Crystal structure of poly[di-aqua-(μ-2-carb-oxy-acetato-κ(3) O,O':O'')(2-carb-oxy-acetato-κO)di-μ-chlorido-dicobalt(II)].
Identifieur interne : 000006 ( PubMed/Checkpoint ); précédent : 000005; suivant : 000007Crystal structure of poly[di-aqua-(μ-2-carb-oxy-acetato-κ(3) O,O':O'')(2-carb-oxy-acetato-κO)di-μ-chlorido-dicobalt(II)].
Auteurs : Yasmina Bouaoud [Algérie] ; Zouaoui Setifi [Algérie] ; Andrii Buvailo [Ukraine] ; Vadim A. Potaskalov [Ukraine] ; Hocine Merazig [Algérie] ; Georges Dénés [Canada]Source :
- Acta crystallographica. Section E, Crystallographic communications ; 2016.
Abstract
The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2] n , comprises one Co(II) atom, one water mol-ecule, one singly deprotonated malonic acid mol-ecule (HMal(-); systematic name 2-carb-oxy-acetate) and one Cl(-) anion. The Co(II) atom is octa-hedrally coordinated by the O atom of a water mol-ecule, by one terminally bound carboxyl-ate O atom of an HMal(-) anion and by two O atoms of a chelating HMal(-) anion, as well as by two Cl(-) anions. The Cl(-) anions bridge two Co(II) atoms, forming a centrosymmetric Co2Cl2 core. Each malonate ligand is involved in the formation of six-membered chelate rings involving one Co(II) atom of the dinuclear unit and at the same time is coordinating to another Co(II) atom of a neighbouring dinuclear unit in a bridging mode. The combination of chelating and bridging coordination modes leads to the formation of a two-dimensional coordination polymer extending parallel to (001). Within a layer, O-Hwater⋯Cl and O-Hwater⋯O hydrogen bonds are present. Adjacent layers are linked through O-H⋯O=C hydrogen bonds involving the carb-oxy-lic acid OH and carbonyl groups.
DOI: 10.1107/S2056989015023269
PubMed: 26870577
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Crystal structure of poly[di-aqua-(μ-2-carb-oxy-acetato-κ(3) O,O':O'')(2-carb-oxy-acetato-κO)di-μ-chlorido-dicobalt(II)].</title><author><name sortKey="Bouaoud, Yasmina" sort="Bouaoud, Yasmina" uniqKey="Bouaoud Y" first="Yasmina" last="Bouaoud">Yasmina Bouaoud</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000</wicri:regionArea><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Buvailo, Andrii" sort="Buvailo, Andrii" uniqKey="Buvailo A" first="Andrii" last="Buvailo">Andrii Buvailo</name><affiliation wicri:level="1"><nlm:affiliation>National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine; SciMax LLC, 2 Marshala Yakubovskogo str. 03191, Kyiv, Ukraine.</nlm:affiliation><country xml:lang="fr">Ukraine</country><wicri:regionArea>National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine; SciMax LLC, 2 Marshala Yakubovskogo str. 03191, Kyiv</wicri:regionArea><wicri:noRegion>Kyiv</wicri:noRegion></affiliation></author><author><name sortKey="Potaskalov, Vadim A" sort="Potaskalov, Vadim A" uniqKey="Potaskalov V" first="Vadim A" last="Potaskalov">Vadim A. Potaskalov</name><affiliation wicri:level="1"><nlm:affiliation>Department of General and Inorganic Chemistry, National Technical University of Ukraine, 'Kyiv Polytechnic Institute', 37 Prospect Peremogy, 03056 Kiev, Ukraine.</nlm:affiliation><country xml:lang="fr">Ukraine</country><wicri:regionArea>Department of General and Inorganic Chemistry, National Technical University of Ukraine, 'Kyiv Polytechnic Institute', 37 Prospect Peremogy, 03056 Kiev</wicri:regionArea><wicri:noRegion>03056 Kiev</wicri:noRegion></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénés">Georges Dénés</name><affiliation wicri:level="1"><nlm:affiliation>Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Laboratories for Inorganic Materials, Department of Chemistry and Biochemistry, Concordia University, Montréal, Québec, H3G 1M8, Canada.</nlm:affiliation><country xml:lang="fr">Canada</country><wicri:regionArea>Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Laboratories for Inorganic Materials, Department of Chemistry and Biochemistry, Concordia University, Montréal, Québec, H3G 1M8</wicri:regionArea><wicri:noRegion>H3G 1M8</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:26870577</idno><idno type="pmid">26870577</idno><idno type="doi">10.1107/S2056989015023269</idno><idno type="wicri:Area/PubMed/Corpus">000006</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000006</idno><idno type="wicri:Area/PubMed/Curation">000006</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000006</idno><idno type="wicri:Area/PubMed/Checkpoint">000006</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000006</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Crystal structure of poly[di-aqua-(μ-2-carb-oxy-acetato-κ(3) O,O':O'')(2-carb-oxy-acetato-κO)di-μ-chlorido-dicobalt(II)].</title><author><name sortKey="Bouaoud, Yasmina" sort="Bouaoud, Yasmina" uniqKey="Bouaoud Y" first="Yasmina" last="Bouaoud">Yasmina Bouaoud</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000</wicri:regionArea><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Buvailo, Andrii" sort="Buvailo, Andrii" uniqKey="Buvailo A" first="Andrii" last="Buvailo">Andrii Buvailo</name><affiliation wicri:level="1"><nlm:affiliation>National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine; SciMax LLC, 2 Marshala Yakubovskogo str. 03191, Kyiv, Ukraine.</nlm:affiliation><country xml:lang="fr">Ukraine</country><wicri:regionArea>National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine; SciMax LLC, 2 Marshala Yakubovskogo str. 03191, Kyiv</wicri:regionArea><wicri:noRegion>Kyiv</wicri:noRegion></affiliation></author><author><name sortKey="Potaskalov, Vadim A" sort="Potaskalov, Vadim A" uniqKey="Potaskalov V" first="Vadim A" last="Potaskalov">Vadim A. Potaskalov</name><affiliation wicri:level="1"><nlm:affiliation>Department of General and Inorganic Chemistry, National Technical University of Ukraine, 'Kyiv Polytechnic Institute', 37 Prospect Peremogy, 03056 Kiev, Ukraine.</nlm:affiliation><country xml:lang="fr">Ukraine</country><wicri:regionArea>Department of General and Inorganic Chemistry, National Technical University of Ukraine, 'Kyiv Polytechnic Institute', 37 Prospect Peremogy, 03056 Kiev</wicri:regionArea><wicri:noRegion>03056 Kiev</wicri:noRegion></affiliation></author><author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><affiliation wicri:level="1"><nlm:affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</nlm:affiliation><country xml:lang="fr">Algérie</country><wicri:regionArea>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000</wicri:regionArea><wicri:noRegion>Constantine 25000</wicri:noRegion></affiliation></author><author><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénés">Georges Dénés</name><affiliation wicri:level="1"><nlm:affiliation>Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Laboratories for Inorganic Materials, Department of Chemistry and Biochemistry, Concordia University, Montréal, Québec, H3G 1M8, Canada.</nlm:affiliation><country xml:lang="fr">Canada</country><wicri:regionArea>Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Laboratories for Inorganic Materials, Department of Chemistry and Biochemistry, Concordia University, Montréal, Québec, H3G 1M8</wicri:regionArea><wicri:noRegion>H3G 1M8</wicri:noRegion></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Crystallographic communications</title><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2] n , comprises one Co(II) atom, one water mol-ecule, one singly deprotonated malonic acid mol-ecule (HMal(-); systematic name 2-carb-oxy-acetate) and one Cl(-) anion. The Co(II) atom is octa-hedrally coordinated by the O atom of a water mol-ecule, by one terminally bound carboxyl-ate O atom of an HMal(-) anion and by two O atoms of a chelating HMal(-) anion, as well as by two Cl(-) anions. The Cl(-) anions bridge two Co(II) atoms, forming a centrosymmetric Co2Cl2 core. Each malonate ligand is involved in the formation of six-membered chelate rings involving one Co(II) atom of the dinuclear unit and at the same time is coordinating to another Co(II) atom of a neighbouring dinuclear unit in a bridging mode. The combination of chelating and bridging coordination modes leads to the formation of a two-dimensional coordination polymer extending parallel to (001). Within a layer, O-Hwater⋯Cl and O-Hwater⋯O hydrogen bonds are present. Adjacent layers are linked through O-H⋯O=C hydrogen bonds involving the carb-oxy-lic acid OH and carbonyl groups.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">26870577</PMID><DateCreated><Year>2016</Year><Month>2</Month><Day>12</Day></DateCreated><DateCompleted><Year>2016</Year><Month>02</Month><Day>12</Day></DateCompleted><DateRevised><Year>2016</Year><Month>2</Month><Day>14</Day></DateRevised><Article PubModel="Electronic-eCollection"><Journal><JournalIssue CitedMedium="Print"><Volume>72</Volume><Issue>Pt 1</Issue><PubDate><Year>2016</Year><Month>Jan</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Crystallographic communications</Title><ISOAbbreviation>Acta Crystallogr E Crystallogr Commun</ISOAbbreviation></Journal><ArticleTitle>Crystal structure of poly[di-aqua-(μ-2-carb-oxy-acetato-κ(3) O,O':O'')(2-carb-oxy-acetato-κO)di-μ-chlorido-dicobalt(II)].</ArticleTitle><Pagination><MedlinePgn>21-4</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S2056989015023269</ELocationID><Abstract><AbstractText>The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2] n , comprises one Co(II) atom, one water mol-ecule, one singly deprotonated malonic acid mol-ecule (HMal(-); systematic name 2-carb-oxy-acetate) and one Cl(-) anion. The Co(II) atom is octa-hedrally coordinated by the O atom of a water mol-ecule, by one terminally bound carboxyl-ate O atom of an HMal(-) anion and by two O atoms of a chelating HMal(-) anion, as well as by two Cl(-) anions. The Cl(-) anions bridge two Co(II) atoms, forming a centrosymmetric Co2Cl2 core. Each malonate ligand is involved in the formation of six-membered chelate rings involving one Co(II) atom of the dinuclear unit and at the same time is coordinating to another Co(II) atom of a neighbouring dinuclear unit in a bridging mode. The combination of chelating and bridging coordination modes leads to the formation of a two-dimensional coordination polymer extending parallel to (001). Within a layer, O-Hwater⋯Cl and O-Hwater⋯O hydrogen bonds are present. Adjacent layers are linked through O-H⋯O=C hydrogen bonds involving the carb-oxy-lic acid OH and carbonyl groups.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Bouaoud</LastName><ForeName>Yasmina</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Setifi</LastName><ForeName>Zouaoui</ForeName><Initials>Z</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Buvailo</LastName><ForeName>Andrii</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska str. 64, 01601 Kiev, Ukraine; SciMax LLC, 2 Marshala Yakubovskogo str. 03191, Kyiv, Ukraine.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Potaskalov</LastName><ForeName>Vadim A</ForeName><Initials>VA</Initials><AffiliationInfo><Affiliation>Department of General and Inorganic Chemistry, National Technical University of Ukraine, 'Kyiv Polytechnic Institute', 37 Prospect Peremogy, 03056 Kiev, Ukraine.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Merazig</LastName><ForeName>Hocine</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Dénés</LastName><ForeName>Georges</ForeName><Initials>G</Initials><AffiliationInfo><Affiliation>Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Laboratories for Inorganic Materials, Department of Chemistry and Biochemistry, Concordia University, Montréal, Québec, H3G 1M8, Canada.</Affiliation></AffiliationInfo></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2016</Year><Month>Jan</Month><Day>01</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Acta Crystallogr E Crystallogr Commun</MedlineTA><NlmUniqueID>101648987</NlmUniqueID></MedlineJournalInfo><OtherID Source="NLM">PMC4704765</OtherID><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">cobalt</Keyword><Keyword MajorTopicYN="N">coordination polymer</Keyword><Keyword MajorTopicYN="N">crystal structure</Keyword><Keyword MajorTopicYN="N">malonate</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>11</Month><Day>02</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2015</Year><Month>12</Month><Day>03</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>2</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>2</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>2</Month><Day>13</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">26870577</ArticleId><ArticleId IdType="doi">10.1107/S2056989015023269</ArticleId><ArticleId IdType="pii">wm5235</ArticleId><ArticleId IdType="pmc">PMC4704765</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Algérie</li><li>Canada</li><li>Ukraine</li></country></list><tree><country name="Algérie"><noRegion><name sortKey="Bouaoud, Yasmina" sort="Bouaoud, Yasmina" uniqKey="Bouaoud Y" first="Yasmina" last="Bouaoud">Yasmina Bouaoud</name></noRegion><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name><name sortKey="Setifi, Zouaoui" sort="Setifi, Zouaoui" uniqKey="Setifi Z" first="Zouaoui" last="Setifi">Zouaoui Setifi</name></country><country name="Ukraine"><noRegion><name sortKey="Buvailo, Andrii" sort="Buvailo, Andrii" uniqKey="Buvailo A" first="Andrii" last="Buvailo">Andrii Buvailo</name></noRegion><name sortKey="Potaskalov, Vadim A" sort="Potaskalov, Vadim A" uniqKey="Potaskalov V" first="Vadim A" last="Potaskalov">Vadim A. Potaskalov</name></country><country name="Canada"><noRegion><name sortKey="Denes, Georges" sort="Denes, Georges" uniqKey="Denes G" first="Georges" last="Dénés">Georges Dénés</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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