Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)
Identifieur interne : 000176 ( PascalFrancis/Corpus ); précédent : 000175; suivant : 000177Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu)
Auteurs : A. Ait Salah ; K. Benkhouja ; K. Jaafari ; J. Romero De Paz ; E. Climent ; R. Saez PucheSource :
- Journal of alloys and compounds [ 0925-8388 ] ; 2005.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Divanadates of general formula ZnMV2O7 (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV2O7and ZnNiV2O7 crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P21/c, while the third member of this family of vanadates ZnCuV2O7 shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M2V2O7 vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn2+ to give the ZnMV2O7 samples studied in the present work.
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Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 05-0465553 INIST |
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ET : | Structural characterization and magnetic properties of divanadates ZnMV2O7 (M = Co, Ni and Cu) |
AU : | AIT SALAH (A.); BENKHOUJA (K.); JAAFARI (K.); ROMERO DE PAZ (J.); CLIMENT (E.); SAEZ PUCHE (R.) |
AF : | L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065/El Jadida/Maroc (1 aut., 2 aut., 3 aut.); Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n/28040 Madrid/Espagne (4 aut., 5 aut., 6 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2005; Vol. 402; No. 1-2; Pp. 213-218; Bibl. 11 ref. |
LA : | Anglais |
EA : | Divanadates of general formula ZnMV2O7 (M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV2O7and ZnNiV2O7 crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P21/c, while the third member of this family of vanadates ZnCuV2O7 shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M2V2O7 vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn2+ to give the ZnMV2O7 samples studied in the present work. |
CC : | 001B60A66F; 001B70E50E |
FD : | Propriété magnétique; Structure cristalline; Susceptibilité magnétique; Chaleur massique; Point Néel; Synthèse chimique; Diffraction RX; Réseau monoclinique; Vanadate; Matériau antiferromagnétique; 7550E; 6166F |
ED : | Magnetic properties; Crystal structure; Magnetic susceptibility; Specific heat; Neel temperature; Chemical synthesis; XRD; Monoclinic lattices; Vanadates; Antiferromagnetic materials |
SD : | Síntesis química |
LO : | INIST-1151.354000131993370380 |
ID : | 05-0465553 |
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Pascal:05-0465553Le document en format XML
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O<sub>7</sub>
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O<sub>7</sub>
(M = Co, Ni and Cu)</title>
<author><name sortKey="Ait Salah, A" sort="Ait Salah, A" uniqKey="Ait Salah A" first="A." last="Ait Salah">A. Ait Salah</name>
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<s3>MAR</s3>
<sZ>1 aut.</sZ>
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<sZ>1 aut.</sZ>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<term>Monoclinic lattices</term>
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<term>Specific heat</term>
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<term>Point Néel</term>
<term>Synthèse chimique</term>
<term>Diffraction RX</term>
<term>Réseau monoclinique</term>
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<front><div type="abstract" xml:lang="en">Divanadates of general formula ZnMV<sub>2</sub>
O<sub>7</sub>
(M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>
O<sub>7</sub>
and ZnNiV<sub>2</sub>
O<sub>7</sub>
crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>
/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>
O<sub>7</sub>
shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>
V<sub>2</sub>
O<sub>7</sub>
vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup>
to give the ZnMV<sub>2</sub>
O<sub>7</sub>
samples studied in the present work.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>
O<sub>7</sub>
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<fA14 i1="01"><s1>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065</s1>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<fA14 i1="02"><s1>Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n</s1>
<s2>28040 Madrid</s2>
<s3>ESP</s3>
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<fC01 i1="01" l="ENG"><s0>Divanadates of general formula ZnMV<sub>2</sub>
O<sub>7</sub>
(M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>
O<sub>7</sub>
and ZnNiV<sub>2</sub>
O<sub>7</sub>
crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>
/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>
O<sub>7</sub>
shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>
V<sub>2</sub>
O<sub>7</sub>
vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup>
to give the ZnMV<sub>2</sub>
O<sub>7</sub>
samples studied in the present work.</s0>
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<server><NO>PASCAL 05-0465553 INIST</NO>
<ET>Structural characterization and magnetic properties of divanadates ZnMV<sub>2</sub>
O<sub>7</sub>
(M = Co, Ni and Cu)</ET>
<AU>AIT SALAH (A.); BENKHOUJA (K.); JAAFARI (K.); ROMERO DE PAZ (J.); CLIMENT (E.); SAEZ PUCHE (R.)</AU>
<AF>L.C.M.M., Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, P.O. Box 4065/El Jadida/Maroc (1 aut., 2 aut., 3 aut.); Departamemo de Química Inorgánica I, Facultad de Ciencias Quimicas, Vniversidad Complulense de Madrid, Ciudad Universitaria s/n/28040 Madrid/Espagne (4 aut., 5 aut., 6 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of alloys and compounds; ISSN 0925-8388; Suisse; Da. 2005; Vol. 402; No. 1-2; Pp. 213-218; Bibl. 11 ref.</SO>
<LA>Anglais</LA>
<EA>Divanadates of general formula ZnMV<sub>2</sub>
O<sub>7</sub>
(M = Co, Ni and Cu) have been prepared as powdered samples and the X-ray structural determination and magnetic studies have been carried out. Both ZnCoV<sub>2</sub>
O<sub>7</sub>
and ZnNiV<sub>2</sub>
O<sub>7</sub>
crystallize with the so-called dichromate structure type, showing monoclinic symmetry, space group P2<sub>1</sub>
/c, while the third member of this family of vanadates ZnCuV<sub>2</sub>
O<sub>7</sub>
shows the thortveitite structure type with monoclinic symmetry, space group C2/c. Magnetic susceptibility and specific heat measurements reveal that these derivatives behave as antiferromagnets and the estimated Néel temperatures are 4.5, 3.5 and 5.3 K for cobalt, nickel and copper vanadates, respectively. In all cases, the one-dimensional magnetic behavior that present the M<sub>2</sub>
V<sub>2</sub>
O<sub>7</sub>
vanadates is broken down when the magnetic cation M is half replaced by the diamagnetic Zn<sup>2+</sup>
to give the ZnMV<sub>2</sub>
O<sub>7</sub>
samples studied in the present work.</EA>
<CC>001B60A66F; 001B70E50E</CC>
<FD>Propriété magnétique; Structure cristalline; Susceptibilité magnétique; Chaleur massique; Point Néel; Synthèse chimique; Diffraction RX; Réseau monoclinique; Vanadate; Matériau antiferromagnétique; 7550E; 6166F</FD>
<ED>Magnetic properties; Crystal structure; Magnetic susceptibility; Specific heat; Neel temperature; Chemical synthesis; XRD; Monoclinic lattices; Vanadates; Antiferromagnetic materials</ED>
<SD>Síntesis química</SD>
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