Crystal structure of poly[diaqua(μ-2-carboxyacetato-κ3O,O′:O′′)(2-carboxyacetato-κO)di-μ-chlorido-dicobalt(II)]
Identifieur interne : 000438 ( Ncbi/Curation ); précédent : 000437; suivant : 000439Crystal structure of poly[diaqua(μ-2-carboxyacetato-κ3O,O′:O′′)(2-carboxyacetato-κO)di-μ-chlorido-dicobalt(II)]
Auteurs : Yasmina Bouaoud [Algérie] ; Zouaoui Setifi [Algérie] ; Andrii Buvailo [Ukraine] ; Vadim A. Potaskalov [Ukraine] ; Hocine Merazig [Algérie] ; Georges Dénés [Canada]Source :
- Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2016.
Abstract
In the title coordination polymer, [Co(C3H3O4)Cl(H2O)]
Url:
DOI: 10.1107/S2056989015023269
PubMed: 26870577
PubMed Central: 4704765
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PMC:4704765Le document en format XML
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<italic>O</italic>
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′:<italic>O</italic>
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<italic>O</italic>
,<italic>O</italic>
′:<italic>O</italic>
′′)(2-carboxyacetato-κ<italic>O</italic>
)di-μ-chlorido-dicobalt(II)]</title>
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<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000,<country>Algeria</country>
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</nlm:aff>
<country xml:lang="fr">Algérie</country>
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<country xml:lang="fr">Algérie</country>
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<author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénés">Georges Dénés</name>
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<front><div type="abstract" xml:lang="en"><p>In the title coordination polymer, [Co(C<sub>3</sub>
H<sub>3</sub>
O<sub>4</sub>
)Cl(H<sub>2</sub>
O)]<sub><italic>n</italic>
</sub>
, the sixfold coordination environment of the Co<sup>II</sup>
atom consists of two O atoms from a chelating hydrogen malonate anion (HMal<sup>−</sup>
), one O atom originating from a μ<sub>2</sub>
-bridging malonate ligand (HMal<sup>−</sup>
), one O atom from a water molecule and two μ<sub>2</sub>
-bridging Cl<sup>−</sup>
atoms, connecting neighbouring Co<sub>2</sub>
Cl<sub>4</sub>
motifs into a two-dimensional polymer extending parallel to (001). Interlayer O—H⋯O hydrogen bonds link the layers into a three-dimensional network.</p>
</div>
</front>
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