[Not Available].
Identifieur interne : 000121 ( Ncbi/Checkpoint ); précédent : 000120; suivant : 000122[Not Available].
Auteurs : Salah Kouass [Tunisie] ; Abderrahmen Guesmi [Tunisie] ; Ahmed DrissSource :
- Acta crystallographica. Section C, Crystal structure communications [ 1600-5759 ] ; 2010.
Abstract
The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.
DOI: 10.1107/S0108270109052810
PubMed: 20048409
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">[Not Available].</title><author><name sortKey="Kouass, Salah" sort="Kouass, Salah" uniqKey="Kouass S" first="Salah" last="Kouass">Salah Kouass</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, 2092 Tunis, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, 2092 Tunis</wicri:regionArea><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name><affiliation><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university" n="3">Université de Tunis - El Manar</orgName></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2010">2010</date><idno type="RBID">pubmed:20048409</idno><idno type="pmid">20048409</idno><idno type="doi">10.1107/S0108270109052810</idno><idno type="wicri:Area/PubMed/Corpus">000055</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000055</idno><idno type="wicri:Area/PubMed/Curation">000055</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000055</idno><idno type="wicri:Area/PubMed/Checkpoint">000055</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000055</idno><idno type="wicri:Area/Ncbi/Merge">000121</idno><idno type="wicri:Area/Ncbi/Curation">000121</idno><idno type="wicri:Area/Ncbi/Checkpoint">000121</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">[Not Available].</title><author><name sortKey="Kouass, Salah" sort="Kouass, Salah" uniqKey="Kouass S" first="Salah" last="Kouass">Salah Kouass</name><affiliation wicri:level="4"><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, 2092 Tunis, Tunisie.</nlm:affiliation><country xml:lang="fr">Tunisie</country><wicri:regionArea>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, 2092 Tunis</wicri:regionArea><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university">Université de Tunis - El Manar</orgName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name><affiliation><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university" n="3">Université de Tunis - El Manar</orgName></affiliation></author><author><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name></author></analytic><series><title level="j">Acta crystallographica. Section C, Crystal structure communications</title><idno type="eISSN">1600-5759</idno><imprint><date when="2010" type="published">2010</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The title compound, namely lithium cobalt(II/III) bis(diphosphate), Li(4.03)Co(1.97)(P(2)O(7))(2), is a new mixed-valent lithium/cobalt(II/III) phosphate. Three metal sites out of seven are occupied simultaneously by Li(+) and Co(II/III) ions. This disorder was established both from an analysis of the atomic displacement ellipsoids and Li/Co-O bond distances, and by means of a charge-distribution (CHARDI) model, which provides satisfactory agreement on the computed charges (Q) for all the cations.</div></front></TEI><affiliations><list><country><li>Tunisie</li></country><region><li>Gouvernorat de Tunis</li></region><settlement><li>Tunis</li></settlement><orgName><li>Université de Tunis - El Manar</li></orgName></list><tree><noCountry><name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name></noCountry><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Kouass, Salah" sort="Kouass, Salah" uniqKey="Kouass S" first="Salah" last="Kouass">Salah Kouass</name></region><name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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