Romero De Paz">J. Romero De Paz</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1>
<s2>28040 Madrid</s2>
<s3>ESP</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
</affiliation>
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<s2>28040 Madrid</s2>
<s3>ESP</s3>
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<sZ>6 aut.</sZ>
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<country>Espagne</country>
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<author><name sortKey="Saez Puche, R" sort="Saez Puche, R" uniqKey="Saez Puche R" first="R." last="Saez Puche">R. Saez Puche</name>
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<s2>28040 Madrid</s2>
<s3>ESP</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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</analytic>
<series><title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
<imprint><date when="2005">2005</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetic materials</term>
<term>Chemical synthesis</term>
<term>Crystal structure</term>
<term>Magnetic properties</term>
<term>Magnetic susceptibility</term>
<term>Monoclinic lattices</term>
<term>Neel temperature</term>
<term>Specific heat</term>
<term>Vanadates</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Propriété magnétique</term>
<term>Structure cristalline</term>
<term>Susceptibilité magnétique</term>
<term>Chaleur massique</term>
<term>Point Néel</term>
<term>Synthèse chimique</term>
<term>Diffraction RX</term>
<term>Réseau monoclinique</term>
<term>Vanadate</term>
<term>Matériau antiferromagnétique</term>
<term>7550E</term>
<term>6166F</term>
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<front><div type="abstract" xml:lang="en">Divanadates of general formula ZnMV<sub>2</sub>
O<sub>7</sub>
 (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>
O<sub>7</sub>
and ZnNiV<sub>2</sub>
O<sub>7</sub>
 crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>
/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>
O<sub>7</sub>
 shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>
V<sub>2</sub>
O<sub>7</sub>
 vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup>
 to give the ZnMV<sub>2</sub>
O<sub>7</sub>
 samples studied in the present work.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0925-8388</s0>
</fA01>
<fA03 i2="1"><s0>J. alloys compd.</s0>
</fA03>
<fA05><s2>402</s2>
</fA05>
<fA06><s2>1-2</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>
O<sub>7</sub>
 (M = Co, Ni and Cu)</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>AIT SALAH (A.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>BENKHOUJA (K.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>JAAFARI (K.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>ROMERO DE PAZ (J.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>CLIMENT (E.)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>SAEZ PUCHE (R.)</s1>
</fA11>
<fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1>
<s2>El Jadida</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1>
<s2>28040 Madrid</s2>
<s3>ESP</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA20><s1>213-218</s1>
</fA20>
<fA21><s1>2005</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>1151</s2>
<s5>354000131993370380</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2005 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>11 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>05-0465553</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of alloys and compounds</s0>
</fA64>
<fA66 i1="01"><s0>CHE</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Divanadates of general formula ZnMV<sub>2</sub>
O<sub>7</sub>
 (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>
O<sub>7</sub>
and ZnNiV<sub>2</sub>
O<sub>7</sub>
 crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>
/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>
O<sub>7</sub>
 shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>
V<sub>2</sub>
O<sub>7</sub>
 vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup>
 to give the ZnMV<sub>2</sub>
O<sub>7</sub>
 samples studied in the present work.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B60A66F</s0>
</fC02>
<fC02 i1="02" i2="3"><s0>001B70E50E</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Propriété magnétique</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Magnetic properties</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Susceptibilité magnétique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Magnetic susceptibility</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Chaleur massique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Specific heat</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Point Néel</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Neel temperature</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Synthèse chimique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Chemical synthesis</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Síntesis química</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>XRD</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Réseau monoclinique</s0>
<s5>18</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Monoclinic lattices</s0>
<s5>18</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Vanadate</s0>
<s2>NA</s2>
<s5>19</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Vanadates</s0>
<s2>NA</s2>
<s5>19</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Matériau antiferromagnétique</s0>
<s5>20</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Antiferromagnetic materials</s0>
<s5>20</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>7550E</s0>
<s4>INC</s4>
<s5>60</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>6166F</s0>
<s4>INC</s4>
<s5>61</s5>
</fC03>
<fN21><s1>325</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)

Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)

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